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The transmitting signal of wireless communication system is impaired by the nonlinearity of RF power amplifier (PA) which leads to signal distortion and spectrum spillover, by which the signal transmission quality is affected. Digital predistortion (DPD) is an efficient and economical way to correct the nonlinear effects of power amplifiers. The recursive least square (RLS) recognition algorithm is commonly used to extract the correction coefficients of the DPD model, and the accuracy of the extraction directly affects the system performance. In this paper, a new variable forgetting factor identification algorithm (new variable forgetting factor recursive least square, NVFFRLS) is proposed for recursive least square (RLS) identification algorithm. The 64-QAM signal is combined with a memory polynomial (MP) predistortion model for predistortion system simulation. The experimental results show that, compared with the RLS identification algorithm and two kinds of variable forgetting factor RLS identification algorithms, the algorithm has smaller estimation error, faster convergence, and better tracking capability, stability, and adaptability; the predistortion system based on NVFFRLS identification algorithm can compensate the nonlinear memory effects of power amplifier more effectively. [ABSTRACT FROM AUTHOR]