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1. Regioselective Reductive Hydration of Alkynes To Form Branched or Linear Alcohols.

Author

Le Li and Herzon, Seth B.

Subjects
*REGIOSELECTIVITY (Chemistry), *REDUCTIVE coupling reactions (Chemistry), *HYDRATION, *ALKYNES, *ALCOHOLS (Chemical class), *HYDROCARBONS, *FEEDSTOCK
Abstract

The regioselective reductive hydration of terminal alkynes using two complementary dual catalytic systems is described. Branched or linear alcohols are obtained in 75–96% yield with ≥25:1 regioselectivity from the same starting materials. The method is compatible with terminal, di-, and trisubstituted alkenes. This reductive hydration constitutes a strategic surrogate to alkene oxyfunctionalization and may be of utility in multistep settings. [ABSTRACT FROM AUTHOR]

Published
2012
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