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In this study the effects of Al2O3 nanoparticle concentration were investigated on the membrane structure/performance; the boundary of variations was detected, introduced as Nanoparticle Concentration Threshold (NCTh), and was used for forecasting the field of membrane application. For this purpose, Al2O3 nanoparticles with a size of 70 nm and a concentration between 0 and 0.52 Wt.% were added to the membrane matrix. Loading threshold of Al2O3 nanoparticles was evaluated and the properties of the nanocomposite membrane were compared up and sub the loading threshold. Rheometric analysis, contact angle measurement, SEM images, and filtration experiments showed that concentration threshold of Al2O3 nanoparticles was 0.39 Wt.%. Based on their properties, the antifouling performance of those membranes possessing Al2O3 concentration below the threshold was evaluated in a membrane bioreactor (MBR). [ABSTRACT FROM AUTHOR]

The aim of this study is to investigate the effect of the presence and impregnation of iron oxide nanoparticles with the polysulfone membrane matrix. The nanoparticles were synthesized via co-precipitation method and were added to the membrane structure through blending with the polymeric matrix (Blended Nanocomposite Membranes (BNM)), deposition by photopolymerization (PhotoPolymerized Nanocomposite Membranes (PPNM)) and deposition by interfacial polymerization (Interfacially Polymerized Nanocomposite Membranes (IPNM)). FTIR analysis proved the presence of nanoparticles in all of the three types of membranes. According to AFM images, nanoparticles enhance the membrane roughness. On the account of SEM images obtained from the membrane surface, nanocomposite membranes have a more uniform surface compared to neat polymeric membranes. In addition, the cross-sectional SEM images of the membrane revealed that the blending method provides the opportunity of controlling the membrane morphology by means of nanoparticles. Contact angle analysis confirmed the development of nanocomposite membrane hydrophilicity versus neat polymeric membranes. The filtration experiments including permeation flux, dye rejection, and molecular weight cut off were done to compare all of the nanocomposite membranes. The results indicated that the blending method can improve the membrane structural properties and the deposition method can improve their separation yield. [ABSTRACT FROM AUTHOR]

Abstract: This work investigates filtration performance of mesh filter bioreactor for synthetic municipal wastewater treatment. Critical flux is measured by flux stepping method and the effect of aeration rate on the critical flux is investigated. The long term monitoring of trans-filter pressure evolution at sub and super-critical fluxes is performed. The analysis of resistance is achieved by determination of resistances and microscopic observation of bio-cake. Cake resistance values vary from 78% to 92% of total filtration resistance for sub and super-critical fluxes. The effect of variations of specific aeration demands (SADm: 0.5–6m3/m2 h) on suspended solid of effluent, turbidity of filtrate, filtration resistance, and zeta potential of biomass is evaluated. The results show that filtrate quality is decreased when the aeration rate increases. It is attributed to stable formation of dynamic membrane. A rather clear filtrate, less than 18 NTU of turbidity, is obtained for SADm 0.5m3/m2 h. The results also show that the total filtration resistance of the sub-critical flux significantly decreases with increasing aeration intensity until SADm 2m3/m2 h and thereafter slightly decreases. It is also shown that the variations of zeta potential of biomass with aeration rate highly correspond to the alterations of filtration resistance. [Copyright &y& Elsevier]

Abstract: Treatment of pharmaceutical wastewater is a real challenge for wastewater engineers. In this study, a pilot-scale system including an external loop airlift membrane bioreactor (ELAMBR) was applied for treatment of a synthetic pharmaceutical wastewater. The performance of this system was evaluated in removal of acetaminophen as the main pollutant of a pharmaceutical wastewater. A conventional activated sludge (CAS process) laboratory system was used in parallel with this system to compare both systems in regard to their ability for acetaminophen removal. The performance of the ELAMBR system was monitored for approximately one month to investigate the long-term operational stability of the system and possible effects of solids retention time on the efficiency of removal of acetaminophen. The removal efficiency was significantly higher in the ELAMBR system than the CAS process. 100% of the acetaminophen was removed after 2days in this system. The results also showed that initial concentration of acetaminophen, chemical oxygen demand (COD) and mixed liquid suspended solids (MLSS) are the most effective parameters in removal of a pollutant such as acetaminophen. This study demonstrates the usefulness of ELAMBR system for pharmaceutical wastewater treatment with the advantages such as: (i) simple operation and maintenance, (ii) efficient removal of pharmaceutical pollutant and COD and (iii) low-energy consumption. [Copyright &y& Elsevier]

Abstract: The effects of sludge viability on process performance and membrane fouling in a membrane bioreactor were investigated. A laboratory-scale submerged membrane bioreactor (SMBR) containing a flat-sheet microfiltration membrane was used at various percentages of living cellular flocs and dead cells. The effect of live to dead cells ratio on the extracellular polymeric substances (EPS) concentration was also studied. The proportion of dead cells affected the type of EPS in the mixed liquor as well as hydrophobicity of activated sludge. Tightly bound EPS (TB-EPS) mitigated membrane fouling, whereas loosely bound EPS (LB-EPS) caused severe membrane fouling. The results show that the content of TB-EPS and LB-EPS increases with dead cells portion. Furthermore, the ratio of TB-EPS to LB-EPS was presented as an important parameter in MBR performance. It was showed that this ratio is a good representative of flocculability of activated sludge and fouling intensity. Compared to the live cells, the dead cells had lower hydrophobicity and induced membrane fouling so that membrane permeability of the viable activated sludge was twice of the dead cell culture. The potential of zone settling velocity (ZSV) to be considered as a key parameter in MBR operation was also reported. [Copyright &y& Elsevier]

Abstract: The rising demand for high quality water heightens the need to soften hard and very hard water. In this study, flat sheet polysulfone ultrafiltration membranes were prepared by phase inversion and modified by UV-induced polymerization of acrylic acid in order to prepare nanofiltration membranes for water desalination. Polyethylene glycol of different molecular weights mainly in the range of 1500–4000Da were used in the casting solution and acrylic acid was polymerized on the membrane surface. In this way, a manipulated membrane was prepared with higher pore size and higher surface charge density for improved water softening. The results show that by increasing irradiation time and monomer concentration in the photografting process, pure water flux declines and salt rejection increases. For a membrane photografted for 180min with acrylic acid solution (6wt.%) and PEG-4000 as additive, the rejection of Na2SO4, MgSO4, NaCl and CaCl2 follows a decreasing in order of 100%, 77.9%, 49.9% and 35.9% respectively. The RMS roughness of the prepared membrane is 1.65nm, which is well in the nanofiltration roughness range. Featuring a large pore size and high surface charge density, the developed nanofiltration membranes show a promising capability for water desalination. [Copyright &y& Elsevier]