1. Practical silicon deposition rules derived from silane monitoring during plasma-enhanced chemical vapor deposition.
- Author
-
Bartlome, Richard, De Wolf, Stefaan, Demaurex, Bénédicte, Ballif, Christophe, Amanatides, Eleftherios, and Mataras, Dimitrios
- Subjects
- *
CHEMICAL vapor deposition , *POLYSILANES , *RADIO frequency , *ELECTRIC reactors , *PLASMA gases - Abstract
We clarify the difference between the SiH4 consumption efficiency η and the SiH4 depletion fraction D, as measured in the pumping line and the actual reactor of an industrial plasma-enhanced chemical vapor deposition system. In the absence of significant polysilane and powder formation, η is proportional to the film growth rate. Above a certain powder formation threshold, any additional amount of SiH4 consumed translates into increased powder formation rather than into a faster growing Si film. In order to discuss a zero-dimensional analytical model and a two-dimensional numerical model, we measure η as a function of the radio frequency (RF) power density coupled into the plasma, the total gas flow rate, the input SiH4 concentration, and the reactor pressure. The adjunction of a small trimethylboron flow rate increases η and reduces the formation of powder, while the adjunction of a small disilane flow rate decreases η and favors the formation of powder. Unlike η, D is a location-dependent quantity. It is related to the SiH4 concentration in the plasma cp, and to the phase of the growing Si film, whether the substrate is glass or a c-Si wafer. In order to investigate transient effects due to the RF matching, the precoating of reactor walls, or the introduction of a purifier in the gas line, we measure the gas residence time and acquire time-resolved SiH4 density measurements throughout the ignition and the termination of a plasma. [ABSTRACT FROM AUTHOR]
- Published
- 2015
- Full Text
- View/download PDF