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In this paper, we focus on develop high-order and structure-preserving numerical algorithm for the two-dimensional nonlinear space fractional Schrödinger equations. By constructing a new generating function, we obtain a fourth-order numerical differential formula and use it to approximate the spatial Riesz derivative, while the Crank–Nicolson method is applied for the time derivative. Based on the energy method, the conservation, solvability and convergence of the numerical algorithm are proved. Finally, some numerical examples are used to verify the correctness of the theoretical analysis and the validity of the numerical algorithm. [ABSTRACT FROM AUTHOR]