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[Display omitted] • Reverse IP strategy was proposed to fabricate TFC PA membranes. • Defect-free PA skin layer was constructed on hydrophobic PVDF/PTFE substrates. • The membranes exhibit excellent performance in aqueous and organic solutions. • Pure water permeances are over 11 LMH/bar with MgCl 2 rejections of over 95%. • Methanol permeances are over 3.3 LMH/bar with Congo red rejections of over 98.5%. Polyvinylidene fluoride (PVDF) and polytetrafluoroethylene (PTFE) porous membranes are ideal substrates for preparing thin-film composite (TFC) polyamide (PA) membranes with improved solvent resistance. However, it remains difficult to construct PA skin layers on PVDF and PTFE substrates via conventional interfacial polymerization (IP) due to the hydrophobic nature of these materials. To address this challenge, a reverse IP process was proposed to construct a defect-free PA skin layer on PVDF and PTFE substrates, in which the hydrophobic PVDF and PTFE substrates were soaked with the organic phase to ensure uniform coverage of reacted solution on the substrates. This novel strategy can effectively tackle the issue of uneven wetting of the aqueous phase on hydrophobic substrates in the conventional IP process. The resultant TFC membranes (i.e. M rev-PVDF and M rev-PTFE) exhibit excellent nanofiltration (NF) performance in both aqueous and organic solutions. M rev-PVDF and M rev-PTFE have MgCl 2 rejections of 96.12% and 95.17%, alongside the water permeances of 12.8 LMH/bar and 11.2 LMH/bar, respectively (M rev-PTFE was activated with DMF). It is further shown that M rev-PVDF and M rev-PTFE could also reject 99.4% and 98.5% of Congo red in methanol solution at solvent permeances of over 3.3 LMH/bar, while they also perform excellently in other polar protic solvents. Consequently, this work opens a new window for constructing high-performance TFC PA membranes on hydrophobic substrates and expands the application of the TFC PA NF membrane. [ABSTRACT FROM AUTHOR]