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Membrane distillation crystallization (MDC) is an emerging hybrid thermal membrane technology that synergizes membrane distillation (MD) and crystallization, which can achieve both freshwater and minerals recovery from high concentrated solutions. Due to the outstanding hydrophobic nature of the membranes, MDC has been widely used in numerous fields such as seawater desalination, valuable minerals recovery, industrial wastewater treatment and pharmaceutical applications, where the separation of dissolved solids is required. Despite the fact that MDC has shown great promise in producing both high-purity crystals and freshwater, most studies on MDC remain limited to laboratory scale, and industrializing MDC processes is currently impractical. This paper summarizes the current state of MDC research, focusing on the mechanisms of MDC, the controls for membrane distillation (MD), and the controls for crystallization. Additionally, this paper categorizes the obstacles hindering the industrialization of MDC into various aspects, including energy consumption, membrane wetting, flux reduction, crystal yield and purity, and crystallizer design. Furthermore, this study also indicates the direction for future development of the industrialization of MDC. [ABSTRACT FROM AUTHOR]

The existence of various pollutants in water environment contributes to global pollution and poses significant threats to humans, wildlife, and other living beings. The emergence of an effective, realistic, cost-effective, and environmentally acceptable technique to treat wastewater generated from different sectors is critical for reducing pollutant accumulation in the environment. The electrochemical advanced oxidation method is a productive technology for treating hazardous effluents because of its potential benefits such as lack of secondary pollutant and high oxidation efficiency. Recent researches on advanced oxidation processes (AOPs) in the period of 2018–2022 are highlighted in this paper. This review emphasizes on recent advances in electro-oxidation (EO), ozone oxidation, sonolysis, radiation, electro-Fenton (EF), photolysis and photocatalysis targeted at treating pharmaceuticals, dyes and pesticides polluted effluents. In the first half of the review, the concept of the AOPs are discussed briefly. Later, the influence of increasing current density, pH, electrode, electrolyte and initial concentration of effluents on degradation are discussed. Lastly, previously reported designs of electrochemical reactors, as well as data on intermediates generated and energy consumption during the electro oxidation and Fenton processes are discussed. According to the literature study, the electro-oxidation technique is more appropriate for organic compounds, whilst the electro-Fenton technique appear to be more appropriate for more complex molecules. [ABSTRACT FROM AUTHOR]