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Based on neon gas puffing, an active feedback control of H-mod plasma divertor detachment experiment was successfully operated on the EAST tokamak. During the feedback control discharge, the plasma was detached by puffing neon gas and the strike point splitting phenomenon on divertor target was also clearly observed by divertor probes diagnostic. In boundary region, many neutral particle processes (atom and molecule) were happened and accompanied by their emission spectra under the detachment discharge. By studying these emission spectra, it is helpful for us to understand the role of atoms and molecules in boundary recycling, which is important for studying the physical mechanism of divertor detachment. For the Fulcher-α system (, D2 emission spectra in the range from 601 nm to 606 nm were observed, identified and fitted in the detachment experiment for the first time on the EAST, and the spectra in the Q(0–0) band ( in the Q branch of the Fulcher-α system were used for detailed analysis to acquire the boundary region temperature Te (below 5 eV), which could not be provided very well by other diagnostics on the EAST. An electronic version deuterium molecular spectral line database was established to identify the spectral lines and a multi-peak fitting program was developed to fit and analyze the observed spectra. [ABSTRACT FROM AUTHOR]

Based on the passive spectroscopy, the atomic emission spectra in the boundary region of the plasma have been measured by a high resolution optical spectroscopic multichannel analysis (OSMA) system in EAST tokamak. The Zeeman splitting of the spectral lines has been observed. A fitting procedure by using a nonlinear least squares method was applied to fit and analyze all polarization π and components of the atomic spectra to acquire the information of the local plasma. The spectral line shape was investigated according to emission spectra from different regions (e.g., low-field side and high-field side) along the viewing chords. Each polarization component was fitted and classified into three energy categories (the cold, warm, and hot components) based on different atomic production processes, in consistent with the transition energy distribution by calculating the gradient of the spectral profile. The emission position, magnetic field intensity, and flow velocity of a deuterium atom were also discussed in the context. [ABSTRACT FROM AUTHOR]

The excellent physical and chemical properties of cubic boron nitride (c-BN) film make it a promising candidate for various industry applications. However, the c-BN film thickness restricts its practical applications in many cases. Thus, it is indispensable to develop an economic, simple and environment-friend way to synthesize high-quality thick, stable c-BN films. High-cubic-content BN films are prepared on silicon (100) substrates by radio frequency (RF) magnetron sputtering from an h-BN target at low substrate temperature. Adhesions of the c-BN films are greatly improved by adding hydrogen to the argon/nitrogen gas mixture, allowing the deposition of a film up to 5-μm thick. The compositions and the microstructure morphologies of the c-BN films grown at different substrate temperatures are systematically investigated with respect to the ratio of H2 gas content to total working gas. In addition, a primary mechanism for the deposition of thick c-BN film is proposed. [ABSTRACT FROM AUTHOR]

Growth and structural properties of thin a-C films prepared by the 60 MHz very-high-frequency (VHF) magnetron sputtering were investigated. The energy and flux of ions impinging the substrate were also analyzed. It is found that the thin a-C films prepared by the 60 MHz sputtering have a lower growth rate, a smooth surface, and more sp3 contents. These features are related to the higher ion energy and the lower ions flux onto the substrate. Therefore, the 60 MHz VHF sputtering is more suitable for the preparation of thin a-C film with more sp3 contents. [ABSTRACT FROM AUTHOR]

In order to design the scale model in a wide frequency range, a method based on the reflective loss is proposed according to the high-frequency approximation algorithm, and an example of designing the scale model of a plate-shaped absorber is given in this paper. In the example, the frequency of the full-size measurement ranges from 2.0 GHz to 2.4 GHz, the thickness of the full-size absorber is 1 mm and the scale ratio is 1/5. A two-layer scale absorber is obtained by the proposed method. The thickness values of the bottom and top layer are 0.4 mm and 0.5 mm, respectively. Furthermore, the scattering properties of a plate model and an SLICY model are studied by FEKO to verify the effectiveness of the designed scale absorber. Compared with the corresponding values from the theoretical scale model, the average values of the absolute deviations in 10 GHz∼12 GHz are 0.53 dBm2, 0.65 dBm2, 0.76 dBm2 for the plate model and 0.20 dBm2, 0.95 dBm2, 0.77 dBm2 for the SLICY model while the incident angles are 0°, 30°, and 60°, respectively. These deviations fall within the Radar cross section (RCS) measurement tolerance. Thus, the work in this paper has important theoretical and practical significance. [ABSTRACT FROM AUTHOR]

The structural, electronic, and optical properties of Zn3(VO4)2 are investigated using full potential linearized augmented plane wave (FP-LAPW) method within the framework of density functional theory (DFT). Various approaches are adopted to treat the exchange and correlation potential energy such as generalized gradient approximation (GGA), GGA+U, and the Tran–Blaha modified Becke–Johnson (TB-mBJ) potential. The calculated band gap of 3.424 eV by TB-mBJ is found to be close to the experimental result (3.3 eV). The optical anisotropy is analyzed through optical constants, such as dielectric function and absorption coefficient along parallel and perpendicular crystal orientations. The absorption coefficient reveals high absorption ( of photons in the ultraviolet region. [ABSTRACT FROM AUTHOR]

During edge localized modes (ELMs), the sheath evolution in front of the Experimental Advanced Superconducting Tokamak (EAST) upper divertor is studied to estimate the sputtered tungsten (W) atoms from the divertor target. A large potential drop across the sheath is formed during ELMs by compared with inter-ELMs, and the maximum of sheath potential drop can exceed one thousand of eV in current EAST operation. Due to the enhancement of the sheath potential drop during ELMs, the W physical sputtering yield from the deuterium (D) ions and the impurity ions on the upper divertor target is found to be significant. It is established that the sputtered W yield during ELMs is at least higher by an order of magnitude than inter-ELMs, and D ions and carbon (C) ions are the main ions governing the W production for the current H-mode with ELMs discharges. With increase in the pedestal electron temperature, the maximum of the D and C ion impact energy during ELMs shows a nearly linear increase, and the D ions have sufficient impact energy to cause the strong W physical sputtering. As a consequence, the D ions may dominate the sputtered W flux from the divertor target when the C concentration is controlled less than one percent for the higher heating power H-mode with ELM discharges in near future. [ABSTRACT FROM AUTHOR]

In the present study, high-quality apatite-type La9.33Ge6O26 powders are successfully synthesized by a facile molten-salt synthesis method (MSSM) at low temperatures, using LiCl, LiCl/NaCl mixture (mass ratio 1:1) as molten salt, respectively. Experimental results indicate that the optimal mass ratio between reactant and molten salt is 1:2, and LiCl/NaCl mixed molten-salt is more beneficial for forming high-quality La9.33Ge6O26 powders than LiCl individual molten-salt. Comparing with the conventional solid-state reaction method (SSRM), the synthesis temperature of apatite-type La9.33Ge6O26 powders using the MSSM decreases more than 350 °C, which can effectively avoid Ge loss in the preparation process of precursor powders. Furthermore, the powders obtained by the MSSM are homogeneous, non-agglomerated and well crystallized, which are very favorable for gaining dense pellets in the premise of avoiding Ge loss. On the basis of high-quality precursor powders, the dense and pure ceramic pellets of La9.33Ge6O26 are gained at a low temperature of 1100 °C for 2 h, which exhibit higher conductivities (, and lower activation energies (, ) than that synthesized by the SSRM. [ABSTRACT FROM AUTHOR]

The pressure-induced structural evolution of apatite-type La9.33Si6O26 was systematically studied using in situ synchrotron x-ray diffraction (XRD). The XRD spectra indicated that a subtly reversible phase transition from P63/m to P63 symmetry occurred at ∼13.6 GPa because of the tilting of the SiO4 tetrahedra under compression. Furthermore, the La9.33Si6O26 exhibited a higher axial compression ratio for the a-axis than the c-axis, owing to the different axial arrangement of the SiO4 tetrahedra. Interestingly, the high-pressure phase showed compressibility unusually higher than that of the initial phase, suggesting that the low P63 symmetry provided more degrees of freedom. Moreover, the La9.33Si6O26 exhibited a lower phase transition pressure () and a higher lattice compression than La10Si6O27. Comparisons between La9.33Si6O26 and La10Si6O27 provided a deeper understanding of the effect of interstitial oxygen atoms on the structural evolution of apatite-type lanthanum silicates (ATLSs). [ABSTRACT FROM AUTHOR]

To investigate the radiative divertor behavior and physics for the scenario of impurity seeded plasma in ITER, the radiative divertor experiments with argon (Ar) seeding under ITER-like tungsten divertor condition were carried out during recent EAST campaigns. The experimental results reveal the high efficiency of reducing heat load and particle flux onto the divertor targets owing to increased radiation by Ar seeding. We achieve detached plasmas in these experiments. The inner–outer divertor asymmetry reduces after Ar seeding. Impurities, such as Ar, C, Li, and W, exist in the entire space of the vacuum chamber during EAST operations, and play important roles in power exhausting and accelerating the plasma detachment process. It is remarkable that the contamination of the core plasma is observed using Ar seeding owing to the sputtering of plasma facing components (PFCs), particularly when Ar impurity is injected from the upper tungsten divertor. [ABSTRACT FROM AUTHOR]

Carbon monoxide (CO) is a gaseous pollutant with adverse effects on human health and the environment. Kaolinite is a natural mineral resource that can be used for different applications, including that it can also be used for retention of pollutant gases. The adsorption behavior of carbon monoxide molecules on the (001) surface of kaolinite was studied systematically by using density-functional theory and supercell models for a range coverage from 0.11 to 1.0 monolayers (ML). The CO adsorbed on the three-fold hollow, two-fold bridge, and one-fold top sites of the kaolinite(001) was tilted with respect to the surface. The strongest adsorbed site of carbon monoxide on the kaolinite (001) surface is the hollow site followed by the bridge and top site. The adsorption energy of CO decreased when increasing the coverage, thus indicating the lower stability of surface adsorption due to the repulsion of neighboring CO molecules. In addition to the adsorption structures and energetics, the lattice relaxation, the electronic density of states, and the different charge distribution have been investigated for different surface coverages. [ABSTRACT FROM AUTHOR]

A stable and insoluble V2O5·nH2O/tetra-n-butyl titanate (TBO) hybrid xerogel was synthesized by the sol–gel method. This novel material proved to be an efficient absorbent with an absorption capacity of 179 mg·g−1 for Rhodamine B (RhB) in water due to its unique layered structure, which can effectively accommodate RhB molecules between its layers as demonstrated by XRD and FTIR spectroscopic analyses. [ABSTRACT FROM AUTHOR]