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6G vehicle-to-everything (V2X) communication will be combined with vehicle automatic driving technology and play an important role in automatic driving. However, in 6G V2X systems, vehicle users have the characteristics of high-speed movement. Therefore, how to provide stable and reliable wireless link quality and improve channel gain has become a problem that must be solved. To solve this problem, a new multi-user scheduling algorithm based on block diagonalization (BD) precoding for 6G ultra-massive multiple-input multiple-output (MIMO) systems is proposed in this paper. The algorithm takes advantage of the sensitive nature of BD precoding to channel correlation, uses the Pearson coefficient after matrix vectorization to measure the channel correlation between users, defines the scheduling factor to measure the channel quality according to the user noise enhancement factor, and jointly considers the influence of the correlation between user channels and channel quality, ensuring the selection of high-quality channels while minimizing channel correlation. Simulation results show that compared with the multi-user scheduling algorithm based on subspace correlation, condition number, and geometric angle, the proposed algorithm can obtain higher user channel gain, effectively reduce the system bit error rate, and can be applied to 6G V2X communication. [ABSTRACT FROM AUTHOR]