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Two coordination polymers [Ag(HIMPAA)(IMPAA)] ( 1), [Cu(HIMPAA)(IMPAA)Cl] ( 2), (HIMPAA = (2 E)-3-[4-(1H-imidazol-1-ylmethyl)phenyl]acrylic acid) have been synthesised with ozagrel and structurally characterized by element analysis, infrared spectra (IR), PXRD and X-ray crystal diffraction. Complex 1 is the monoclinic system, space group P21/c with a = 10.897(3) Å, b = 6.1624(14) Å, c = 19.274(4) Å, α = 90.00°, β = 113.13°, γ = 90.00°, V = 1190.2(5) Å, Z = 2. In complex 1, the Ag(I) atom is two-coordinated in a linear mode. Intermolecular O-H···O hydrogen bonds links 1 to generate one-dimensional hydrogen bonds chain. Complex 2 is the monoclinic system, space group C2/c with a = 22.742(7) Å, b = 13.829(4) Å, c = 7.918(2) Å, α = 90.00°, β = 97.10°, γ = 90.00°, V = 2471.1(12) Å, Z = 4. In complex 2, four HIMPAA and four Cu(II) ions forms a novel 52-membered macrocycle [Cu(IMPAA)]. The 52-membered macrocycle is further briged by HIMPAA to form a two-dimensional network. Graphical Abstract: A one-dimensional coordination polymers [Ag(HIMPAA)(IMPAA)] ( 1) and a two-dimensional network [Cu(HIMPAA)(IMPAA)Cl] ( 2), (HIMPAA = (2 E)-3-[4-(1H-imidazol-1-ylmethyl)phenyl] acrylic acid) were synthesised with ozagrel and structurally characterized by element analysis, IR, PXRD and X-ray crystal diffraction. [ABSTRACT FROM AUTHOR]

Two Cd(II) complexes, [Cd(CMOPAA)(Phen)(H2O)]n (1) and [Cd(CMOPAA)(Bipy)]n (2), (H2CMOPAA = 4-carboxymethoxy-3-phenylacrylic acid, Phen = 1,10-phenanthroline and 2,2′-bipyridine = Bipy) were synthesized with 4-carboxymethoxy-3-phenylacrylic acid ligands by solvothermal condition and structurally characterized by element analysis, IR, TGA and single crystal X-ray diffraction. Complex 1 crystalizes in the monoclinic system, space group C2/c with a = 12.4609 (11) Å, b = 18.7973 (16) Å, c = 13.4544 (12) Å, β = 99.732 (1)°, V = 3106.1 (5) Å3. The asymmetric unit of complex 1 consists of one Cd(II) ion, one CMOPAA2− ligand, one Phen ligand and one H2O. Cd(II) ion is an eight-coordinated distorted dodecahedron geometry. Each CMOPAA2− ligand coordinates with two adjacent Cd(II) ions to form a one-dimensional chain. Complex 2 crystalizes in the triclinic system, space group P-1 with a = 9.407 (3) Å, b = 9.838 (3) Å, c = 11.792 (4) Å, α = 83.974 (4)°, β = 78.392 (3)°, γ = 67.019 (3)°, V = 983.7 (5) Å3. The asymmetric unit of complex 2 consists of one Cd(II) ion, one CMOPAA2− ligand and one Bipy ligand. Cd(II) ion is a seven-coordinated twisted single-cap triangular prism configuration. The hexadentate bridging CMOPAA2− ligands coordinates with four adjacent Cd(II) ions to form a one-dimensional chain. The tetradentate bridging CMOPAA2− ligands link the neighboring one-dimensional chains to form a novel two-dimensional network structure. Two Cd(II) complexes, [Cd(CMOPAA)(Phen)(H2O)]n (1) and [Cd(CMOPAA)(Bipy)]n (2), (H2CMOPAA = 4-carboxymethoxy-3-phenylacrylic acid, Phen = 1,10-phenanthroline and 2,2′-bipyridine = Bipy) were synthesized with 4-carboxymethoxy-3-phenylacrylic acid ligands and structurally characterized by element analysis, IR, TGA and single crystal X-ray diffraction. Complex 1 is a one-dimensional chain and complex 2 is a two-dimensional network structure. [ABSTRACT FROM AUTHOR]