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The cement industry plays a significant role in global carbon emissions, underscoring the urgent need for measures to transition it toward a net-zero carbon footprint. This paper presents a detailed plan to this end, examining the current state of the cement sector, its carbon output, and the imperative for emission reduction. It delves into various low-CO 2 technologies and emerging innovations such as alkali-activated cements, calcium looping, electrification, and bio-inspired materials. Economic and policy factors, including cost assessments and governmental regulations, are considered alongside challenges and potential solutions. Concluding with future prospects, the paper offers recommendations for policymakers, industry players, and researchers, highlighting the roadmap's critical role in achieving a carbon-neutral cement sector. • Cement industry faces urgent need for net-zero transition due to high carbon emissions. • Roadmap spans phases: foundation, acceleration, net-zero, targeting emissions by 2050. • Innovations like alkali-activated cements offer promise for emission reduction. • Collective action and policy crucial for sustainable transformation of cement sector. [ABSTRACT FROM AUTHOR]

Safe disposal of solid wastes containing heavy metals is a significant task for environment protection. Immobilization treatment is an effective technology to achieve this task. Cementitious material treatments and thermal treatments are two types of attractive immobilization treatments due to that the heavy metals could be encapsulated in their dense and durable wasteforms. This paper discusses the heavy metal immobilization mechanisms of these methods in detail. Physical encapsulation and chemical stabilization are two fundamental mechanisms that occur simultaneously during the immobilization processes. After immobilization treatments, the wasteforms build up a low permeable barrier for the contaminations. This reduces the exposed surface of wastes. Chemical stabilization occurs when the heavy metals transform into more stable and less soluble metal bearing phases. The heavy metal bearing phases in the wasteforms are also reviewed in this paper. If the heavy metals are incorporated into more stable and less soluble metal bearing phases, the potential hazards of heavy metals will be lower. Thus, converting heavy metals into more stable phases during immobilization processes should be a common way to enhance the immobilization effect of these immobilization methods. [ABSTRACT FROM AUTHOR]

Heavy metal stabilization by chemical chelating agent and solidification by cement are technologies currently used to reduce the leaching of heavy metals in municipal solid waste incineration (MSWI) fly ash. This paper studied the physico-chemical properties of the fly ash, heavy metals content in the fly ash, and the leaching concentration of the heavy metals from fly ash. The effect of four chelating agents namely dithiocarbamate (1#), dithiocarbamic acid dipotassium salt (2#), amino dithiocarbamate chelating resin (3#) and thiourea (4#) on the stabilization and leaching of heavy metals were investigated. Different addition ratios (1%, 2% and 3% w/w) of the chelating agents, various curing time (7, 14, 28 days), and different amounts of the cement (10%, 15% and 20% w/w) were used in order to find the agent with the optimum stabilization and leaching of heavy metals as well as find the effect of combining the agent and cement. The results showed that the dithiocarbamate (1#) chelating agent had the best stabilizing performance due to the three-dimensional structure after their reaction. The addition of cement to the fly ash led to the immobilization of heavy metals due to the C-S-H gel formation. The technology of cement solidification and chelating agent stabilization was optimal from the point of economic cost and the complexity aspect. Image 10654 • The stabilization performance of four chemical chelating agents in MSWI fly ash was compared. • Dithiocarbamate presents the best stabilization character among the four agents. • Stabilized agents combined with solidified cements show better performance. • Cd is more difficult to stabilized/solidified than the other heavy metals. [ABSTRACT FROM AUTHOR]

Abstract Rapid urbanisation, with associated housing and infrastructure demands, leads to increased mining and use of non-renewable mineral raw materials needed for the construction industry including concrete and cement. In an emerging economy, like Thailand, which is part of Association of Southeast Asian Nations (ASEAN), current environmental management policies are insufficient to reduce raw material requirements or waste from demolition by generating inputs to construction through reuse or recycling. As part of the European Union (EU), Great Britain has successfully implemented integrated policies and achieved high rates of recycled aggregates in construction (29%) and a 70% reuse and recycling target for construction and demolition (C&D) waste. In this paper, Material Flow Analysis (MFA) of cement/concrete materials is combined with an interpretation of related policies to provide a deeper understanding how to achieve more sustainable management of natural resources. A comparative MFA for the construction industry in Great Britain and Thailand (representing an ASEAN country) has been developed that quantifies raw material inputs, buildings and infrastructure outputs, so that the practices in the two countries can be contrasted. We report domestic cement production and import/export data, and calculate the raw materials needed for cement and its calcination process for concrete production. Considering the most relevant policies and taxation in Great Britain, we identify possible ways forward for Thailand by introducing new policies and taxation that will have positive effects on raw material extraction, processing, construction and disposal practices and disposal behaviors. Following the MFA and policy analysis, we believe that similar benefits apply to other emerging economies. Graphical abstract Image 1 Highlights • Describes policies to provide a deeper understanding how to achieve more sustainable management of mined resources in the construction sector. • Reports domestic cement production and import/export data, and calculate the raw materials needed for cement and its calcination process for concrete production. • A comparative MFA for the construction industry in EU (Great Britain) and emerging economy (Thailand, representing an ASEAN country), has been developed. • Quantifies raw material inputs, buildings and infrastructure outputs, so that the practices in the two countries can be contrasted. • Identifies policies that can help other countries to reduce the disposal of non-renewable natural and mined resources. • More widely, similar approaches and policies will influence sustainable resource and waste management in other emerging economies. [ABSTRACT FROM AUTHOR]

This paper examines the application of cement (C)-barite (Ba) based-Stabilisation/Solidification (S/S) for the remediation of 137 Cs-contaminated soils, investigating the influence of soil: grout and C: Ba ratios on the shielding performance of the S/S mix assessed as gamma radiation shielding ( γRS ) index variation. Results from experiments were used to perform a novel approach and an economic analysis in order to calculate the effective dose reduction achievable by S/S and to assess the optimum quantities and costs of selected mixes, respectively. Gamma ray spectrometer measurements indicate that γRS index increases with increasing barite percentage up to a maximum level of 50%; however a further increase results in a worsening of the shielding performances. A maximum γRS variation of 46.5% was recorded with grout percentage increasing from 16.6 to 50%. At the photon energy of 662 keV ( 137 Cs), the maximum grout amount results in the possibility to shield up to 24.1% of γ-rays emitted. The effective dose reduction achievable by the investigated S/S allows a maximum 137 Cs-soil contamination in the range 2.94–14.55 kBq kg −1 successfully treatable employing a soil: grout ratio of 1: 1 (C: Ba = 1:1). Technical data, jointly with economic analysis findings, make cement-barite based-S/S very competitive in cost-effectiveness and could provide a basis for decision-making of 137 Cs-contaminated site remediation. [ABSTRACT FROM AUTHOR]

Oak Ridge tank sludges that have been collected over several decades are being combined for treatment and disposal. Stabilization of the highly radioactive, mixed-waste sludges in the different tank sets has been evaluated prior to the proposed combination and treatment. This paper documents the testing of a Melton Valley Storage Tank (MVST)/Bethel Valley Evaporator Storage Tank set. Subsequent papers will discuss continued work on other tank sets and efforts to maximize the sludge loading. Grout formulations were tested in the laboratory both with a surrogate and with a sample of an actual mixed waste tank sludge from MVST W-25. Wet-sludge loadings of 50–60 wt% resulted in strong wasteforms with no free water and gave a volume increase of about 40–50 vol%. Resource Conservation and Recovery Act (RCRA) metals included in the surrogate testing were cadmium, chromium, lead, selenium, thallium, and mercury. The actual sludge sample was only characteristically hazardous for mercury by the Toxic Characteristic Leaching Procedure but exceeded the Universal Treatment Standard (UTS) limit for chromium. The grout formulations stabilized these two RCRA metals within UTS limits. In addition, a grout leachability index of about 9.0–10.0 was measured for both 85Sr and 137Cs, meeting the recommended requirement of >6.0. [Copyright &y& Elsevier]

Highly radioactive, mixed-waste sludges that have been collected at Oak Ridge over several decades are being combined for treatment and disposal. Stabilization of the sludges in the different tank sets was tested prior to the proposed combination and treatment. This paper, which follows a previous article on the Melton Valley Storage Tank/Bethel Valley Evaporator Storage Tank set, documents the testing of the Gunite and Associated Tank and Old Hydrofracture Facility tank sets, as well as the combined sludges of all the Oak Ridge National Laboratory tank sets; the third paper on this subject will discuss efforts to maximize the sludge loading. The grout formulations were tested in the laboratory with surrogates. A wet-sludge loading of 60 wt% resulted in strong wasteforms with no free water and gave a volume increase of about 30–40 vol%. The Resource Conservation and Recovery Act metals included in the surrogate testing were silver, cadmium, chromium, lead, selenium, thallium, zinc, and mercury. The grout formulations stabilized these metals within the Universal Treatment Standards limits. In addition, a grout leachability index of about 10.0–12.0 was measured for both 85Sr and 137Cs, meeting the recommended requirement of >6.0. [Copyright &y& Elsevier]

Decarbonizing the cement manufacturing sector presents an interesting and pressing challenge as it is one of the largest energy consumers in industry (i.e., 7%), emitting considerable amounts of anthropogenic carbon dioxide (i.e., 7%). This paper performs a technical and environmental assessment of decarbonisation of cement production through process modelling and simulation, thermal integration analysis, and Life Cycle Assessment (LCA). Integration of three post-combustion capture methods for a conventional cement plant with an annual productivity of one million tons and a carbon capture rate of 90% is evaluated in comparison to the reference case without carbon capture and storage (CCS). Mass and energy balances derived from simulations are used for the assessment of three innovative capture systems: reactive gas-liquid absorption using Methyl-Di-Ethanol-Amine, reactive gas-solid adsorption using calcium looping (CaL) technology and membrane separation. For the LCA study, a "cradle-to-gate" approach is carried out using GaBi software, according to the ReCiPe impact assessment method. The general conclusion is that integrating the CCS methods into the cement production process leads to a decrease in global warming potential (GWP) in the range of 69.91%–76.74%. Of the CCS technologies analysed, CaL technically outperforms the others as it requires 34% less coal and provides 1.6 times higher gross energy efficiency. From an environmental perspective, CaL integration ranks first, with the lowest scores in six of the nine impact categories and a GWP reduction of 76.74% compared to the baseline scenario without CCS. [Display omitted] • Decarbonisation of the cement industry by post-combustion CO 2 capture technologies. • Thermal integration, technical and environmental evaluation were carried out. • Chemical scrubbing and calcium looping are self-sufficient in terms of heat and power. • Calcium looping exhibits better environmental performances than other two cases. [ABSTRACT FROM AUTHOR]

This paper presents the performance of cement mortar containing black rice husk ash (BRHA) under nitric and acetic acid attacks. The BRHA, collected from an electrical generating power plant that uses rice husk as fuel, was ground using a grinding machine. The compressive strength loss, weight loss, and expansion of mortars under nitric and acetic acid attack were investigated. The test results of BRHA properties in accordance with the ASTM C 618 standard found that the optimal grinding time was 4 h as this achieved a Blaine fineness of 5370 cm2/g. For parametric study, BRHA were used as a Portland cement Type 1 replacement at the levels of 0%, 10%, 20%, 30%, 40%, and 50% by weight of binder. The water-to-binder ratios were 0.55, 0.60, and 0.65. From test results, when the percentage replacements of BRHA in cement increased, it was observed that the strength loss and weight loss of mortars containing BRHA under acetic acid attack were higher than those of the mortars against nitric acid attack. It was found that, of the various BHRA mortars, the strength loss and weight loss due to nitric and acetic acid attacks were the lowest in the mortar with 10% BRHA replacement. For 10%, 20% and 30% BRHA replacements, the rate of expansion of the BRHA mortar decreased when compared with the control mortar. For the mortars with other percentage replacements of BRHA, the rate of expansion increased. Furthermore, the effective water-to-binder ratios of control and BRHA mortars were the primary factor for determining the durability of mortar mixed with BRHA. [Copyright &y& Elsevier]

This paper assess the mechanical an environmental behaviour of cement mortars manufactured with addition of fly ash (FA) and bottom ash (BA), as partial cement replacement (10%, 25% and 35%). The environmental behaviour was studied by leaching tests, which were performed under several temperature (23 °C and 60 °C) and pH (5 and 10) conditions, and ages (1, 2, 4 and 7 days). Then, the accumulated amount of the different constituents leached was analysed. In order to obtain an environmental burden (EB) value of each cement mixture, a new methodology was developed. The EB value obtained is related to the amount leached and the hazardous level of each constituent. Finally, the integral study of compressive strength and EB values of cement mixtures allowed their classification. The results showed that mortars manufactured with ordinary Portland cement (OPC) and with coal BA had similar or even better environmental and mechanical behaviour than mortars with FA. Therefore, the partial replacement of cement by BA might be as suitable or even better as the replacement by FA. [Copyright &y& Elsevier]

This paper reports the preparation of sulphur polymer cements (SPCs) incorporating waste ilmenite mud for use in concrete construction works. The ilmenite mud raw material and the mud-containing SPCs (IMC-SPCs) were characterised physico-chemically and radiologically. The optimal IMC-SPC mixture had a sulphur/mud ratio (w/w) of 1.05 (mud dose 20 wt%); this cement showed the greatest compressive strength (64 MPa) and the lowest water absorption coefficient (0.4 g cm−2 at 28 days). Since ilmenite mud is enriched in natural radionuclides, such as radium isotopes (2.0·103 Bq kg−1 228Ra and 5.0·102 Bq kg−1 226Ra), the IMC-SPCs were subjected to leaching experiments, which showed their environmental impact to be negligible. The activity concentration indices for the different radionuclides in the IMC-SPCs containing 10% and 20% ilmenite mud met the demands of international standards for materials used in the construction of non-residential buildings. [Copyright &y& Elsevier]

This paper presents a study of cement replacement by sugar cane bagasse ash (SCBA) in industrial scale aiming to reduce the CO2 emissions into the atmosphere. SCBA is a by-product of the sugar/ethanol agro-industry abundantly available in some regions of the world and has cementitious properties indicating that it can be used together with cement. Recent comprehensive research developed at the Federal University of Rio de Janeiro/Brazil has demonstrated that SCBA maintains, or even improves, the mechanical and durability properties of cement-based materials such as mortars and concretes. Brazil is the world’s largest sugar cane producer and being a developing country can claim carbon credits. A simulation was carried out to estimate the potential of CO2 emission reductions and the viability to issue certified emission reduction (CER) credits. The simulation was developed within the framework of the methodology established by the United Nations Framework Convention on Climate Change (UNFCCC) for the Clean Development Mechanism (CDM). The State of São Paulo (Brazil) was chosen for this case study because it concentrates about 60% of the national sugar cane and ash production together with an important concentration of cement factories. Since one of the key variables to estimate the CO2 emissions is the average distance between sugar cane/ethanol factories and the cement plants, a genetic algorithm was developed to solve this optimization problem. The results indicated that SCBA blended cement reduces CO2 emissions, which qualifies this product for CDM projects. [Copyright &y& Elsevier]

In this paper, black rice husk ashes (BRHAs), which are agrowastes from an electricity generating power plant and a rice mill, were ground and used as a partial cement replacement. The durability of mortars under sulfate attack including expansion and compressive strength loss were investigated. For parametric study, BRHA were used as a Portland cement Type 1 replacement at the levels of 0%, 10%, 30%, and 50% by weight of binder. The water-to-binder ratios were 0.55 and 0.65. For the durability of mortar exposed to sulfate attack, 5% sodium sulfate (Na2SO4) and magnesium sulfate (MgSO4) solutions were used. As a result, when increasing the percentage replacement of BRHA, the expansion and compressive strength loss of mortar decreased. At the replacement levels of 30% and 50% of BRHA, the expansion of the mortars was less than those mixed with sulfate-resistant cement. However, the expansion of the mortars exposed to Na2SO4 was more than those exposed to MgSO4. Increasing the replacement level of BRHA tends to reduce the compressive strength loss of mortars exposed to Na2SO4 attack. In contrary, under MgSO4 attack, when increasing the replacement level of BRHA, the compressive strength loss increases from 0% to 50% in comparison to Portland cement mortar. Results show that ground BRHA can be applied as a pozzolanic material to concrete and also improve resistance to sodium sulfate attack, but it can impair resistance to magnesium sulfate attack. [Copyright &y& Elsevier]

Abstract: Many secondary materials are being considered for use as substitutes for natural aggregates in highway applications due to their suitable engineering and economic properties. During the design life of the application, recycled materials are exposed to freeze/thaw cycles and other aging processes such as carbonation, coupled with intermittent infiltration/wetting by precipitation events. In such scenarios, leaching of material constituents is a primary pathway for environmental impact. This paper presents results of the effect of freezing and thawing on the leaching behavior of major and minor constituents from a laboratory formulated granular cement-based material. Scenarios considered included water percolating through the material (flow-through) and run-off (flow-around), both important leaching pathways in highway environments. The effect of moisture content at the time of freezing, number of freeze/thaw (F/T) cycles, and material size reduction were investigated. F/T exposure and subsequent infiltration/wetting resulted in consolidation and self-cementing of the granular cement-based material. For the flow-around scenario, F/T exposure resulted in a reduction in constituent release with time and increasing F/T cycles. For the flow-through scenario, moisture content at the time of freezing was an important parameter and an increase in the release was initially observed due to preferential flow/cracks and/or constituent redistribution prior to a decrease that resulted from self-cementing during further thawing and percolation. [Copyright &y& Elsevier]

Highly radioactive, mixed-waste sludges that have been collected in tanks at Oak Ridge over several decades are being combined for treatment and disposal. Stabilization of the sludges in the different tank sets was tested prior to the proposed combination and treatment. This paper is the third one in a series on the laboratory stabilization/solidification of these tank sludges. It discusses efforts to maximize the sludge loading with no strength criterion for the grout formulation. Grout formulations were tested in the laboratory both with surrogates and with actual samples of tank sludge. Hydrogels eliminated free water generation, even at sludge loadings of >90 wt%, albeit strong monoliths did not form at such high loadings. Correlations established the dependence of the chromium and mercury performance in the Toxicity Characteristic Leach Procedure for the surrogates on the slag content of the grout while the lead performance depended on the extract pH. The surrogate sludge loading was limited by the chromate content to about 90 wt%, meeting Universal Treatment Standard limits. However, tests with actual sludges at such high loadings revealed problems with lead and silver stabilization that were not experienced with the surrogate testing. [Copyright &y& Elsevier]

In this research, the effect of curing temperature on the metalloid (As) leachability of cemented paste backfill (CPB; a mix of tailings, cement and water) is studied. ASTM C 1308 leaching protocol is used to determine the leachability of CPB samples subjected to different curing temperatures (2, 20 and 35 °C). In addition, the effect of curing temperature on the microstructure of CPB is assessed to determine if the temperature dependence of the leaching characteristics of CPB is related to variations in the microstructure of the cement matrix. The microstructural techniques used include, powder x-ray diffraction, mercury intrusion porosimetry, and scanning electron microscopy techniques. The results obtained indicate that the curing temperature has a significant effect on the leachability of CPB. It is found that as curing temperature increased from 2 °C to 35 °C the performance of the CPB for arsenic immobilization decreased. The magnitude of this temperature-induced change in As-leachability of CPB depends on the curing temperature range (low (≤20 °C) or elevated (35 °C) temperatures). This curing temperature dependency of the leachability of CPB is attributable to the temperature-induced changes in the pore structure of CPB, formation/development of hydration products and pH in the CPBs during the curing process. The results also indicate that diffusion dominates as the leaching mechanism through the studied temperature range and is independent of curing temperature. However, curing temperature does control the availability for arsenic to leach. The new findings presented in this paper will contribute to design more environmental-friendly cemented paste backfill materials and structures, which is vital for sustainable mining. • Impact of temperature on the As leachability of cemented paste backfill (CPB) is studied. • Curing temperature has a significant effect on the As leachability of CPB. • Diffusion dominates as the leaching mechanism and is independent of curing temperature. • Curing temperature does control the availability for arsenic to leach. [ABSTRACT FROM AUTHOR]