1. Photocatalyst based on TiO2 nanotube arrays co-decorated with CdS quantum dots and reduced graphene oxide irradiated by γ rays for effective degradation of ethylene.
- Author
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Zhang, Quan, Ye, Shengying, Song, Xianliang, and Luo, Shucan
- Subjects
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TITANIUM dioxide nanoparticles , *PHOTOCATALYSTS , *QUANTUM dots , *GRAPHENE oxide , *ETHYLENE , *CHEMICAL reduction - Abstract
We report herein a means of transforming TiO 2 nanotube arrays (TNAs) from an amorphous state to an anatase crystal state (denoted as ∗ TNAs), and present a single-step synthetic route for preparing CdS quantum dots (CdS QDs) as well as reduced graphene oxide (rGO) through gamma-ray irradiation. The as-prepared ∗ TNAs, CdS QDs, and rGO, which had all been subjected to gamma-ray irradiation, were then assembled together to produce the desired heterojunction (denoted as CdS QDs/rGO- ∗ TNAs). X-ray diffraction (XRD), field-emission scanning electron microscopy (FESEM), ultraviolet/visible diffuse-reflectance spectroscopy (UV/Vis DRS), Fourier-transform infrared spectroscopy (FTIR), micro-Raman spectrometry (RS), atomic force microscopy (AFM), and X-ray photoelectron spectroscopy (XPS) have been applied to characterize the appearance and performance of this photocatalyst. The photocatalytic activity of CdS QDs/rGO- ∗ TNAs towards ethylene degradation has been measured by placing it in a simulated cold-storage environment, the temperature and humidity of which were set at about 3 ± 1 °C and 75–90%, respectively. The results showed that the rate constant ( K ) of ethylene degradation could reach up to 1.07 × 10 −3 min −1 with CdS QDs/rGO- ∗ TNAs, as compared to 2.30 × 10 −4 min −1 with ∗ TNAs and 6.25 × 10 −4 min −1 with CdS QDs- ∗ TNAs, indicating that the constructed CdS QDs/rGO- ∗ TNAs constitutes a promising photocatalyst for ethylene removal in a cold storage environment. [ABSTRACT FROM AUTHOR]
- Published
- 2018
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