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Nanofluids as thermal absorption media or optical filters have showed great potential for application in direct absorption solar collector or hybrid photovoltaic/thermal (PV/T) collectors. Due to their nanoscale size and high surface energy, particles in nanofluid have a great tendency to aggregate into large secondary agglomerate, even in the presence of the anti-agglomeration agent, which could in turn lead to significant change in the thermal and optical properties of the nanofluid. However, rare work has been carried out to investigate the relation between the aggregation and optical properties of the nanofluid, which in our view, is of great importance for the enhanced performance of the nanofluid in solar collectors. In this study, taken alumina nanofluids with controlled particle aggregation properties as example, we were able to investigate the underlying correlation between the size distribution of the aggregate in nanofluid and their resulting absorption coefficients. It was found that inhibited aggregation and resultant smaller aggregated particle size could lead to larger absorption coefficient. Both Rayleigh scattering and Mie scattering theories have been attempted to predict the optical properties of the nanofluid after particle aggregation. The results indicate that values obtained by Rayleigh scattering theory are several orders higher than experimental values but that predicted by Mie scattering theory can reasonably match with the experimental results. Specially, it was demonstrated that by introducing the projected areas of the nanoparticle aggregate corresponding to smallest sphere enclosing diameter, more accurate absorption coefficient prediction based on Mie theory can be obtained. Our study is expected to provide a valuable guidance for the regulation of the optical properties of nanofluids and to improve their performance in solar collectors. [ABSTRACT FROM AUTHOR]

In this study, evolution and final state of particle size distribution (PSD) of TiO 2 /water suspension were described by a modified population balance equation considering both natural convection and Brownian motion. The calculation was verified by experimental measurement of scanning electron microscope and Laser particle analyzer. Based on the predicted PSD, Rayleigh scattering theory (for d < 4 λ ) and Fraunhofer diffraction theory (for d > 4 λ ) were then employed to determine the scattering and absorption coefficients of TiO 2 /water suspensions with various particle concentrations and at various light wavelengths. UV–Vis investigation showed that the predicted optical properties of TiO 2 /water suspension considering PSD are in much better agreement with the experimental results than that without considering PSD, at all particle concentrations investigated. It is traditionally accepted that for colloid suspension the scattering coefficient can be neglected compared to the absorption coefficient and therefore the extinction, which is the combination of the absorption and scattering coefficients, can be approximately replaced by the absorption coefficient. However, our finding indicates that, when particle aggregation is considered, the scattering coefficient of TiO 2 /water suspension could be much higher than the absorption coefficient. Consequently, using the absorption coefficient alone to replace the extinction coefficient even at long wavelengths could result in significant calculation errors and is not recommended. [ABSTRACT FROM AUTHOR]

Direct contact condensation of jets in fluid has been widely applied in many industrial applications owing to the low requirement of driving potential and high efficiency of heat and mass transfer. Here, experiments are carried out to investigate the velocity field characteristics of the turbulent jet induced by direct contact condensation of steam jet in crossflow of water in a vertical pipe. Visual equipment is specially invented to investigate the velocity field characteristics by using Particle Image Velocimetry (PIV) measurement technique. The high intensity laser light reflected by the pure steam region just outside the nozzle-exit brings out severe damage to the CCD camera. To solve this technical problem, a black plate is adopted to shield the pure steam region. According to the contours of the velocity fields and streamlines, the influences of jet momentum ratio, jet Reynolds number and water temperature on the jet flow field are explored. The jet centerline trajectory equations in exponential form are established based on the local maximum mean velocity. By introducing the jet Reynolds number and jet momentum ratio, the correlation for prediction of jet centerline trajectory equations is proposed, and the predicted results are within 30% of the experimental data. The reciprocal of the local maximum mean velocity and the half-width of the jet are proportional to the downstream coordinate along the jet velocity centerline trajectory. The scaled velocity field complies with the self-similarity principle. [ABSTRACT FROM AUTHOR]

• Monodispersed HCSs with tunable cavity size were synthesized through a thermal-etching process without template. • The "inside-out" oriented thermal etching process was induced by the "core-shell" differentiated chemical structures of CSs. • HCSs exhibited a SISG efficiency as high as 88.9%, which outperforms most of the previously reported carbon-based materials. • The delicate heat management contributes to the significantly improved SISG efficiency. Hollow carbon spheres (HCSs) with controllable morphology and structure have received considerable attention in the field of energy conversion and storage. Herein, monodispersed HCSs with cavity sizes tuned from 100 nm to 800 nm and shell thickness from 450 nm to 50 nm were successfully synthesized through a unique template-free thermal-etching method. It was evidenced that the dynamically controllable synthesis of HCSs was attributed to the "inside-out" oriented thermal oxidation etching of carbon spheres (CSs) induced by the differentiated "core-shell" chemical structures. Comparing to CSs, the obtained HCSs exhibited much increased efficiency for solar-driven interfacial steam generation (SISG), reaching as high as 88.9%, which outperforms most of the previously reported carbon-based materials. It was then demonstrated that the rational heat management for both photothermal and thermal-evaporation conversion is essential to achieve satisfying SISG efficiency. Depending on the increasing cavity sizes, HCSs presented gradual increases in both photothermal conversion and thermal-evaporation performances, mainly attributed to the improved light absorption and the delicate heat management, respectively. However, the further increase in cavity size resulted in excessive heat loss and presented decreased thermal-evaporation performance. This work provides an alternative and promising approach to the reasonable design of hollow nanostructures with delicate heat management for efficient SISG as well as other solar energy conversion applications. Hollow carbon spheres with tunable cavity was synthesized by an oriented thermal etching of hydrothermally synthesized carbon spheres, which exhibited excellent solar steam generation performances, with delicate heat management in both photothermal conversion and thermal-evaporation processes. [Display omitted] [ABSTRACT FROM AUTHOR]