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Electroinduced Drift of Neutral Charge Clusters in Salt Solutions presents studies of the processes accompanying the effect of periodic electric and magnetic fields on salt solutions in polar dielectric liquids. The authors explain phenomena from a physical point of view, without theoretical constructions and mathematical calculations. This is done in order to make the book accessible to a wide audience and to help the reader navigate in a multilateral topic that is touched upon when studying processes that occur in liquid media under the external influence of an electromagnetic nature. Additional Features: Explores the phenomenon of selective drift of solvated ions in polar dielectric liquids Applies general principles of electricity and magnetism to describe experimental results Demonstrates how small perturbations of the equilibrium distribution determine not the corrections to the effects but the effects themselves Approaches nonequilibrium molecular physics as a science of physical and chemical processes This book will be useful to specialists, engineers and graduate students, especially those recording and transmitting information in liquid media.

La détermination des équilibres en solution est essentielle à tout travail en chimie, depuis la chimie analytique jusqu'à la géochimie en passant par l'industrie chimique, les problèmes de corrosion, etc. Cet ouvrage présente les techniques de détermination des équilibres de manière unifiée, depuis les approximations usuelles (méthode des réactions prépondérantes) jusqu'au calcul numérique, en introduisant les méthodes de mathématiques appliquées nécessaires ainsi que leur mise en œuvre.Un grand nombre d'exercices sont proposés en fin de chapitre.

There are essentially two theories of solutions that can be considered exact: the McMillan-Mayer theory and Fluctuation Solution Theory (FST). The first is mostly limited to solutes at low concentrations, while FST has no such issue. It is an exact theory that can be applied to any stable solution regardless of the number of components and their co

The demands for green and sustainable synthetic methods in the fields of healthcare and fine chemicals, combined with the pressure to produce these substances expeditiously and in an environmentally benign fashion, pose significant challenges to the synthetic chemical community. Green chemistry can avoid pollution by utilizing techniques that are environmentally friendly by design and one of the best green techniques is the use of microwave (MW) assisted aqueous synthetic protocols. Fusing MW technique with water (as a benign reaction medium) can offer an extraordinary synergistic effect with greater potential than these two individual components in isolation. Selective microwave heating can be exploited to develop a high yield protocol and the use of water expedites the MW-protocol with more energy efficiency. This book provides an overview of the various processes developed using aqueous microwave chemistry and is written for chemists, chemical engineers and researchers in the early stages who want to develop sustainable and green processes. Written by well known microwave experts, the book is a comprehensive examination of the field and is the first book that deals strictly with aqueous microwave chemistry and represents a significant effort towards green chemistry. It covers all the microwave-assisted aqueous reactions in depth, including heterocycle synthesis, metal catalysis, enzyme catalysis, polymer synthesis, nanomaterials synthesis and nano-catalysis. Each chapter contains representative experimental procedures, helping the reader quickly replicate some of the experiments to gain hands-on experience.

An Overview of a Rapidly Expanding Area in ChemistryExploring the future in chemical analysis research, Ionic Liquids in Chemical Analysis focuses on materials that promise entirely new ways to perform solution chemistry. It provides a broad overview of the applications of ionic liquids in various areas of analytical chemistry, in

Hansen solubility parameters (HSPs) are used to predict molecular affinities, solubility, and solubility-related phenomena. Revised and updated throughout, Hansen Solubility Parameters: A User's Handbook, Second Edition features the three Hansen solubility parameters for over 1200 chemicals and correlations for over 400 materials including p

The behavior of substances in solutions may not be adequately characterized by the effect of any single physicochemical parameter of solvents, nor are numerous semi-empirical scales of the solvent effect (their a polaritya) suitable for their limited selections only. In recent decades, it has been found that the variation of reaction rate consta

Through the ages, water has been the inspiration of poets, painters, composers and philosophers. Today however, water is perceived as a commodity, with little thought for its role in influencing chemical reactions and shaping our terrestrial environment to make it fit for life. Water 2nd Edition is an update and extension of the RSC paperback first published in 1983. This book discusses current scientific knowledge of water: its remarkable properties, its influence on dissolved substances and its usually neglected but controlling role in the life sciences and ecology. With emphasis on developments over the last two decades, attention is drawn to important issues such as water quality, usage, economics and politics.

Comment se forme un solide à partir d'une solution? Quelles propriétés possède une dispersion de particules? Cet ouvrage développe des aspects de la chimie des cations métalliques. Il s'adresse aux étudiants avancés de 2e et 3e cycles universitaires, aux élèves des écoles d'ingénieurs et aux chercheurs de l'industrie.

Critical Survey of Stability Constants and Related Thermodynamic Data of Fluoride Complexes in Aqueous Solution covers the problems and techniques for measuring fluoride stability constants. This book is composed of two parts encompassing five chapters that describe the general characteristics of fluoride as a ligand, as well as the techniques for measuring fluoride enthalpy. The second part contains tabulations of fluoride's stability constants in aqueous solution.

Polymer–Polymer Miscibility discusses miscibility of polymeric mixtures. This book explains the theoretical and practical aspects of polymer miscibility, which has become a considerable area of research in many academic and industrial laboratories. Comprised of seven chapters, this book starts with an overview of the physical nature of the variations of the basic polymer structure. This monograph then discusses the two cases of miscible polymer blends, namely, poly(vinyl chloride) (PVC)–butadiene/acrylonitrile copolymer (NBR) and polystyrene–poly(2,6-dimethyl-1,4-phenylene oxide) (PPO) blends. This text explores the useful and unique properties of blends of poly(vinyl chloride) and butadiene/acrylonitrile copolymer rubber. Other chapters discuss the thermodynamic theories for the phase separation of block copolymers. The reader is also introduced to other variations of chemical structure, which can result in the permanent attachment of polymers to each other through block and graft copolymers. This text also explores the feasibility of covalent bonding of polymer components. This book is intended for chemical engineers and materials scientists.

A monograph examining recent progress in the field of inhomogeneous fluids, focusing on the theoretical - as well as experimental - techniques used. It presents the comprehensive theory of first-order phase transitions, including melting, and contains numerous figures, tables and display equations.;The contributors treat such subjects as: exact sum rules for inhomogenous fluids, explaining density functional and integral equation methods; exact solutions for two-dimensional homogeneous and inhomogeneous plasmas; current advances in the theory of interfacial electrochemistry; wetting experiments and the theory of wetting; freezing, with an emphasis on quantum systems and homogeneous nucleation in liquid-vapour and solid-liquid transitions; self-organizing liquids as well as kinetic phenomena in inhomogeneous fluids, using a modified Enskog theory.;Featuring over 1000 bibliographic citations, this volume is aimed at physical, surface, colloid and surfactant chemists; also physicists, electrochemists and graduate-level students in these disciplines.

Equilibrium Constants of Liquid-Liquid Distribution Reactions, Part III: Compound Forming Extractants, Solvating Solvents, and Inert Solvents focuses on the compilation of equilibrium constants of various compounds, such as acids, ions, salts, and aqueous solutions. The manuscript presents tables that show the distribution reactions of carboxylic and sulfonic acid extractants and their dimerization and other reactions in the organic phase and extraction reactions of metal ions from aqueous solutions. The book also states that the inorganic anions in these solutions are irrelevant, since they do not take part in the extraction reaction. The publication examines tables that illustrate the distribution of inorganic acids, salts, and complexes between aqueous solutions and solvents that have oxygen donor atoms. Tables that show the distribution of inorganic acids, salts, and complexes between aqueous solutions and inert solvents that do not have donor atoms and often utilized as inert diluents are also presented. The manuscript is a vital reference for readers and researchers interested in the equilibrium constants of compounds.

Reaction Kinetics, Volume II: Reactions in Solution deals with the kinetics of reactions in solution and discusses the basic principles and theories of kinetics, including a brief description of homogeneous gas reactions. This book is divided into two chapters. The first chapter focuses on the general principles of reactions in solution that includes reactions between ions and involving dipoles; influence of pressure on rates in solution; substituent effects; and homogeneous catalysis in solution. Chapter 2 primarily deals with general features of reactions in solution, emphasizing the relationship between the results of a kinetic investigation and actual reaction mechanism. This volume is intended for undergraduate students of chemistry who have not previously studied chemical kinetics. This book is also useful to more advanced students in other fields, such as biology and physics, who wish to have a general knowledge of the subject.

This book emphasises those features in solution chemistry which are difficult to measure, but essential for the understanding of both the qualitative and the quantitative aspects. Attention is paid to the mutual influences between solute and solvent, even at extremely small concentrations of the former. The described extension of the molecular concept leads to a broad view — not by a change in paradigm — but by finding the rules for the organizations both at the molecular and the supermolecular level of liquid and solid solutions.

Ultracentrifugation of Macromolecules: Modern Topics covers the theoretical description of the problem of sedimentation equilibrium of polydisperse nonideal solutions. The book discusses the sedimentation equilibrium in polydisperse nonideal solutions and the size distribution analysis by ultracentrifugal methods. The text also describes the simultaneous sedimentation and equilibrium in beta-lactoglobulin B, chymotrypsinogen A, and lysozyme solutions; as well as the sedimentation analysis of a multiple myeloma?G-globulin. People involved in physical biochemistry will find the book invaluable.

Solvent Extraction in Flame Spectroscopic Analysis provides an introductory discussion on the technique of solvent extraction in flame spectrometry. The book is comprised of six chapters the cover the various aspects and applications of solvent extraction. The text first covers the role of solvent extraction in flame spectrometric analysis, and then proceeds to describing the solvent suitable for flame spectrometry. Next, the book discusses the theoretical and practical aspects of the solvent extraction technique. The text also covers the application of the technique on various elements. The book will be of great use to researchers and professionals who require a good understanding of the various techniques in spectrometry.

Solvent Effects on Chemical Phenomena, Volume I discusses the developments in the understanding of solvent effects on chemical phenomena in solution. This five-chapter volume begins with a discussion on the general concepts of various solvation types, including positive and negative, inner and outer sphere, and mixed component. The subsequent chapter deals with the determination of the actual solvation number for single ions. A short list of the total effective hydration numbers of electrolytes determined from temperature dependence of proton shifts is also provided in this chapter. Another chapter presents a number of examples of the unusual properties of certain mixed aqueous systems. The solvent effects on reaction rates and mechanisms are highlighted in the concluding chapter. This chapter also covers various types of solvents, such as protic and dipolar aprotic. The enthalpy and entropy of activation in salvation and the Finkelstein reactions are also discussed. Research chemists and scientists, teachers, and students with courses in solution chemistry will greatly benefit from this volume.