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Pyrolysis is considered to be an effective technology that not only provides renewable energy but also mitigates climate change. Biochar, one by-product of pyrolysis, can be utilized in multiple ways by different biochar applications, which could result in considerable changes in renewable energy production and carbon sequestration. In existing literature, however, the economic and environmental benefits of pyrolysis and biochar applications are rately discussed, thus, a thorough investigation on conjunctive applications of pyrolysis and biochar should be conducted. This study (1) reviews the pyrolysis outputs from various inputs such as energy crops, crop residuals, animal manures, municipal solid wastes, and sewer sludge; (2) discusses the economic and environmental consequences from pyrolysis and biochar applications through the investigation of a lifecycle assessment; and (3) illustrates the potential climate-induced impacts on agriculture and stability of feedstock supply. To do this, this paper adopts a sector-wide model to compare the effectiveness and efficiency of pyrolysis and biochar applications with and without impacts of climate change for a specific region as a case study; and addresses the influential factors that potentially affect the large-scale development of pyrolysis. The results show that, in the absence of climate change impacts, conjunctive applications of pyrolysis and biochar can reduce more than 2.69 million tons of CO 2 emission and generate electricity of 3,962 MWh annually. In the cases where climate-induced impacts do have influences on crop yields, transitions among pyrolysis technologies and agricultural practice would occur. Under such a circumstance, net electricity generation and emission reduction would decrease by 1.72% and 3.19%, respectively. Thus,taking potential climate change impacts into account is necessary to avoid considerable deviations from the target. • Various organic feedstocks and pyrolysis technologies are reviewed and discussed. • Pyrolysis and biochar applications improve sustainable energy and social development. • Climate-induced impacts are assessed to understand uncertainty. • Pyrolysis and biochar efficiency are introduced in the face of climate change. [ABSTRACT FROM AUTHOR]