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1. Amination of allyl alcohol to propionitrile over a Zn30Cr4.5/γ-Al2O3 bimetallic catalyst via coupled dehydrogenation–hydrogenation reactions.

Author

Zhang, Yuecheng, Wei, Tianyu, Pian, Yanjie, and Zhao, Jiquan

Subjects
*AMINATION, *ALLYL alcohol, *NITRILES, *ZINC alloys, *BIMETALLIC catalysts, *ALUMINUM oxide, *DEHYDROGENATION, *CHEMICAL reactions
Abstract

Highlights: [•] Zn30Cr4.5/γ-Al2O3 showed good performance on the amination of allyl alcohol to propionitrile. [•] The hydrogen derived from dehydrogenation in situ acted as a source for hydrogenation. [•] Chromium could diminish the size of ZnAl2O4 crystallites. [•] The performance of the catalyst can be recovered on line by combustion. [ABSTRACT FROM AUTHOR]

Published
2013
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