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It has been proven that the future of energy demands for human society is related to clean energy sources such as solar energy. On the other hand, fuel cell technology converts the chemical energy of a fuel into electrical energy. Meanwhile, the polygeneration system based on (semi) renewable energy can be a viable alternative to conventional fuel-based systems. However, examining their performance for widespread implementation requires further and powerful studies. The aim of the present work is to evaluate the performance of the polygeneration energy system to produce electricity, heat, hydrogen and cool. The novel hybrid power system consists of the 10 kW el phosphoric acid fuel cell, linear Fresnel solar reflector (LFR), Organic Rankine Cycle (ORC) and Stirling engine (SE). In the novel energy conversion process proposed, the fuel cell generates electricity and heat, and its waste heat is used to generate additional electricity in the SE. The fuel and oxidant required by the fuel cell are supplied by an electrolyzer that is powered by an ORC system. A solar thermal collector provides the duty required by the evaporator of ORC system. The effect of key parameters such as current density, solar radiation and flow rate of hydrogen on the system energy and exergy performance is also investigated. To evaluate the performance of the LFR system the climatic conditions of Tehran (in Iran) and Beijing (in China) are considered. Results revealed that, the SE and ORC system separately generates 1.48 and 26.54 kW of electricity, respectively. Furthermore, the electrolyzer consumes 23.36 kW of electric power and 3.64 kW of cooling is produced by the chiller. In addition, the energy efficiency and total exergy destruction of the proposed system are 71.32 % and 57.94 kW, respectively. [ABSTRACT FROM AUTHOR]