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This paper presents a comprehensive system for assessing contaminant emissions, including the dominant contaminant reduction effects, recessive contaminant reduction effects, and contaminant reduction efficiency indexes. The system is used to evaluate the linkage changes in contaminant emissions reduction across different sectors, the ease of regulation, and the returns on emissions reduction efforts. The study's results demonstrate that firstly, COVID-19 initially reduced contaminant emissions across almost all sectors, although this effect waned over time. Secondly, applying conventional regulatory measures to sectors with high reductions in contaminant emissions may not yield the expected results. Thirdly, while some sectors may be more difficult to regulate, they may offer a higher return on investment in terms of emissions reduction. Based on the above results, the paper advocates for timely measures to consolidate environmental gains, prevent rebounding of contaminant emissions, prioritize supervision and management of easily regulated sectors, prioritize upgrading of cleaner production in sectors with high reduction efficiency indices, and increase investment in environmental technology. • Created a new comprehensive system for assessing contaminant emission changes. • Quantified the unique linkage changes of contaminant emissions during COVID-19. • Developed new models to reveal contaminants' regulatory difficulty and return. • The innovative reduction effects of four key contaminant indicators were measured. • Applied WHEM firstly in research across multiple areas of contaminant emissions. [ABSTRACT FROM AUTHOR]