1. Experimental demonstration of comminution with transcritical carbon dioxide cycles.
- Author
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Hesse, Max, Asetre, Pascuala, Anderson, Ryan, Edwards, Cliff, Lee, Chuck, Malpica, Oscar, and Klein, Bern
- Subjects
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SUPERCRITICAL carbon dioxide , *CARBON cycle , *CARBON dioxide , *SIZE reduction of materials , *POROSITY , *CARBON sequestration - Abstract
A new comminution technology that can reduce energy consumption when compared to traditional grinding of rock is presented. The process is based on pulverization driven by transcritical CO 2 cycles, resulting in tensile fracture inside the particle rather than compression from outside. Tensile strength of many rocks is approximately 10 times lower compared to compressive strength offering significant potential for saving energy. In this apparatus, comminution can occur over multiple cycles to enhance rock breakage without extracting and refeeding rock between cycles. The test rig depicts test conditions to capture and to recycle the CO 2. Limestone is utilized as an example material in a lab-scale experimental apparatus. Within the apparatus, the temperature and pressure are raised to supercritical conditions. A rapid release of the CO 2 into a decompression chamber results in an expansion of supercritical CO 2 inside the pores and fractures rock from tension instead of compression. Results show a significant fraction of the limestone is comminuted in three consecutive CO 2 pressure cycles. A majority of the resulting particles exhibit larger fragments from 5 mm to 13.2 mm. 6.2% of the feed material was directly transferred to fine material <300 μm without many intermediate progeny particles. Initial results indicate a larger ratio of the pressure before and after burst, and longer soak times aid pulverization. A single rock is also analyzed, where it is noted that breakage occurs along visible fractures, and this behavior is noted over consecutive cycles. [Display omitted] • Supercritical carbon dioxide migrates into pore structure • Rapid depressurization causes gas expansion and fracture via tensile forces • Generating direct tensile forces offers potential for energy saving • Pressure before and after expansion and soak time influence fracture • Comminution advances with further supercritical CO2 cycles [ABSTRACT FROM AUTHOR]
- Published
- 2022
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