1. A new dinuclear MnII compound with intermolecular π–π interactions.
- Author
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Chun-Bo Liu and Guang-Bo Che
- Subjects
- *
HYDROGEN bonding , *MOLECULAR structure , *CHEMICAL structure , *PYRIDINE , *MANGANESE , *LIGANDS (Chemistry) - Abstract
In the title compound, bis(μ-pyridine-2,5-dicarboxylato)bis[aqua(pyrazino[2,3- f][1,10]phenanthroline)manganese(II)] dihydrate, [Mn2(C7H3NO4)2(C14H8N4)2(H2O)2]·2H2O, each MnII atom is six-coordinated by three N atoms from one bidentate pyrazino[2,3- f][1,10]phenanthroline and one monodentate pyridine-2,5-dicarboxylate ligand, and three O atoms from two monodentate pyridine-2,5-dicarboxylate ligands and one water molecule. The two MnII atoms are bridged by two pyridine-2,5-dicarboxylate ligands, forming a centrosymmetric dinuclear molecule. Neighboring molecules interact through π–π contacts, leading to a one-dimensional supramolecular structure, and O—H⋯O hydrogen bonds complete the structure. [ABSTRACT FROM AUTHOR]
- Published
- 2006
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