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Hydrogen is considered a promising clean energy vector with the features of high energy capacity and zero-carbon emission. Water splitting is an environment-friendly and effective route for producing high-purity hydrogen, which contains two important half-cell reactions, namely, the anodic oxygen evolution reaction (OER) and the cathodic hydrogen evolution reaction (HER). At the heart of water splitting is high-performance electrocatalysts that efficiently improve the rate and selectivity of key chemical reactions. Recently, perovskite oxides have emerged as promising candidates for efficient water splitting electrocatalysts owing to their low cost, high electrochemical stability, and compositional and structural flexibility allowing for the achievement of high intrinsic electrocatalytic activity. In this review, we summarize the present research progress in the design, development, and application of perovskite oxides for electrocatalytic water splitting. The emphasis is on the innovative synthesis strategies and a deeper understanding of structure–activity relationships through a combination of systematic characterization and theoretical research. Finally, the main challenges and prospects for the further development of more efficient electrocatalysts based on perovskite oxides are proposed. It is expected to give guidance for the development of novel non-noble metal catalysts in electrochemical water splitting. [ABSTRACT FROM AUTHOR]

Antimony (Sb) as a low-toxic and cost-effective metal is a promising material to catalyse CO 2 electroreduction to formate with practical viability. However, monometallic Sb suffers from intrinsically low catalytic activity and the competing hydrogen evolution. Here, we report nanoporous Sb-Bi alloys for substantially improving the catalytic activity of Sb and suppressing hydrogen evolution. The optimal Sb-Bi alloy exhibits a maximum Faradaic efficiency of 95.8 % toward formate production, surpassing the 11.6 % of monometallic Sb counterpart. Operating the catalyst in the flow cell demonstrates a formate partial current density of 734 mA cm−2 and cathodic energy efficiency of 59 % at a moderate overpotential of 800 mV, representing a record formate-production performance so far. Experimental and theoretical studies indicate that the Sb-Bi interactions activate Sb sites to selectively stabilize *OCHO intermediates, facilitating CO 2 -to-formate conversion. This work offers insights in manipulating bimetallic interactions to transform inert materials into active catalysts for efficient electrocatalysis. [Display omitted] • Sb-Bi interactions induce electrocatalytic switching from HER to CO 2 ER. • Sb 2 Bi 6 exhibits a maximum formate selectivity of 95.8 % in an H-type cell. • Sb 2 Bi 6 achieves a record formate activity of 734 mA cm−2 in a flow cell. • Sb-Bi interactions facilitate Sb sites to stabilize *OCHO for formate formation. [ABSTRACT FROM AUTHOR]

Given its superior structure, the abundance of surface functional groups, and low cost, cotton fiber filtration paper can be used as the support for hydrogen evolution reaction (HER) and oxygen evolution reaction catalysts (OER) instead of copper foam (CF), nickel foam (NF), or carbon cloth (CC). Herein, the chemical plating method was used to create thin self-supporting electrodes based on cotton fiber filtration paper (FP). The Co-Ni-P amorphous nanospheres can be uniformly dispersed on the self-supporting FP due to its porous structure and oxygen functional groups. The Co-Ni-P/FP electrode has an overpotential as low as 125 mV for HER and 320 mV for OER at the current density of 10 mA cm−2. Additionally, according to density functional theory (DFT) calculations, the Co atom added to the Ni-P nanosphere can lead to considerably more charge accumulation around the Co and Ni active sites, which greatly encourages the HER and OER processes. The novel porous support, FP, provides a fresh way the preparation of self-supporting electrodes. [Display omitted] • Filter paper is used to prepare the self-supporting electrode as the substrate. • The preparation method is simple and the properties are stable. • Rich oxygen-containing functional groups of FP promote deposition and dispersion. • Explore the excellent electrochemical performance of amorphous Co-Ni-P/FP by DFT. [ABSTRACT FROM AUTHOR]