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Industrial processes and municipal wastes largely contribute to the fluctuations in iron (Fe) content in soils. Fe, when present in unfavorable amount, causes harmful effects on human, flora, and fauna. The present study is an attempt to evaluate the composition of Fe in surface soils from paper mill and municipal landfill sites and assess their potential ecological and human health risks. Geochemical fractionation was conducted to explore the chemical bonding of Fe across different fractions, i.e., water-soluble (F1) to residual (F6). Different contamination factors and pollution indices were evaluated to comprehend Fe contamination extent across the study area. Results indicated the preference for less mobile forms in the paper mill and landfill, with 26.66% and 43.46% of Fe associated with the Fe–Mn oxide bound fraction (F4), and 57.22% and 24.78% in the residual fraction (F6). Maximum mobility factor (MF) of 30.65% was observed in the paper mill, and 80.37% in the landfill. The enrichment factor (EF) varied within the range of 20 < EF < 40, signifying a high level of enrichment in the soil. The individual contamination factor (ICF) ranged from 0 to >6, highlighting low to high contamination. Adults were found to be more vulnerable towards Fe associated health risks compared to children. The Hazard Quotient (HQ) index showed the highest risk potential pathways as dermal contact > ingestion > inhalation. The study offers insights into potential Fe contamination risks in comparable environments, underscoring the crucial role of thorough soil assessments in shaping land use and waste management policies. [Display omitted] • Geochemical fractionation unveils less bioavailable Fe in contaminated soil. • EF, ICF, and I geo indicate high Fe contamination. • Adults are more susceptible to potential health risks from surplus Fe exposure. • HQ analysis pinpoints dermal contact as the primary pathway for Fe exposure risks. [ABSTRACT FROM AUTHOR]

Over time, the risk assessment of dermal exposure to pollutants in print paper products has received considerable attention. Most studies have focused on organic pollutants, especially bisphenol A (BPA). However, little is known about the levels of trace elements in print paper products, despite the knowledge that these elements are components of printing inks and toners. This study was aimed at determining the concentrations of trace elements in 5 types of paper products, namely bulletins, magazines, special events program booklets, handbills, and newspapers. The average daily intake (ADI) of each element was subsequently estimated through dermal exposure to the papers. The detection frequency of the elements of interest was high (nearly 100%) in most paper products, with the exception of chromium, whose detection was low. In contrast, Ag was not detected in any sample. The levels of the elements in the paper products were low and comparable to those found in other personal and consumer products with the potential for skin contact. The range values of estimated ADIs were 1.70–3.90E-08, 2.30–18.2E-10, 2.60–16.4E-09, 3.65–5.75E-08, 1.29–4.38E-08, 6.23–15.6E-10, 1.51–2.80E-10, 1.43–9.16E-09, 0.00–9.47E-09, and 4.68–220E-08 mg/kg bw/day for Mn, Co, Ni, Cu, Zn, As, Cd, Pb, Cr and Fe respectively. These values were well below the dermal standard reference doses (R f D) for each element. The present results indicate that dermal exposure to trace elements from print paper products was low and does not pose significant risks for toxic (non-carcinogenic) effects on humans. • Previous efforts have focused on the risk assessment of organic contaminants in print paper products. • Limited attention accorded to risk assessment of trace elements in print paper products • Human dermal exposure to trace elements via print paper products was low • Exposure to trace elements via print paper products has low risks of non-carcinogenic events. [ABSTRACT FROM AUTHOR]

Agro-based pulp and paper mills (PPMs) inevitably produce numerous refractory pollutants in their wastewater, including chlorolignin, chlorophenols, chlorocatechols, chloroguaiacol, cyanide, furan, dioxins, and other organic compounds, as well as various heavy metals, such as nickel (Ni), zinc (Zn), chromium (Cr), iron (Fe), lead (Pb), arsenic (As), etc. These pollutants pose significant threats to aquatic and terrestrial life due to their cytogenotoxicity, mutagenicity, impact on sexual organs, hormonal interference, endocrine disruption, and allergenic response. Consequently, it is crucial to reclaim pulp paper mill wastewater (PPMW) with high loads of refractory pollutants through effective and environmentally sustainable practices to minimize the presence of these chemicals and ensure environmental safety. However, there is currently no comprehensive published review providing up-to-date knowledge on the fate of refractory pollutants from PPMW in soil and aquatic environments, along with valuable insights into the associated health hazards and remediation methods. This critical review aims to shed light on the potential adverse effects of refractory pollutants from PPMW on natural ecosystems and living organisms. It explores existing effective treatment technologies for remediating these pollutants from wastewater, highlighting the advantages and disadvantages of each approach, all in pursuit of environmental safety. Special emphasis is placed on emerging technologies used to decontaminate wastewater discharged from PPMs, ensuring the preservation of the environment. Additionally, this review addresses the major challenges and proposes future research directions for the proper disposal of PPMW. It serves as a comprehensive source of knowledge on the environmental toxicity and risks associated with refractory pollutants in PPMW, making it a valuable reference for policymakers and researchers when selecting appropriate technologies for remediation. The scientific community, concerned with mitigating the widespread risks posed by refractory pollutants from PPMs, is expected to take a keen interest in this review. [Display omitted] [ABSTRACT FROM AUTHOR]

Three specific catalysts, namely ZIF-67 (zeolitic imidazolate framework-67), Co@NCF (Co@Nitrogen-Doped Carbon Framework), and 3D NCF (Three-Dimensional Nitrogen-Doped Carbon Framework), were prepared and studied for pulp and paper mill effluent degradation using heterogeneous activation of peroxymonosulfate (PMS). Numerous characterizations, including scanning electron microscopy (SEM), X-ray diffraction (XRD), and N 2 adsorption, were used to characterize the properties of three different catalysts. 3D NCF is remarkably effective at heterogeneous activation of PMS to generate sulfate radicals to degrade pulp and paper mill effluent (PPME) compared to the other as-prepared catalysts. The catalytic activity reveals a sequence of 3D NCF > Co@NCF > ZIF-67.3D NCF could degrade organic pollutants in 30 min at an initial COD concentration of 1146 mg/L of PPME, 0.2 g/L catalysts, 2 g/L PMS, and 50 °C. Consequently, it was observed that the degradation of PPME using 3D NCF followed first-order kinetics, with an activation energy of 40.54 kJ mol−1. Overall, 3D NCF/PMS system reveals promising performance for PPME removal. • 3D NCF synthesized via calcining and etching a zeolitic imidazolate framework (ZIF-67). • 3D NCF presented the highest activity in the pulp and paper mill effluent degradation. • 3D NCF proved to be a promising catalyst and has superior stability. • Pulp and paper mill effluent degradation on 3D NCF followed pseudo-first-order kinetics. [ABSTRACT FROM AUTHOR]

Accompanying China's accession to the World Trade Organization, the rapid development of the Chinese economy has led to increasingly serious environmental issues. However, the inherent mechanisms underlying the impact of Environmental Information Disclosure (EID) policy and trade on the environmental effects of Chinese paper enterprises remain unclear in the context of the era's requirement for a resource-conserving and environmentally-friendly society. The pollution problem in the papermaking industry has received attention worldwide, and how to balance the environmental and development issues of papermaking enterprises is an urgent issue that needs to be solved in the academic community. This study explores the impact mechanisms of EID policy and trade on the environmental effects of enterprises from the perspective of financial constraints. Utilizing the PSM-DID model, the study investigates the moderating effects of financial constraints on the EID policy and import-export trade. The findings reveal that both external and internal financial constraints have negative, detrimental effects on the environmental effects of the EID policy and trade. These constraints impede research and development investment and technological upgrades, hinder productivity improvement, and hamper the realization of "regulatory and trade innovation effects". This study enriches our understanding of the mechanisms by which trade affects the environmental effects of Chinese paper enterprises and further identifies the impacts of Chinese EID policy and trade on pollution emissions by enterprises, providing a theoretical basis and practical foundation for the government in formulating financial, environmental, and trade policies. • Analyzing the environmental effects of Chinese paper enterprises from the perspective of financing constraints. • This study validated the research hypothesis using three micro databases. • This study decomposes the impact mechanism into three aspects: scale effects, technical effects, and structural effects. [ABSTRACT FROM AUTHOR]

The heteroatoms and transition metal co-doped carbon-based catalysts are an important way to improve the catalytic activity of oxygen reduction reaction (ORR). Herein, we reported a facile method to obtain iron, nitrogen, and sulfur co-doped cellulose paper carbon fibers as catalysts (Fe–N–S/CFs) for ORR in microbial fuel cells (MFCs) with the adsorption recovery of Congo red molecules from dye wastewater. The thermal treatment promoted the etching of carbon surface by ferric ions, resulting in increased surface roughness for forming the defective carbon structure. The rich active species and defective carbon formed on the etched surface to enhance the electroactive surface area and effective sites. Fe–N–S/CFs catalysts achieved high half-wave potential due to the synergy effect between chemical components and defect structures. The assembled single-chamber air cathode MFC gained a high maximum power density of 1773 ± 40 mW m−2 versus Pt/C MFC of 1325 ± 94 mW m−2. This work provides a strategy for recovering dye molecules from wastewater to prepare non-precious metal catalysts for enhancing ORR activity. • Mg(OH) 2 @PF was employed to efficiently adsorb Congo red from the dye wastewater. • Congo red/Mg(OH) 2 @PF co-calcined with iron nitrate to fabricate Fe–N–S/FCs catalyst. • The Fe–N–S/CFs showed the excellent ORR performance with the active specie of FeN x. • The assembled air cathode MFCs achieved high maximum power density (1773 ± 40 mW m−2). [ABSTRACT FROM AUTHOR]

The primary source of soil pollution is a complex mixture of numerous inorganic and organic compounds (including chlorinated compounds, nutrients, and heavy metals, etc.). The presence of all of these compounds makes remediation and cleanup difficult. In this study, the phytoremediation ability of Jatropha curcas and Pongamia pinnata was tested to remove nickel (Ni) and Zinc (Zn) from paper mill and municipal landfill contaminated soils, to understand the uptake potential and to estimate the accumulation pattern of Ni and Zn in the vegetative parts of the plant. The experiments were carried out in pots (3 kg capacity) and the different combinations of soil were made by mixing the contaminated soil with a reference soil (forest soil) as T 0 , T 25 , T 50 , T 75 and T 100. The plant biomass, chlorophyll content, proline, nitrate reductase activity and metal removal efficiency (%)were determined after 120 DAS (i.e., the days after sowing). The results of the study showed that with increasing metal stress, there is a reduction in the above-ground biomass content in both the plant species with a slightly less impact on the root biomass. Over a period of 4 months, J. curcas and P. pinnata removed 82–86% and 93-90% Ni, respectively. The removal of Zn was significantly less as compared to Ni as most of the Zn remained in the belowground part (roots) and in the soil. Besides, the phytostabilization capacities of the plants were calculated on the basis of their tolerance index (TI), bioaccumulation factor (BAF) and translocation factor (TF). The low BAF and TF values with increasing heavy metals (HMs) content indicates its higher phytostabilization capacity in the root and rhizospheric region as compared to phytoaccumulation. [Display omitted] • J. curcas and P. pinnata removes 82 - 86 % and 93- 90 % Ni respectively. • High biomass and bioaccumulation factor (BAF) > 1: Suitable for metal phytoextraction. • Low biomass and BAF < 1: Suitable for metal phytostabilization. • Low translocation factor (< 1) indicated the phytostabilization capacity of the plants. [ABSTRACT FROM AUTHOR]

This study investigated the effectiveness of extended aeration system (EAS) and rice straw activated carbon-extended aeration system (RAC-EAS) in the treatment of pulp and paper biorefinery effluent (PPBE). RAC-EAS focused on the efficient utilization of lignocellulosic biomass waste (rice straw) as a biosorbent in the treatment process. The experiment was designed by response surface methodology (RSM) and conducted using a bioreactor that operated at 1–3 days hydraulic retention times (HRT) with PPBE concentrations at 20, 60 and 100%. The bioreactor was fed with real PPBE having initial ammonia-N and total phosphorus (TP) concentrations that varied between 11.74 and 59.02 mg/L and 31–161 mg/L, respectively. Findings from the optimized approach by RSM indicated 84.51% and 91.71% ammonia-N and 77.62% and 84.64% total phosphorus reduction in concentration for EAS and RAC-EAS, respectively, with high nitrification rate observed in both bioreactors. Kinetic model optimization indicated that modified stover models was the best suited and were statistically significant (R2 ≥ 0.98) in the analysis of substrate removal rates for ammonia-N and total phosphorus. Maximum nutrients elimination was attained at 60% PPBE and 48 h HRT. Therefore, the model can be utilized in the design and optimization of EAS and RAC-EAS systems and consequently in the prediction of bioreactor behavior. [ABSTRACT FROM AUTHOR]

The research assessed waste-based briquettes consumption compared to conventional fuels in the Andes. Laboratory tests were conducted together with on-field analysis in Colquencha (Bolivia). The laboratory study shows that the performances of briquettes are better in terms of PM2.5 (933.4 ± 50.8 mg kg−1) and CO emissions (22.89 ± 2.40 g kg−1) compared to animal dung (6265.7 ± 1273.5 mgPM2.5 kg−1 and 48.10 ± 12.50 gCO kg−1), although the boiling time increased due to the lower fuel consumption rate and firepower compared to shrubs. The social survey organized with 150 Bolivian citizens suggested that low-income households are not able to pay for an alternative fuel: about 40% would pay less than 4 USD per month, while methane use for cooking is positively correlated with the income level (r = 0.244, p < 0.05). On field analysis suggested that local cookstoves are not appropriate for briquettes combustion since indoor air pollution overcomes 30 ppm of CO and 10 mgPM2.5 m-3. On balance, local small manufactures can be the main target for selling waste-based briquettes to reduce shrubs and wood consumption. However, briquettes production costs seem not yet competitive to natural easy-to-obtain fuels (i.e., animal dung). The research encourages the use of cellulosic and biomass waste-based briquettes in the Andean area for cooking, heating, or manufacturing and strongly advises policy-makers to introduce economic incentives for the recovery of secondary raw materials. • Analysis of waste-based briquettes use in Andean areas were conducted. • Laboratory analysis, social surveys, and on field evaluations are the methods. • Briquettes can be employed for reducing about 30% of the conventional fuels. • The research encourages the employment of waste-based briquettes in the Andes. • Incentives to briquettes production and consumption should be introduced. [ABSTRACT FROM AUTHOR]

Novel Carbon quantum dots-graphite composite ink-based Screen-printed electrodes (CQDs/SPEs) were used to assemble a highly sensitive electrochemical aptasensor against chlorpyrifos (CPF). The aptasensor showed a broad linear range from 1 pM (0.445 ng/ml) to 500 nM (0.22 mg/ml) with a detection limit (LOD) 0.834 pM (0.37 ng/ml); sensitivity 21.39 μA pM−1 cm− 2 and with good linearity of R2 = 0.973. Moreover, the aptasensor's showed better selectivity among few other pesticides. Further, the aptasensor electrode showed high stability for five months when stored at 4 °C. In the final step, the aptasensor's ability to identify CPF in real samples was evaluated on spiked potato (Solanum tuberosum) extract samples. Potato extract spiked with CPF in the electrochemical aptasensing platform showed excellent linearity of R2 = 0.981. The developed aptasensor showed good response to without spiked potato extract with increasing volumes. Hence, the developed aptasensor demonstrated reasonable applicability in real food and agriculture samples. • Chlorpyrifos (CPF), an organophosphate pesticide, is known for detrimental effects on environment raising global health concern. • Electrochemical based disposable screen printed aptasensor is developed for the detection of chlorpyrifos pesticide. • The CQDs/SPE aptasensor was fabricated using carbon quantum dots (CQDs) through drop cast method. • The aptasensor exhibited a wide linear range (1 pM-500 nM) with LOD (0.834 pM) and high sensitivity (21.39 μA pM−1 cm− 2). [ABSTRACT FROM AUTHOR]

The JK Paper industry located at Rayagada discharges biologically untreated effluent more than the permissible limit prescribed by Pollution Control Board, Odisha in to the environment. The industry is seriously polluting the surrounding aquatic and terrestrial environment. No detailed intensive study was carried out by previous workers on this industry earlier. The present study aims at finding out the impact of effluent on the flora at the contaminated site. The chemically treated effluent (TE) contained significant amount of mercury and cadmium. The TE has high BOD, COD, dissolved solids and suspended solids when compared to normal river water at the site of discharge. The TE deteriorated the natural water bodies changing the physico-chemical properties of natural river water. After meeting the river water the TE was diluted after 1 km distance from the meeting point of the river. Crop plants collected from the contaminated site showed higher level of residual Hg and Cd and significant depletion in pigment was observed. Plants collected from both the sides of the treated effluent canal showed significant amount residue mercury and cadmium in the plant leaves. The plants exposed to the TE, showed variation in chlorophyll and Phaeophytin pigment content when compared to their respective control values in all terrestrial plants collected from the contaminated site. In some plant leaves little increment in the pigment level was noted but the values were not significant. The changes observed in the plant pigment might be due to heavy metal accumulation. The presence of residual Hg and Cd in crop plants and plant leaves grazed by grazing animals after absorption, accumulation and enrichment may lead to a possible biological magnification, warrants attention. Proper biological treatment, treatment of effluent by modern methods and removal of heavy metals from the effluent before discharge by the industry is suggested. • Biological treatment of the effluent was not carried out by the industry & chemicals present in the effluent were significantly high.. • The water quality of the river water deteriorated due to the discharge of effluent of the paper mill. • Plants collected from the contaminated site showed significant accumulation of cadmium and mercury in leaf tissues • Significant depletion in pigment content of exposed plant leaves was noticed. • Depletion in plant pigment was due to accumulation of cadmium and mercury in plant tissues absorbed from the effluent. [ABSTRACT FROM AUTHOR]

The current study analyzed the high heating values (HHVs) of various waste biomass materials intending to the effective management and more sustainable consumption of waste as clean energy source. Various biomass waste samples including date leaves, date branches, coconut leaves, grass, cooked macaroni, salad, fruit and vegetable peels, vegetable scraps, cooked food waste, paper waste, tea waste, and cardboard were characterized for proximate analysis. The results revealed that all the waste biomass were rich in organic matter (OM). The total OM for all waste biomass ranged from 79.39% to 98.17%. Likewise, the results showed that all the waste biomass resulted in lower ash content and high fixed carbon content associated with high fuel quality. Based on proximate analysis, various empirical equations (HHV=28.296-0.2887(A)-656.2/VM, HHV=18.297-0.4128(A)+35.8/FC and HHV=22.3418-0.1136(FC)-0.3983(A)) have been tested to predict HHVs. It was observed that the heterogeneous nature of various biomass waste considerably affects the HHVs and hence has different fuel characteristics. Similarly, the HHVs of waste biomass were also determined experimentally using the bomb calorimeter, and it was observed that among all the selected waste biomass, the highest HHVs (21.19 MJ kg−1) resulted in cooked food waste followed by cooked macaroni (20.25 MJ kg−1). The comparison revealed that experimental HHVs for the selected waste biomass were slightly deviated from the predicted HHVs. Based on HHVs, various thermochemical and biochemical technologies were critically overviewed to assess the suitability of waste biomass to energy products. It has been emphasized that valorizing waste-to-energy technologies provides the dual benefits of sustainable management and production of cleaner energy to reduce fossil fuels dependency. However, the key bottleneck in commercializing waste-to-energy systems requires proper waste collection, sorting, and continuous feedstock supply. Moreover, related stakeholders should be involved in designing and executing the decision-making process to facilitate the global recognition of waste biorefinery concept. [Display omitted] • The high heating values (HHVs) of biomass waste were assessed with the aim for the sustainable consumption of waste as a source of clean energy. • All the biomass waste were rich in organic matter and fixed carbon content that ranged from 79.39% to 98.17% and 50.64%–54.26% respectively. • The maximum HHVs (21.19 MJkg−1) were recorded for cooked food waste. • The heterogeneous nature of various biomass waste considerably affects the HHVs and hence serve as suitable feedstock for various energy conversion technologies. [ABSTRACT FROM AUTHOR]

Review papers help researchers understand the direction and flow of research and help beginners quickly acquire relevant knowledge. Therefore, the review paper should describe only accurate contents and should be written with only core and important matters. Recently, Othmani et al. (2022) reviewed more than 200 papers related to the adsorptive removal of three harmful pollutants: toxic organics (phenols), anionic heavy metal (Cr(VI)) and cationic heavy metal (Cd(II)) by agricultural waste materials. However, Cr(VI)-related section of this review is missing something important that should be provided to the readers of this journal. In fact, the removal mechanism of Cr(VI) by nonliving biomass including agricultural waste materials under acidic conditions is not a simple anion adsorption but a complex mechanism involving redox reaction called "adsorption-coupled reduction". Therefore, when interpreting the factors affecting Cr(VI) removal, it should be interpreted in terms of the redox reaction concept, not anion adsorption. • Reduction of Cr(VI) to Cr(III) by agricultural waste materials. • Complex mechanism called "adsorption-coupled reduction". • Interpretation of experimental data with reduction reaction concept. [ABSTRACT FROM AUTHOR]

To ensure safe drinking water, it is necessary to have a simple method by which the probable pollutants are detected at the point of distribution. Nitrite contamination in water near agricultural locations could be an environmental concern due to its deleterious effects on the human population. The development of a frugal paper-based microfluidic sensor could be desirable to achieve the societal objective of providing safe drinking water. This work describes the development of a facile and cost-effective microfluidic paper-based sensor for quantitative estimation of nitrite in aquatic environments. A simple punching machine was used for fabrication and rapid prototyping of paper-based sensors without the need of any specialized equipment or patterning techniques. A reusable 3D printed platform served as the support for simultaneous testing of multiple samples. The nitrite estimation was carried out with smartphone-assisted digital image acquisition and colorimetric analysis. Under optimized experimental conditions, the variation in average grayscale intensity with concentration of nitrite was linear in the range from 0.1 to 10 ppm. The limits of detection and quantitation were 0.12 ppm and 0.35 ppm respectively. The reproducibility, expressed as relative standard deviation was 1.31%. The selectivity of nitrite detection method was determined by performing interference studies with commonly existing co-ions in water, such as bicarbonates, chloride and sulphate. The paper-based sensor was successfully applied for estimation of nitrite in actual water samples and showed high recoveries in the range of 83.5–109%. The results were in good agreement with those obtained using spectrophotometry. The developed paper-based sensor method, by virtue of its simplicity, ease of fabrication and use, could be readily extended for detection of multiple analytes in resource-limited settings. [ABSTRACT FROM AUTHOR]

The paper microzones method (PMZs) is a green chemical method that uses the principle of the three primary colors of red, green and blue (RGB) to detect the water quality of the droplets on white paper. However, this method is rarely used in the performance evaluation of photocatalysts. The paper details the first use of paper microzones utilized in the evaluation of photocatalyst performance. A sol-gel method was used to prepare molecularly imprinted modified TiO 2 photocatalysts for the treatment of different wastewaters, and characterized the catalysts using XRD and several other methods. The reliability of PMZs on the evaluation of photocatalytic activity and selectivity was also analyzed. The following results were obtained: EP-TiO 2 catalysts (EP, ethyl paraben, the imprinting molecule) with different S doping levels were synthesized using a one-step sol-gel method, and the best S doping ratio was found to be n(Ti):n(S) 3:1. S-EP-TiO 2 was found to be 100% anatase and showed excellent photocatalytic performance, while the PMZs method accurately determined changes in RGB levels for the photocatalytic degradation process of pollutants using S-EP-TiO 2 as the photocatalyst. A photocatalytic kinetic analysis showed the PMZs method was quite suitable for the evaluation of photocatalyst activity, but the evaluation of selectivity needs improvement. This method is a promising green chemistry way to evaluate photocatalyst performance and the rapid detection of outdoor sewage water quality. [Display omitted] • Innovative application of Paper microzones in the evaluation of photocatalytic performance. • Paper microzones method is compared with the traditional spectroscopic method. • Simple operation and green chemistry for environmental research. [ABSTRACT FROM AUTHOR]

Titanium dioxide nanoparticles (TiO 2 NPs) are becoming more and more renowned as biocompatible nanomaterials with diverse biological functions. In the present study, the aqueous extract of tea residue (tea filtered waste powder) was used to synthesize the TiO 2 NPs and treated for effluent bioremediations. Maximum absorption in the UV–Vis spectrum of the TiO 2 NPs was seen at 358 nm, and the XRD pattern reveals peaks at 2 h values of 25.78, 38.24, 47.98, 54.76, 55.32, 62.64, 69.05, 70.15, 75.24, and 83.59 that may be indexed to the (101), (004), (200), (105), (211), (204), (116), (220), (215) and (303). The FT-IR spectra of TiO 2 NPs showed a peak at 3420, 2925, 1621, 1382, 1098, and 687 cm-1. The spherical form and size were disclosed by FE-SEM analyses, and the EDAX pattern verified the purity of the TiO 2 NPs. The average particles size of the TiO 2 NPs was 32 nm. The photodegradation of paper mill waste water is significantly deteriorated up to 99.08% for 600 min, but textile waste water is degraded up to 98.06% for the same duration. Furthermore, we reported that TiO 2 NPs may rapidly breakdown industrially hazardous effluents when exposed to sunshine. Overall, this new, straightforward, and environmentally beneficial strategy may be of interest to the management of efficient degradation of dye solutions in the polluted regions. • Biofabricated of TiO 2 NPs is using Tea residue for the first time. • Biofabricated TiO 2 NPs have Crystalline, Uniform, Spherical and monodispersed nanoparticles. The average size of the particle are 24 nm. • The biofabricated TiO 2 NPs have shown excellent photocatalytic applications. [ABSTRACT FROM AUTHOR]

Paper–TiO 2 –Ag 2 O floating photocatalysts were produced under mild condition and their photocatalytic activity for the degradation of aromatic amine under sunlight stimulant was investigated. Characterizations by Raman, XRD, XPS, DRS and PL confirmed the presence of TiO 2 and Ag 2 O, and the morphology of the appended TiO 2 /Ag 2 O layer was probed by FE-SEM. The photocatalytic activity of the prepared samples was investigated by the degradation of aniline (AN) in water under simulated sun-light illumination and constrained conditions, i.e. non-stirring and non-oxygenation. The presence of Ag 2 O combined with TiO 2 was shown to improve the resistance of paper to bacteria attack, thus increasing the durability of the photocatalyst. Thanks to its hydrophobic character, the paper–TiO 2 –Ag 2 O NPs can be employed as useful floating photocatalyst and can be reused in continuous cycles. • Paper–TiO 2 decorated with Ag 2 O nanoparticles was prepared by a facile method. •Generation of TiO 2 anatase and Ag 2 O phases was confirmed by XRD, Raman and XPS. •Paper–TiO 2 –Ag 2 O exhibits excellent photodegradation activity toward of aniline. •Paper–TiO 2 –Ag 2 O displays good antibacterial activity against E. Coli under sunlight. [ABSTRACT FROM AUTHOR]

Household garbage rooms release abundant bioaerosols and are an important source of pathogens; however, information on the distribution and survival patterns of pathogens in different waste components is limited. In this study, a culture method and 16S rRNA high-throughput sequencing were used to determine bacterial communities, culturable pathogens, and human bacterial pathogens (HBPs). The results showed that abundant culturable bacteria were detected in all waste types, and a large number of S. aureus was detected on the surface of recyclable wastes, whereas S. aureus , total coliforms, Salmonella , Enterococcus , and hemolytic bacteria were detected in food waste and other waste. The activities of these detected pathogenic bacteria decreased after 24 h of storage but re-activated within one week. Factors affecting the emergence of pathogens varied with different waste components. Sequencing results showed that Pseudomonas , Acinetobacter, and Burkholderia were abundant in the waste samples, whereas Achromobacter , Exiguobacteriums, Bordetella , and Corynebacterium were the primary pathogens in the bioaerosol and wall attachment. The results of traceability analysis showed that bioaerosol microbes were mainly derived from raw kitchen waste (5.98%) and plastic and paper contaminated with food waste (19.93%) in garbage rooms. In addition, bioaerosols were the main source of microflora in the wall attachment, which possessed high HBP diversity and required more attention. These findings will help in understanding the microbial hazards in different waste components and provide guidance for the control and risk reduction of bioaerosols during waste management and recycling. [Display omitted] • Abundant Staphylococcus aureus were detected on the surface of recyclable wastes. • Diverse pathogenic bacteria were detected in food wastes and other wastes. • The activities of pathogens decreased after 24 h but re-activated within one week. • Abundant and diverse human bacterial pathogens were detected in the wall attachment. • Raw kitchen waste and contaminated plastic and paper were main sources of bioaerosol. [ABSTRACT FROM AUTHOR]

Environmental monitoring of mercury (Hg2+) ions has become increasingly important as a result of their detrimental effects on biological organisms at all levels. To recognize toxic metal ions, utmost effort has been devoted to developing new materials that are highly selective, ultra-sensitive, and provide rapid response. In this context, a new chemosensor, 2-imino [N - (N-amido phenyl)]-6-methoxy-3-carbethoxy quinoline (L), has been synthesized by combining 2-formyl-6-methoxy-3-carbethoxy quinoline and benzhydrazide and it has been extensively characterized by NMR, FTIR, ESI-Mass and SCXRD analysis. Probe L has excellent specificity and sensitivity toward Hg2+ ions in semi-aqueous solutions, with a detection limit of 0.185 μM, regardless of the presence of other interfering cations. Chromogenic behavior was demonstrated by the L when it changed the color of the solution from colorless to light yellow, a change that can be observed visually. The probe L forms a 1:1 stochiometric complex with an estimated association constant (K a) of 6.74 × 104 M−1. The 1H NMR change and density functional theory calculations were analyzed to improve our understanding of the sensing mechanism. Also, an inexpensive and simple paper-based test kit has been developed for the on-site detection of mercury ions in water samples. • Quinoline Schiff base probe (L) was designed and synthesized as a colorimetry sensor for Hg2+ ions. • Probe L showed highly selective towards Hg2+ ions with a LOD of 0.185 μM. • Probe L forms a 1:1 stochiometric complex with a binding constant of 6.74 × 104 M−1. • The paper-based test kit has been developed for detecting mercury ions. [ABSTRACT FROM AUTHOR]

Chlorinated paraffins (CPs) are hazardous to humans, and dietary intake acts as the primary pathway for human exposure to CPs. Takeout food is popular worldwide, but the presence of CPs in takeout food and its packaging is unclear. In this study, the concentrations and distributions of short- and median-chain CPs (SCCPs and MCCPs, respectively) were measured in 97 samples of four categories of takeout food and 33 samples of three types of takeout packaging. The SCCP and MCCP median concentrations for the takeout food samples were 248 and 339, 77.2 and 98.2, 118 and 258, 42.9 and 64.4 ng/g wet weight in meat, starch, half meat/half starch, and vegetables, respectively. Takeout food contained higher concentrations of SCCPs than MCCPs. The dominant SCCP and MCCP congener groups in takeout food were C 10 Cl 6–7 and C 14 Cl 7–8 , respectively. The CP concentrations in takeout food were lower than those in packaging. The SCCP and MCCP median concentrations, respectively, in packaging were 9750 and 245 ng/g in polypropylene, 2830 and 135 ng/g in paper, and 2060 and 119 ng/g in aluminum foil. The concentrations of SCCPs and MCCPs were comparable in aluminum foil, whereas the concentrations of SCCPs were higher than those of MCCPs in polypropylene and paper. Correlations between CP concentrations in the takeout food and packaging indicated that CPs in packaging were potentially an important source of CPs in the takeout food. A dietary exposure risk assessment showed the takeout food posed a low risk for human exposure to CPs; however, high-frequency consumption may pose a health risk. This study clarified the current contamination situation in takeout food in Beijing, China. The resulting data could be used to prevent human exposure to CPs through dietary intake and to facilitate the market's control over the quality of takeout food. • Chlorinated paraffin (CP) concentrations are highest in animal-origin takeout food. • CP concentrations are highest in polypropylene and lowest in aluminum foil. • Shorter carbon chain and lower chlorination CPs are dominant in food and packaging. • CPs in packaging are a potential source for CPs in takeout food. • The human exposure risk to CPs through takeout food intake is low. [ABSTRACT FROM AUTHOR]

Environmental pollution is a growing concern, particularly the impact of sewage treatment gas on the atmosphere's greenhouse effect. Efficient sewage resource recycling is crucial to achieving carbon neutrality. The bacteria-algae symbiotic sewage treatment system combines wastewater treatment, carbon dioxide fixation, and biomass energy recovery to achieve the goal of carbon neutrality, environmental protection, and the transformation of high-value added products. This paper presents the construction of a sequencing batch photobiological reaction system that utilizes a microbial-algae symbiotic relationship. The system was used to analyze the degradation effects of sCOD, TN, AN, and TP in anaerobic digestion wastewater by varying the microbial-algae ratios. Additionally, changes in the microbial community were analyzed to explore the system's potential for reducing carbon emissions. The study's findings indicate that: 1)When the ratio of bacteria to algae was 2:3, the removal rates of TN, AN, sCOD, and TP were 81.38%, 94.28%, 75.33%, and 96.56%. 2)Changing the ratio of bacteria to algae would affect the bacterial concentration in the mixed system, but not the bacterial community structure. The results indicate that a ratio of 2:3 enhances the removal of pollutants by bacteria and algae symbionts.3) Under the context of carbon neutralization, this paper investigates the reduction of carbon emissions in ADE treated by bacteria-algae symbiosis at the optimal bacteria to algae ratio. The experimental process can reduce 177.03 mg CO 2 compared to complete nutrient consumption treatment, which is equivalent to a reduction of 355.08 g CO 2 per 1 m3 of ADE. For full anaerobic treatment, this experimental process can reduce 228.35 mg of CO 2 equivalent CH 4 , which translates to a reduction of 456.71 g of CO 2 equivalent CH 4 per 1 m3 of ADE. • Optimize the symbiotic system of bacteria and algae in anaerobic digestion wastewater treatment. • Determine the best ratio of bacteria to algae. • Low carbon emissions during the symbiotic treatment of bacteria and algae. [ABSTRACT FROM AUTHOR]

Although studies dealing with adsorption/desorption (and/or retention/release) of pollutants present in environmental compartments is a classical field of research, recent papers are focusing on some weak points of investigations and publications within the area. In addition, an increasing number of works are being published related to new possibilities and alternatives in this kind of research works, many of them in relation to the use of artificial intelligence (AI). Considering the existence of eventual controversies, eventual mistakes, and the convenience of suggesting alternatives to go ahead in the future, in this work, after taking into account some relevant publications in the previous literature, a simple workflow is proposed as a kind of protocol to revise successive steps that could guide the direction to follow when programing research dealing with the retention/release of pollutants in soils and sorbent materials. [Display omitted] • Recent papers show weak points of publications on pollutants adsorption/desorption. • Increasing works on the use of artificial intelligence in this kind of research. • A protocol is proposed to guide programing research on pollutants retention/release. [ABSTRACT FROM AUTHOR]

Supercritical water oxidation (SCWO) has been regarded as a new and efficient technology for the harmless treatment and energy utilization of organic wastes, resulting in the quickly homogeneous oxidation between organics and oxidizers and the former being wholly degraded into small environment-friendly green molecules such as H 2 O and N 2 and inorganic salts. This paper systematically analyzed the influencing behavior and mechanisms of the reaction factors, such as temperature, pressure, residence time, oxidant type, oxidation coefficient, and the concentration and pH values of the raw material, on the treatment effect of organic wastes. For most organic wastes, the SCWO conditions at 550 °C with a residence time of 1min and an oxidation coefficient of 100% can meet the removal rate of more than 99%. To further enhance the degradation rate of organics, the principles, implementation cases, and related equipment components of general enhancement technologies of supercritical water oxidation were discussed, such as fractional oxygen injection, auxiliary fuel co-oxidation, and hydrothermal flame-assisted degradation. This paper proposes a novel supercritical flame-assisted oxidation process in which the reactor performs preheating, corrosion protection, and desalination functions. The use of additive-enhanced oxidation, segmented oxidation, and supercritical hydrothermal flame-assisted oxidation has achieved good results in the complicated treatment process of brutal degradation of organic matter. Figure Schematics of supercritical water oxidation flowchart and focused process enhancement perspectives. [Display omitted] [ABSTRACT FROM AUTHOR]

A novel multimode colorimetric and fluorescent chemosensor was developed using an 8-hydroxy quinoline carbaldehyde Schiff base with a quinoline hydrazide probe (E)-2-((2-(quinolin-2-yl)hydrazineylidene)methyl)quinolin-8-ol (L). NMR (1H &13C), FTIR, and HR-mass spectral characterization techniques confirmed the probe L structural conformation. As Probe L contacts Pb2+ ions, a color change and turn-off emission can be visually detected in EtOH:H 2 O (1:1, v/v, pH = 7.21) medium. The probe displays a good emission at 440 nm due to the combined ESIPT and ICT process. The Pb2+ ion interacts with the probe and selectively quenches fluorescence by inhibiting ESIPT and >C N- isomerization. As per Job's plot, L-Pb 2+ complex formation occurred in a 1:1 stoichiometric ratio, with association constant (K a) and quenching constant (K sv) estimated at 1.52 × 105 M−1 and 4.12 × 105 M, respectively. The detection limits of Pb2+ by spectrophotometric and spectrofluorometric were 1.99 μM (41 ppb) and 23.4 nM (485 ppt), respectively. Additionally, the test paper kit and RGB tool were used to monitor the color changes of L with Pb2+ and the LOD was found to be 5.99 μM (125 ppb). Its recognition mechanism has been verified by 1H NMR, ESI-mass, and theoretical studies. [Display omitted] • Quinoline-Quinoline based probe (L) was Synthesized and Characterized by NMR, IR, and Mass. • Probe L shows visually detectable color change with Pb2+ via turn-off emission. • The LOD of Pb2+ by spectrophotometric and spectrofluorometric were 41 ppb and 485 ppt, respectively. • Used smartphone RGB tool and test paper kit for real-time Pb2+ ion detection. [ABSTRACT FROM AUTHOR]

Constructed wetlands (CWs) are a pollutant treatment design inspired by natural wetlands and are widely utilized for the removal of common pollutants. The research focus lies in the circulation of manganese (Mn) in the environment to enhance pollutant removal within CWs. This paper provides a comprehensive review of recent advancements in understanding the role and effects of Mn in chemical weapons, based on literature retrieval from 2002 to 2021. Ecological risk assessment and heavy metals within CWs emerge as current areas of research interest. Mn sources within CWs primarily include natural deposition, heavy metal wastewater, and intentional addition. The cycling between Mn(II) and Mn(IV) facilitates enhanced wastewater treatment within CWs. Moreover, employing a Mn matrix proves effective in reducing ammonia nitrogen wastewater, organic pollutants, as well as heavy metals such as Cd and Pb, thereby addressing complex pollution challenges practically. To comprehensively analyze influencing factors on the system's performance, both internal factors (biological species, design parameters, pH levels, etc.) and external factors (seasonal climate variations, precipitation patterns, ultraviolet radiation exposure, etc.) were discussed. Among these factors, microorganisms, pollutants, and temperature are the most important influencing factors, which emphasizes the importance of these factors for wetland operation. Lastly, this paper delves into plant absorption of Mn along with coping strategies employed by plants when faced with Mn poisoning or deficiency scenarios. When utilizing Mn for the regulation of constructed wetlands, it is crucial to consider the tolerance levels of associated plant species. Furthermore, the study predicts future research hotspots encompass high-efficiency catalysis techniques, matrix-filling approaches, and preparation of resource utilization methods involving Mn nanomaterials. [Display omitted] [ABSTRACT FROM AUTHOR]

The presence of lignin along with other pollutants makes effluent more complex when it is discharged from Pulp and paper mills. The present study investigates the use of biofilm-forming bacteria isolated from pulp paper mill effluent contaminated sites (PPMECSs) for lignin degradation. Isolated biofilm-forming and lignin-degrading bacteria were identified as Bacillus subtilis , Enterobacter cancerogenus, and Bacillus licheniformis by 16S rRNA gene sequencing. Thin liquid chromatography (TLC) analysis showed that the consortium of bacteria produced acyl-homoserine lactone (AHL) as quorum sensing molecules and extracellular polymeric substances (EPS) that protect the bacterial consortium under unfavorable conditions. The potential consortium was able to reduce lignin (900 ppm) by 73% after 8 days of incubation in a minimal salt medium containing kraft lignin and glucose at pH 7.0 and 37 °C as compared to individual strains. The degradation by-products were identified as amides, alcohols, and acids. The major organic pollutants in the effluent were reduced after treatment of the constructed consortium, thus confirming active biotransformation and biodegradation of the lignin. Microscopic examination also indicated the presence of lignin induced biofilm formation. Hence, the constructed biofilm-forming bacterial consortia based on quorum sensing offered a sustainable and effective solution to treat lignin-containing complex pollutants. • Quorum sensing (QS) induced biofilm formation. • Biofilm formation was maximum by bacterial consortium. • Lignin (900 ppm) reduction was maximum 73% by consortium. • Treatment of lignin by QS based biofilm lead an effective approach to treat effluent. [ABSTRACT FROM AUTHOR]

Both the environment and human health have suffered as a result of excessive and irrational pesticide use. The human body is vulnerable to a wide range of illnesses brought on by prolonged exposure to or intake of food contaminated with pesticide residues, including immunological and hormonal abnormalities and the development of certain tumors. Sensors based on nanoparticles stand out from more conventional spectrophotometry analytical methods due to their low detection limits, high sensitivity, and ease of use; that is why the demand for simple, fast, and less expensive sensing methods increases daily and presents myriad uses. Such demands are fulfilled by employing paper-based analytical devices having intrinsic properties. The presented work reports an on-site, easy-to-handle, and disposable paper-based sensing device for performing fast screening along with readout from a smartphone. The fabricated device utilizes luminescent silica quantum dots, immobilized into a paper cellulose matrix, and the resonance energy transfer phenomenon is employed. The silica quantum dots probes were fabricated from citric acid and, by undergoing physical adsorption, were confined on the nitrocellulose substrate in small wax-traced spots. The silica quantum dots were excited by smartphone ultraviolet LED, acting as an energy source and for capturing the image. The obtained LOD is 0.054 μM, and the coefficient of variation is less than 6.1%, comparable to the result obtained by UV–Visible and fluorometric analysis under similar experimental conditions. In addition, high reproducibility (≥9.8%) and high recovery ≥90% were obtained in spiked blood samples. The fabricated sensor sensitively detected pesticides giving a LOD of 2.5 ppm along with the development of yellow color within a short period of 5 min. The sensor functions well when sophisticated instrumentation is not accessible. The presented work shows the potential of the paper strip for the on-site detection of pesticides in biological and environmental samples. • The easy-to-handle, less expensive and disposable paper-based sensing device for the rapid on-site detection of pesticides is fabricated. • The luminescent silica quantum dots were immobilized in detection zones fabricated on paper for detection. • High reproducibility (≥9.8%) and high recovery ≥90% were obtained in real samples containing chlorpyrifos, lambda, and bifenthrine. • The fabricated nanosensors sensitively detected pesticides giving a LOD of 2.5 ppm. • The present method is an effective approach for analytical applications. [ABSTRACT FROM AUTHOR]

Economic transformation and development serve as effective strategies for resource-based regions to avoid the "resource curse." By optimizing industrial structure and enhancing energy efficiency through government macro-regulation, these regions can achieve sustainable and environment-friendly growth. The general equilibrium model is widely employed to assess the effectiveness of economic transformation and development. In this study, we constructed a provincial social accounting matrix based on macro data from Shanxi, China, to examine the impact of different environmental protection tax rates on the macro economy, industrial structure, and energy consumption. The findings reveal that the implementation of environmental protection tax has successfully optimized the industrial structure and improved energy utilization efficiency. However, it has also led to a slight decline in total output. Hence, it is imperative to establish a more balanced and reasonable environmental protection tax rate to further promote economic transformation and development in resource-based areas. Consequently, this paper puts forth policy recommendations aimed at achieving a harmonious balance between ecological preservation and economic progress in resource-based regions, ultimately enhancing the overall quality of economic development in such areas. • Economic transformation and development are effective ways for resource-based regions to avoid the "resource curse". • This paper is based on macro data from Shanxi, and constructs a provincial social accounting matrix to study the impact of different environmental protection tax rates on macroeconomic, industrial structure, and energy consumption. • Setting a reasonable environmental protection tax rate can promote the economic transformation and development of resource-based areas [ABSTRACT FROM AUTHOR]

The Nordic countries (Denmark, Finland, Iceland, Norway, and Sweden) have effectively kept lower antibiotic-resistant bacterial (ARB) pathogen rates than many other countries. However, in recent years, these five countries have encountered a rise in ARB cases and challenges in treating infections due to the growing prevalence of ARB pathogens. Wastewater-based surveillance (WBS) is a valuable supplement to clinical methods for ARB surveillance, but there is a lack of comprehensive understanding of WBS application for ARB in the Nordic countries. This review aims to compile the latest state-of-the-art developments in WBS for ARB monitoring in the Nordic countries and compare them with clinical surveillance practices. After reviewing 1480 papers from the primary search, 54 were found relevant, and 15 additional WBS-related papers were included. Among 69 studies analyzed, 42 dedicated clinical epidemiology, while 27 focused on wastewater monitoring. The PRISMA review of the literature revealed that Nordic countries focus on four major WBS objectives of ARB: assessing ARB in the human population, identifying ARB evading wastewater treatment, quantifying removal rates, and evaluating potential ARB evolution during the treatment process. In both clinical and wastewater contexts, the most studied targets were pathogens producing carbapenemase and extended-spectrum beta-lactamase (ESBL), primarily Escherichia coli and Klebsiella spp. However, vancomycin-resistant Enterococcus (VRE) and methicillin-resistant Staphylococcus aureus (MRSA) have received more attention in clinical epidemiology than in wastewater studies, probably due to their lower detection rates in wastewater. Clinical surveillance has mostly used culturing, antibiotic susceptibility testing, and genotyping, but WBS employed PCR-based and metagenomics alongside culture-based techniques. Imported cases resulting from international travel and hospitalization abroad appear to have frequently contributed to the rise in ARB pathogen cases in these countries. The many similarities between the Nordic countries (e.g., knowledge exchange practices, antibiotic usage patterns, and the current ARB landscape) could facilitate collaborative efforts in developing and implementing WBS for ARB in population-level screening. [Display omitted] • The Nordic countries are facing a growing problem of antibiotic-resistant pathogens. • Travel abroad and overseas hospitalization frequently lead to imported cases. • Wastewater monitoring cost-effectively gathers population-level data. • Nordic countries can harmonize wastewater surveillance for antibiotic-resistant pathogens. [ABSTRACT FROM AUTHOR]

Exploring the effect of local government multi-objective competition on the transfer of polluting industries is of great practical significance for promoting the high-quality development in the Yangtze River Economic Belt. This paper adopted the extended shift-share analysis method to measure the scale of inter-provincial transfer of polluting industries in the Yangtze River Economic Belt from 2008 to 2020. Considering local governments' economic, innovation, talent and environmental protection competition, the paper examined the effects of local government multi-objective competition on the transfer of polluting industries in the region, and tested its spatial spillover effects. The results showed that: 1. Different competitions had different effects on the transfer of polluting industries. Economic competition intensified the transfer of polluting industries, while talent, innovation, and environmental protection competition all restrained it, among which environmental protection competition had the strongest restraining effect. 2. Compared with the transfer of polluting industries, the direction of economic competition and environmental protection competition on the transfer of industries did not change, but the degree of influence was reduced, talent competition instead promoted industrial transfer of the research region to some extent. 3. From the basin level, government competition in the upstream region more obviously intensified the transfer of polluting industries; while from the economic scale level, the restraining effect of government competition in the developed region on the transfer of polluting industries was much stronger. 4. Both innovation and environmental protection competition had positive spatial spillover effects. Therefore, it is necessary to optimize the promotion and assessment mechanism of local officials, adopt differentiated competitive constraint mechanisms in accordance with local conditions, guide local governments to transform their development concepts, promote the sharing and common use of technological innovations, and promote the orderly transfer of industries in the Yangtze River Economic Belt. • Government economic competition intensified the transfer of polluting industries. • Talent, innovation, and environmental protection competition had restraining effect. • Environmental protection competition had the strongest restraining effect. • The impact of government competition had regional and scale heterogeneity. • Innovation and environmental protection competition had spatial spillover effect. [ABSTRACT FROM AUTHOR]

"Carbon peaking and carbon neutralization" is an important measure to promote China's ecological and environmental protection and high-quality economic development, and the innovation and application of green technology are critical factors in achieving the "double carbon" goal. Based on the number of citations of green patents of listed enterprises in 30 provinces in China from 2011 to 2020, this paper uses GGDP to replace traditional GDP and calculate carbon emission intensity. Based on the relevant panel data at the provincial level, this paper constructs a spatial Durbin model to analyze the impact mechanism of whether the promotion and application of green technologies promote regional carbon emission reduction. The specific research results are as follows: (1) Through regression of the core explanatory variables with a one-stage lag, it is verified that the promotion and application of green technology has a significant positive promoting effect on regional carbon emission reduction, and there are significant spatial spillover effects and "learning by doing" effects. (2) In the part of heterogeneity test, the impact of green technology promotion and application on carbon emission reduction presents apparent regional heterogeneity and factor endowment heterogeneity. (3) The mediating effect test verifies the mediating effect of energy structure and industrial structure on the influence of green technology promotion and application on regional carbon emission reduction. (4) In the part moderating effect test, it is verified that marketization level and new infrastructure construction have a positive moderating effect in their influencing process, financial development, and government support will weaken the influence of green technology promotion and application on carbon emission reduction effect, and human capital level has a nonlinear regulating effect. The research conclusions of this paper provide necessary enlightenment for the coordination and unification of China's economic transition to innovation-driven and green and low-carbon development. • The impact of GTPA on reduction in China was analyzed from a macro perspective. • The GS and FDL plays a negative moderating role in the influence process. • The HCL plays a nonlinear moderating role in the influence process. • The GTPA can significantly reduce regional CEI except in Western China. • Regions with high EDL and high GTI have better carbon reduction effects of GTPA. [ABSTRACT FROM AUTHOR]

The current methods of treating organic waste suffer from limited resource usage and low product value. Research and development of value-added products emerges as an unavoidable trend for future growth. Electro-fermentation (EF) is a technique employed to stimulate cell proliferation, expedite microbial metabolism, and enhance the production of value-added products by administering minute voltages or currents in the fermentation system. This method represents a novel research direction lying at the crossroads of electrochemistry and biology. This article documents the current progress of EF for a range of value-added products, including gaseous fuels, organic acids, and other organics. It also presents novel value-added products, such as 1,3-propanediol, 3-hydroxypropionic acid, succinic acid, acrylic acid, and lysine. The latest research trends suggest a focus on EF for cogeneration of value-added products, studying microbial community structure and electroactive bacteria, exploring electron transfer mechanisms in EF systems, developing effective methods for nutrient recovery of nitrogen and phosphorus, optimizing EF conditions, and utilizing biosensors and artificial neural networks in this area. In this paper, an analysis is conducted on the challenges that currently exist regarding the selection of conductive materials, optimization of electrode materials, and development of bioelectrochemical system (BES) coupling processes in EF systems. The aim is to provide a reference for the development of more efficient, advanced, and value-added EF technologies. Overall, this paper aims to provide references and ideas for the development of more efficient and advanced EF technology. [ABSTRACT FROM AUTHOR]

Benzene is a commonly used industrial chemical that is a significant environmental pollutant. Occupational health specialists and industrial toxicologists are concerned with determining the exact amount of exposure to chemicals in the workplace. There are two main approaches to assess chemical exposure; air monitoring and biological monitoring. Air monitoring has limitations, which biological monitoring overcomes and could be used as a supplement to it. However, there are several factors that influence biological monitoring results. It would be possible to assess exposure more accurately if these factors were taken into account. This study aimed to review published papers for recognizing and discussing parameters that could affect benzene biological monitoring. Two types of effects can be distinguished: positive and negative effects. Factors causing positive effects will increase the metabolite concentration in urine more than expected. Furthermore, the parameters that decrease the urinary metabolite level were referred to as false negatives. From the papers, sixteen influential factors were extracted that might affect benzene biological monitoring results. Identified factors were clarified in terms of their nature and mechanism of action. It is also important to note that some factors influence the quantity and quality of the influence of other factors. As a result of this study, a decision-making protocol was developed for interpreting the final results of benzene biological monitoring. [ABSTRACT FROM AUTHOR]

Enzymatic pretreatment is an effective method which can improve the anaerobic digestion (AD) efficiency of household food waste (HFW). As an alternative to expensive commercial enzymes, mixed enzymes (MEs) produced in situ from HFW by solid-state fermentation (SSF) can greatly promote the hydrolysis rate of HFW and achieve advanced anaerobic digestion (AAD) economically sustainable. In this paper, strategies for improving the efficiency of the enzyme-production process and the abundance of MEs are briefly discussed, including SSF, fungal co-cultivation, and stepwise fermentation. The feasibility of using HFW as an applicable substrate for producing MEs (amylase, protease, and lignocellulose-degrading enzymes) and its potential advantages in HFW anaerobic digestion are comprehensively illustrated. Based on the findings, an integrated AAD process of HFW pretreated with MEs produced in situ was proposed to maximise bioenergy recovery. The mass balance results showed that the total volatile solids removal rate could reach 98.56%. Moreover, the net energy output could reach 2168.62 MJ/t HFW, which is 9.79% higher than that without in situ -produced MEs and pretreatment. Finally, perspectives for further study are presented. [Display omitted] [ABSTRACT FROM AUTHOR]

China's carbon emission trading policy plays a crucial role in achieving both its "3060" dual carbon objectives and the United Nations Sustainable Development Goal 13 (SDG 13) on climate action. The policy's effectiveness in reducing pollution and mitigating carbon emissions holds significant importance. This paper investigated whether China's carbon emission trading policy affects pollution reduction (PM 2.5 and SO 2) and carbon mitigation (CO 2) in pilot regions, using panel data from 30 provinces and municipalities in China from 2005 to 2019 and employing a multi-period difference-in-differences (DID) model. Furthermore, it analyzed the heterogeneity of carbon market mechanisms and regional variations. Finally, it examined the governance pathways for pollution reduction and carbon mitigation from a holistic perspective. The results indicate that: (1) China's carbon emission trading policy has reduced CO 2 emissions by 18% and SO 2 emissions by 36% in pilot areas, with an immediate impact on the "carbon mitigation" effect, while the "pollution reduction" effect exhibits a time lag. (2) Higher carbon trading prices lead to stronger "carbon mitigation" effect, and larger carbon market scales are associated with greater "pollution reduction" effects on PM 2.5. Governance effects on pollution reduction and carbon mitigation vary among pilot regions: Carbon markets of Beijing, Chongqing, Shanghai, and Tianjin show significant governance effects in both "pollution reduction" and "carbon mitigation", whereas Guangdong's carbon market exhibits only a "pollution reduction" effect, and Hubei's carbon market demonstrates only a "carbon mitigation" effect. (3) Currently, China's carbon emission trading policy achieves pollution reduction and carbon mitigation through "process management" and "end-of-pipe treatment". This study could provide empirical insights and policy implications for pollution reduction and carbon mitigation, as well as for the development of China's carbon emission trading market. • China's carbon emission trading (CET) policy promotes pollution reduction and carbon mitigation. • Higher carbon trading prices lead to stronger "carbon mitigation" effect. • Larger carbon market scales bring greater "pollution reduction" effects on PM 2.5. • Regional heterogeneity exists on pollution reduction and carbon mitigation. [ABSTRACT FROM AUTHOR]

In developing economies, the decarbonization of energy sector has become a global priority for sustainable and cleaner energy system. Biohydrogen production from renewable sources of waste biomass is a good source of energy incentive that reduces the pollution. Biohydrogen has a high calorific value and emits no emissions, producing both energy security and environmental sustainability. Biohydrogen production technologies have become one of the main renewable sources of energy. The present paper entails the role of biohydrogen recovered from waste biomasses like agricultural waste (AW), organic fraction of municipal solid waste (OFMSW), food processing industrial waste (FPIW), and sewage sludge (SS) as a promising solution. The main sources of increasing yield percentage of biohydrogen generation from waste feedstock using different technologies, and process parameters are also emphasized in this review. The production paths for biohydrogen are presented in this review article, and because of advancements in R and D, biohydrogen has gained viability as a biofuel for the future and discusses potential applications in power generation, transportation, and industrial processes, emphasizing the versatility and potential for integration into existing energy infrastructure. The investigation of different biochemical technologies and methods for producing biohydrogen, including anaerobic digestion (AD), dark fermentation (DF), photo fermentation (PF), and integrated dark–photo fermentation (IDPF), has been overviewed. This analysis also discusses future research, investment, and sustainable energy options transitioning towards a low-carbon future, as well as potential problems, economic impediments, and policy-related issues with the deployment of biohydrogen in emerging nations. [Display omitted] [ABSTRACT FROM AUTHOR]

This research paper presents a direct approach to synthesize AgNPs deposited on polyoxometalate/ZIF-8 on-site (referred to as AgNPS@PW@ZIF-8) to develop a highly efficient photocatalyst in the water treatment. Phosphotungestic acid (PW) serves a multi-purpose in this context: it acts as a bridge layer between AgNPs and Zeolitic Imidazolate Framework-8 (ZIF-8), a local reducing agent, and a catalyst for electron transfer during the photocatalysis process. A comprehensive characterization of the resulting nanostructure was performed utilizing an array of techniques, such as XRD, FTIR, EDX, TEM, BET, Raman, and TGA. The nanostructure that was created exhibited effective removal of Congo red at different pH levels via a combination of simultaneous adsorption and photocatalysis. After 60 min at pH 7, the dye molecules were completely eliminated in the presence of 0.5 g/L AgNPS@PW@ZIF-8 at room temperature. The charge transfer can be facilitated by the PW bridge layer connecting AgNPs and ZIF-8, owing to the photoactive characteristics and strong electron transfer capabilities of PW molecules. Strong electron transferability of PW between Ag nanoparticles and ZIF-8 facilitates charge transfer and significantly improves the photocatalytic performance of ZIF-8. Moreover, the nanostructure demonstrated great structural stability and recyclability, sustaining a high efficiency of removal throughout five consecutive cycles through the implementation of a simple procedure. Widespread applications of the developed nanostructure in aquatic environments for adsorption and photocatalytic reactions are possible. • AgNPS@PW@ZIF-8 exhibited highly efficient adsorbent/photocatalyst in CR removal. • Charge transfer can be facilitated by the PW bridge layer connecting AgNPs and ZIF-8. • The nanostructure showed high structural stability and recyclability. [ABSTRACT FROM AUTHOR]

Water treatment is one of the most important issues for all walks of life around the world. The unique advantages of the solid-state power electronic pulses in water treatment make it attractive and promising in practical applications. The output voltage, rising time, repetition rate, and peak power of output pulses have a significant impact on the effectiveness of water treatment. Especially in pulse electric field treatment and pulse discharge treatment, the pulse with fast rising time achieves the advantage of generating plasma without corona, which can avoid water heating effect and greatly improve the efficiency of the pulse generator. High repetition rate can significantly reduce the peak power requirement of the pulse in water treatment application, making the equipment smaller and improving the power density. Therefore, the study developed a high-voltage high frequency sub-nanosecond pulse power generator (PPG) system for wastewater treatment. It adopts SiC DSRD (Drift Step Recovery Diode) solid-state switches and realize modular design, which can achieve high performance and can be flexible expanded according to the requirements of water treatment capacity. Finally, an expandable high-voltage PPG for water treatment is built. The output parameters of the PPG include output pulse voltage range from 1 to 5.28 kV, rise time <600 ps (20%–90%), repetition up to 1 MHz. The experiment results of PPG application for pulse discharge water treatment is presented. The results indicate that the proposed generator achieves high-efficiency degradation of 4-Chlorophenol (4-CP), which is one of the most common chlorophenol compounds in wastewater. From experiment, the homemade system can degrade 450 mL waste water containing 500 mg/L 4-CP in 35 min, with a degradation rate of 98%. Thereby, the requirement for electric field intensity decreased. Through the further quantitative analysis, the impact of frequency, voltage, and electrode spacing on the degradation effect of 4-CP is confirmed. • The paper presents SiC DSRD-based PPG, with high-voltage and repetition frequency. • The modular design of the trigger stage makes PPG obtain a higher output voltage. • The proposed PPG achieves high-efficiency degradation of 4-Chlorophenol. • Confirm the impact of frequency, voltage, electrode spacing on degradation effect. [ABSTRACT FROM AUTHOR]

Both ultrasound and sludge retention time (SRT) enable the in-situ sludge reduction during wastewater treatment, but the influence of SRT on ultrasonic lysis – cryptic growth is unclear. This paper researched the influence of different SRTs on sludge lysis - cryptic growth using a sequential bio-reactor (SBR), then explained in details the changes of microorganisms in the SBR. The best SRT for sludge reduction was 30 d, and 47.29% reduction in sludge was achieved. The different SRTs changed the organic matter removal in the wastewater, and the removal rate decreased when SRT exceeded 60 d. The size of the sludge particles varied depending on the SRT, with the smallest size at SRT of 10d being 45.6 μm and the largest size at SRT of 90d being 110.0 μm. SEM showed that the sludge surface changed rough at longer SRT. FTIR and XPS showed notable effect in sludge functional group strength at SRT of 30 d. Extracellular polymeric substance (EPS) reduced the most at SRT of 30 d. The microbial communities of sludge varied with the SRT, and the unique main genus at SRT of 5, 15, 30 and 90 d were C10-SB1 A, Lactococcus, Propioniciclava, Lactococcus, respectively. Furthermore, the SRT changed relative abundance of enzymes concerned with metabolism of carbon, nitrogen, and phosphorus. Similarly, SRT changed the metabolic rate, and the metabolic rate of carbon, nitrogen and phosphorus was best at SRT of 30 d. [Display omitted] • Suitable sludge retention time could improve the sludge reduction. • Sludge reduction via ultrasonic lysis cryptic growth was 47.29% at SRT of 30 d. • SRT impacted the microbial community and relative abundance of key genes. • The microbial community had high variable at SRT = 30 and 90 d. [ABSTRACT FROM AUTHOR]

Anaerobic ammonium oxidation has been considered as an environmental-friendly and energy-efficient biological nitrogen removal (BNR) technology. Recently, new reaction pathway for ammonium oxidation under anaerobic condition had been discovered. In addition to nitrite, iron trivalent, sulfate, manganese and electrons from electrode might be potential electron acceptors for ammonium oxidation, which can be coupled to traditional BNR process for wastewater treatment. In this paper, the pathway and mechanism for ammonium oxidation with various electron acceptors under anaerobic condition is studied comprehensively, and the research progress of potentially functional microbes is summarized. The potential application of various electron acceptors for ammonium oxidation in wastewater is addressed, and the N 2 O emission during nitrogen removal is also discussed, which was important greenhouse gas for global climate change. The problems remained unclear for ammonium oxidation by multi-electron acceptors and potential interactions are also discussed in this review. [Display omitted] [ABSTRACT FROM AUTHOR]

A large amount of agricultural waste causes global environmental pollution. Biogas production by microbial pretreatment is an important way to utilize agricultural waste resources. In this study, Sporocytophaga CG-1 (A, cellulolytic strain) was co-cultured with Bacillus clausii HP-1 (B, non-cellulolytic strain) to analyze the effect of pretreatment of rice straw on methanogenic capacity of anaerobic digestion (AD). The results showed that weight loss rate of filter paper of co-culture combination is 53.38%, which is 29.37% higher than that of A. The synergistic effect of B on A can promote its degradation of cellulose. The cumulative methane production rate of the co-culture combination was the highest (93.04 mL/g VS substrate), which was significantly higher than that of A, B and the control group (82.38, 67.28 and 67.70 mL/g VS substrate). Auxiliary bacteria can improve cellulose degradation rate by promoting secondary product metabolism. These results provide data support for the application of co-culture strategies in the field of anaerobic digestion practices. [Display omitted] • Sporocytophaga sp. was first applied to biological pretreatment of rice straw. • Cellulose degrading bacteria co-degrade cellulose with "auxiliary bacteria". • Synergistic effect can significantly promote lignocellulose hydrolysis. • Synergistic effect can significantly increase the cumulative methane production. [ABSTRACT FROM AUTHOR]

Indole-3-acetic acid (IAA) derived from Actinobacteria fermentations on agro-wastes constitutes a safer and low-cost alternative to synthetic IAA. This study aims to select a high IAA-producing Streptomyces -like strain isolated from Lake Oubeira sediments (El Kala, Algeria) for further investigations (i.e., 16S rRNA gene barcoding and process optimization). Subsequently, artificial intelligence-based approaches were employed to maximize IAA bioproduction on spent coffee grounds as high-value-added feedstock. The specificity was the novel application of the Limited-Memory Broyden-Fletcher-Goldfarb-Shanno Box (L-BFGS-B) optimization algorithm. The new strain AW08 was a significant producer of IAA (26.116 ± 0.61 μg/mL) and was identified as Streptomyces rutgersensis by 16S rRNA gene barcoding and phylogenetic inquiry. The empirical data involved the inoculation of AW08 in various cultural conditions according to a four-factor Box Behnken Design matrix (BBD) of Response surface methodology (RSM). The input parameters and regression equation extracted from the RSM-BBD were the basis for implementing and training the L-BFGS-B algorithm. Upon training the model, the optimal conditions suggested by the BBD and L-BFGS-B algorithm were, respectively, L-Trp (X1) = 0.58 %; 0.57 %; T° (X2) = 26.37 °C; 28.19 °C; pH (X3) = 7.75; 8.59; and carbon source (X4) = 30 %; 33.29 %, with the predicted response IAA (Y) = 152.8; 169.18 μg/mL). Our findings emphasize the potential of the multifunctional S. rutgersensis AW08, isolated and reported for the first time in Algeria, as a robust producer of IAA. Validation investigations using the bioprocess parameters provided by the L-BFGS-B and the BBD-RSM models demonstrate the effectiveness of AI-driven optimization in maximizing IAA output by 5.43-fold and 4.2-fold, respectively. This study constitutes the first paper reporting a novel interdisciplinary approach and providing insights into biotechnological advancements. These results support for the first time a reasonable approach for valorizing spent coffee grounds as feedstock for sustainable and economic IAA production from S. rutgersensis AW08. [Display omitted] • Multifunctional Streptomyces rutgersensis AW 08 represents a novel viable source for indole-3-acetic acid. • Spent coffee grounds can substitute laboratory-grade substrates for Streptomyces fermentation. • L-BFGS-B algorithm implementation with RSM-BBD achieves fast and effective bioprocess optimization. • Artificial intelligence-driven approaches increase indole-3-acetic acid yields up to fivefold. [ABSTRACT FROM AUTHOR]

Conventional plastics are inherently difficult to degrade, causing serious plastic pollution. With the development of society, biodegradable plastics (BPs) are considered as an alternative to traditional plastics. However, current research indicated that BPs do not undergo complete degradation in natural environments. Instead, they may convert into biodegradable microplastics (BMPs) at an accelerated rate, thereby posing a significant threat to environment. In this paper, the definition, application, distribution, degradation behaviors, bioaccumulation and biomagnification of BPs were reviewed. And the impacts of BMPs on soil and marine ecosystems, in terms of physicochemical property, nutrient cycling, microorganisms, plants and animals were comprehensively summarized. The effects of combined exposure of BMPs with other pollutants, and the mechanism of ecotoxicity induced by BMPs were also addressed. It was found that BMPs reduced pH, increased DOC content, and disrupted the nitrification of nitrogen cycle in soil ecosystem. The shoot dry weight, pod number and root growth of soil plants, and reproduction and body length of soil animals were inhibited by BMPs. Furthermore, the growth of marine plants, and locomotion, body length and survival of marine animals were suppressed by BMPs. Additionally, the ecotoxicity of combined exposure of BMPs with other pollutants has not been uniformly concluded. Exposure to BMPs induced several types of toxicity, including neurotoxicity, gastrointestinal toxicity, reproductive toxicity, immunotoxicity and genotoxicity. The future calls for heightened attention towards the regulation of the degradation of BPs in the environment, and pursuit of interventions aimed at mitigating their ecotoxicity and potential health risks to human. [ABSTRACT FROM AUTHOR]

As the world struggles with pressing issues like climate change and sustainable development, affecting health outcomes and environmental quality, the Nordic regionsare at the forefront of major global challenges. This paper investigates the role of human capital, renewable energy use, tourism, natural resources, and economic growth in shaping life in the Nordic region i.e., Denmark, Norway, Sweden, Finland, and Iceland).Utilizing panel data spanning from 1990 to 2020, the Driscoll and Kraay standard error (DSK) technique is employed to analyze this intricate interplay. The study reveals that in the Nordic context, sustainable economic growth, bolstered by investments in human capital and the widespread acceptance of renewable energy sources, has been positively associated with increased life expectancies. Furthermore, prudent management of natural resources has helped mitigate adverse health effects related to depletion, maintaining environmental and public health standards. The thriving tourism industry has also been shown to influence lifespan in this region positively. On the contrary, the empirical finding contended that an adverse correlation exists between carbon emissions and LEX. This research underscores the importance of a comprehensive and balanced approach that considers economic development, sustainable development, and public health in pursuing longer and healthier lives, providing valuable insights for policymakers and regions seeking to replicate these positive outcomes.The findings of this study are both conceptually reliable and empirically robust, providing important insights for the formulation of environmental and health policy. • Sustainable economic growth, bolstered by investments in human capital positively increases life expectancies. • Environmental problems account for 23 percent of global mortality. • The study examined the long-run connection between ECG, CEM, NRR, TOU, HUC, REU, and LEX among the Nordic Regions. • Grossman's healthcare model influences health economics, explaining people's choices for a better demand of healthcare services • Cross-sectional Dependency Test, slope homogeneity test (SHT), adopting the Driscoll-Kraay Standardized (DSK) panel estimation approach. [ABSTRACT FROM AUTHOR]

The purpose of the Esteban study was to describe levels of various biomarkers of exposure to several environmental pollutants, including metals and metalloids, among the French population. This paper describes the distribution of concentrations of 28 metals and metalloids in two different populations, and estimates the main determinants of exposure to total arsenic, the sum of inorganic arsenic (iAs) and its two metabolites monomethylarsonic acid (MMA) and dimethylarsinic acid (DMA), cadmium, chromium, copper, mercury and nickel. Esteban is a cross-sectional study conducted between 2014 and 2016 on a random sample of 2503 adults (18–74 years old) and 1104 children (6–17 years old) from the general population. The data collected included biological samples (blood, hair, and urines), socio-demographic characteristics, environmental and occupational exposure, and information on dietary factors and lifestyle. The geometric mean and percentiles of the distribution were estimated for each metal. Multivariate analyses were performed to identify the determinants of exposure using a generalized linear model. Only four metals had a quantification rate below 90% in adults (beryllium, iridium, palladium, and platinum), and three metals in children (beryllium, iridium, and platinum). The concentrations of total arsenic, cadmium, chromium and mercury were higher than those found in most international studies. The determinants significantly associated with exposure were mainly diet and smoking. Esteban provided a nationwide description of 28 metal and metalloid exposure levels for adults (some never measured before) and for the first time in children. The study results highlighted widespread exposure to several metals and metalloids. These results could be used to advocate public health decisions for continued efforts to reduce harmful exposure to toxic metals. The Reference values (RV 95) built from Esteban could also be used to support future government strategies. • First French HBM study describing the distribution of a significant number of metals in a random sample of children. • Widespread exposure to metals has been observed except for beryllium, iridium, palladium, and platinum. • Diet (fish, seafood) and smoking are the mainly determinants positively associated with exposure. • Esteban study made it possible to establish new RV 95 for certain metals in the general population. [ABSTRACT FROM AUTHOR]

Human fertility is impacted by changes in lifestyle and environmental deterioration. To increase human fertility, assisted reproductive technology (ART) has been extensively used around the globe. As early as 2009, the Endocrine Society released its first scientific statement on the potential adverse effects of environmental endocrine-disrupting chemicals (EDCs) on human health and disease development. Chemicals known as phthalates, frequently employed as plasticizers and additives, are common EDCs. Numerous studies have shown that phthalate metabolites in vivo exert estrogen-like or anti-androgenic effects in both humans and animals. They are associated with the progression of a range of diseases, most notably interference with the reproductive process, damage to the placenta, and the initiation of chronic diseases in adulthood. Phthalates are ingested by infertile couples in a variety of ways, including household products, diet, medical treatment, etc. Exposure to phthalates may exacerbate their infertility or poor ART outcomes, however, the available data on phthalate exposure and ART pregnancy outcomes are sparse and contradictory. Therefore, this review conducted a systematic evaluation of 16 papers related to phthalate exposure and ART pregnancy outcomes, to provide more aggregated results, and deepen our understanding of reproductive outcomes in infertile populations with phthalate exposure. [Display omitted] [ABSTRACT FROM AUTHOR]

After the second industrial revolution, social productivity developed rapidly, and the use of fossil fuels such as coal, oil, and natural gas increased greatly in industrial production. The burning of these fossil fuels releases large amounts of greenhouse gases such as CO 2 , which has caused greenhouse effects and global warming. This has endangered the planet's ecological balance and brought many species, including animals and plants, to the brink of extinction. Thus, it is crucial to address this problem urgently. One potential solution is the use of syngas fermentation with microbial cell factories. This process can produce chemicals beneficial to humans, such as ethanol as a fuel while consuming large quantities of harmful gases, CO and CO 2. However, syngas-fermenting microorganisms often face a metabolic energy deficit, resulting in slow cell growth, metabolic disorders, and low product yields. This problem limits the large-scale industrial application of engineered microorganisms. Therefore, it is imperative to address the energy barriers of these microorganisms. This paper provides an overview of the current research progress in addressing energy barriers in bacteria, including the efficient capture of external energy and the regulation of internal energy metabolic flow. Capturing external energy involves summarizing studies on overexpressing natural photosystems and constructing semiartificial photosynthesis systems using photocatalysts. The regulation of internal energy metabolic flows involves two parts: regulating enzymes and metabolic pathways. Finally, the article discusses current challenges and future perspectives, with a focus on achieving both sustainability and profitability in an economical and energy-efficient manner. These advancements can provide a necessary force for the large-scale industrial application of syngas fermentation microbial cell factories. [Display omitted] [ABSTRACT FROM AUTHOR]

In recent years, precision agriculture, driven by scientific monitoring, precise management, and efficient use of agricultural resources, has become the direction for future agricultural development. The precise identification and assessment of phenotypes, which serve as external representations of a crop's growth, development, and genetic characteristics, are crucial for the realization of precision agriculture. Applications surrounding phenotypic indices also provide significant technical support for optimizing crop cultivation management and advancing smart agriculture, contributing to the efficient and high-quality development of precision agriculture.This paper focuses on lettuce and employs common nutritional stress conditions during growth as experimental settings. By collecting RGB images throughout the lettuce's complete growth cycle, we developed a deep learning-based computational model to tackle key issues in the lettuce's growth and precisely identify and assess phenotypic indices. We discovered that some phenotypic indices, including custom ones defined in this study, are representative of the lettuce's growth status. By dynamically monitoring the changes in phenotypic traits during growth, we quantitatively analyzed the accumulation and evolution of phenotypic indices across different growth stages. On this basis, a predictive model for lettuce growth and development was trained.The model incorporates MSE, SSIM, and perceptual loss, significantly enhancing the predictive accuracy of the lettuce growth images and phenotypic indices. The model trained with the reconstructed loss function outperforms the original model, with the SSIM and PSNR improving by 1.33% and 10.32%, respectively. The model also demonstrates high accuracy in predicting lettuce phenotypic indices, with an average error less than 0.55% for geometric indices and less than 1.7% for color and texture indices. Ultimately, it achieves intelligent monitoring and management throughout the lettuce's life cycle, providing technical support for high-quality and efficient lettuce production. • Accurate identification of 45 lettuce phenotypes was performed using images. • Analysis of phenotypes was conducted through dynamic approaches. • A prediction model was constructed using a reconstructed loss function approach. • Precise prediction of lettuce growth and phenotype was achieved. [ABSTRACT FROM AUTHOR]