1. Novel multiphase nano Ni3Bi2S2/NiS anchored on graphite nanosheet for high-capacity sodium-ion battery anodes.
- Author
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Wang, Xintong, Feng, Dong, Xu, Xuezhi, Huang, Shandong, Ding, Yihong, Lin, Jie, Xie, Yuhui, Wu, Feng, Zhao, Wenbo, Zeng, Tianbiao, and Xie, Delong
- Subjects
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ANODES , *SODIUM ions , *SUPERCAPACITOR electrodes , *METAL sulfides , *CYCLING , *NANOSTRUCTURED materials - Abstract
• A novel binary metal sulfide Ni 3 Bi 2 S 2 is predicted to be synthesized from Bi 2 S 3 and Ni powder using DFT calculation. • Ni 3 Bi 2 S 2 proved a high-capacity, high-reversible, and easy-synthesized anode for sodium-ion batteries first. • Heterojunction-like Ni 3 Bi 2 S 2 /NiS-G composites surpassing most of the recently-reported same-type of sodium-ion batteries. In the context of scalable electrode production via ball-milling, achieving high cycling stability and electrochemical performance in bifunctional anodes for sodium ion batteries (SIBs) is crucial yet remains a significant challenge. To address these objectives, we have developed a unique hybrid anode nanocomposite characterized by its local multiphase nature. This composite involves the incorporation of novel ternary-Ni-Bi-S/binary-Ni-S nanomaterials onto exfoliated graphite nanosheets (Ni 3 Bi 2 S 2 /NiS-G) through a facile ball-milling process. Our combined experimental and theoretical investigations suggest that the interactions between graphite nanosheets and the layered structure of Ni 3 Bi 2 S 2 /NiS, along with the discharge products of Na 2 S, play pivotal roles in enhancing the Na+ diffusion rate and stability of the hierarchical configuration anode. Upon testing, the novel Ni 3 Bi 2 S 2 /NiS-G shows overwhelmingly higher electrochemical performance compared to the Ni 3 Bi 2 S 2 /NiS counterpart, the Ni 3 Bi 2 S 2 /NiS-G delivered a reversible capacity of 489.9 mAh/g at 0.2 A/g after 400 cycles, and displayed a high capacity of 387.3 and 339.6 mAh/g after 500 cycles at 1 A/g and 2 A/g, respectively, yielding a high capacity retention ratio of 84.8 % and 82.8 % of the 1st cycle. This work provided a novel approach for developing new bifunctional anode electrodes with high capacity and rate performance as well as superior cycling stability. [ABSTRACT FROM AUTHOR]
- Published
- 2024
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