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Ammonia allows for long-distance and large-scale storage transport of renewable energy sources. The reactivity of NH 3 -Air flame can be enhanced by doping with hydrogen and by increasing the initial temperature. The flame combustion characteristics of NH 3 –H 2 -Air are studied in a rectangular closed pipe with a mole fraction of 45% H 2 , an equivalence ratio (φ) of 0.8–1.2 and 0.1 MPa. The initial temperatures (T u) of the mixture are 300 K, 375 K and 450 K. Experimental studies of flame front speed, flame tip structure evolution, and overpressure dynamics are performed. Laminar burning velocity (S L), peak mole fraction of key radicals, and flame instability of NH 3 –H 2 -Air flames are simulated in Chemkin Pro-software using the Mathieu and Petersen mechanism. The results show that the relatively low equivalence ratio and initial temperature promote the structural changes of the flame tip, forming a "tulip" flame and a distorted "tulip". As the equivalence ratio increases, the flame front speed and overpressure increase and the flame oscillates slightly. The distortion in the lip of the "tulip" is more pronounced. The increase in temperature promotes flame propagation in the early stages and the pressure decreases. Reactive activity increases with increasing temperature, the peak mole fraction of NH 2 and H radicals increases, and S L increases. At normal temperature, the flame is affected by thermo-diffusive instability only when lean mixture. The Darrieus-Landau instability increases as the equivalence ratio increases. Conversely, the Darrieus-Landau instability decreases with increasing temperature. Therefore, the current experimental and simulation results help to understand the laminar combustion characteristics of NH 3 –H 2 -Air at high temperatures. • The distortion of "tulip" is most obvious at T u = 300 K and φ = 1.1. • Increased temperature promotes flame propagation in the finger-shaped phase. • As The temperature increases (300–450 K), the H and NH 2 mole fractions increase. • DL instability decreases with increasing initial gas temperature. [ABSTRACT FROM AUTHOR]