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Converting wind energy into ammonia (WtA) has been recognized as a promising pathway to produce “green” ammonia compared with traditional coal-based technologies. As the key part of WtA, Power-to-Ammonia (PtA) has great potential to facilitate the usage of wind generation. This paper proposes a co-planning approach for regional wind resources-based ammonia industry and the electric network (EN). To this end, PtA is first modeled as a flexible power load of power systems with spatial and temporal constraints on hydrogen supply chains (HSC). Then a novel co-planning model of WtA and EN is established to optimize the WtA configuration and the EN expansion. An alternating direction method of multipliers (ADMM) based algorithm is introduced to effectively solve this model. Real data of Inner Mongolia Province in China is adopted to verify the effectiveness and significance of the proposed approach. It is shown that the siting and operation flexibility of PtA with HSC can reduce the expansion burden of EN. The co-planning of WtA and EN can significantly enhance wind power utilization and reduce total investment costs. Furthermore, feasibility analysis on WtA in comparison with coal-to-ammonia (CtA) and ultra-high voltage transmission (UHV) provides helpful guidelines for the realization of WtA. [ABSTRACT FROM AUTHOR]