1. Glucose-assisted combustion synthesis of oxygen vacancy enriched α-MoO3 for ethanol sensing.
- Author
-
Liu, Sen, Yang, Zhimin, Zhao, Liang, Zhang, Yaqing, Xing, Yunpeng, Fei, Teng, Zhang, Haiyan, and Zhang, Tong
- Subjects
- *
SELF-propagating high-temperature synthesis , *GAS detectors , *LIGHT metals , *OXYGEN , *ETHANOL , *METALLIC oxides - Abstract
The α-MoO 3 -based materials have been intensively investigated as chemiresistive-type gas sensors due to their excellent sensing performances for gas sensing applications. However, there still remains formidable challenges for developing a simple and scalable approach to synthesize α-MoO 3 with controllable structures. Herein, we demonstrated a glucose-assisted combustion synthesis strategy for the synthesis of α-MoO 3 materials with controllable structures. They were obtained by heat treatment of the gels containing ammonium heptamolybdate tetrahydrate and glucose. Owing to the coordination interactions between glucose and heptamolybdate, α-MoO 3 -2 sample obtained by adding 1.8 g of glucose featured the highest oxygen vacancy concentration with an O/Mo atomic ratio of 2.61. The gas sensing measurements indicated that α-MoO 3 -2 had excellent sensing performances for detecting ethanol. Such ethanol sensor displayed the lowest detection concentration of 5 ppm ethanol, high response of 3.86 toward 20 ppm ethanol, and wide detection range of 5–100 ppm. This study sheds light on preparation of metal oxides with controllable structures on a scalable way for various applications. • A glucose-assisted combustion synthesis method have been developed to preparation of MoO3 samples. • The MoO3 sample thus obtained possesses high oxygen vacancy concentration and surface chemical-adsorbed oxygen species. • The MoO3 sample exhibits excellent sensing performances for ethanol sensing. [ABSTRACT FROM AUTHOR]
- Published
- 2022
- Full Text
- View/download PDF