1. Surface tailoring of cellulose aerogel-like structures with ultrathin coatings using molecular layer-by-layer assembly.
- Author
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Atoufi, Zhaleh, Reid, Michael S., Larsson, Per A., and Wågberg, Lars
- Subjects
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CELLULOSE , *CHEMICAL structure , *SURFACE properties , *SURFACE coatings , *AEROGELS , *BASE oils , *POLYAMIDES , *CELLULOSE synthase - Abstract
Cellulose nanofibril-based aerogels have promising applicability in various fields; however, developing an efficient technique to functionalize and tune their surface properties is challenging. In this study, physically and covalently crosslinked cellulose nanofibril-based aerogel-like structures were prepared and modified by a molecular layer-by-layer (m-LBL) deposition method. Following three m-LBL depositions, an ultrathin polyamide layer was formed throughout the aerogel and its structure and chemical composition was studied in detail. Analysis of model cellulose surfaces showed that the thickness of the deposited layer after three m-LBLs was approximately 1 nm. Although the deposited layer was extremely thin, it led to a 2.6-fold increase in the wet specific modulus, improved the acid-base resistance, and changed the aerogels from hydrophilic to hydrophobic making them suitable materials for oil absorption with the absorption capacity of 16–36 g/g. Thus, demonstrating m-LBL assembly is a powerful technique for tailoring surface properties and functionality of cellulose substrates. Wet stable cellulose-based aerogels tailored through deposition of an ultrathin coating via a molecular layer-by-layer technique that facilitates efficient oil-water separation. [Display omitted] [ABSTRACT FROM AUTHOR]
- Published
- 2022
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