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The rapid development of the Internet of Things has led to numerous functional electronic devices, making it a significant challenge to provide power for these distributed devices. Triboelectric self‐power technology is ideal for smart devices due to its material diversity and high energy efficiency. However, traditional triboelectric materials have weak electrostatic induction due to their low dielectric constant. Additionally, the thermionic emission effect reduces their electric output in high temperatures, limiting their applications. This study designes a thermally robust aramid triboelectric material with a high dielectric constant through heat‐induced cross‐linking heterogeneous interface engineering. This novel material not only achieves high triboelectric output but also maintains high performance across a wide temperature range. The heat‐induced cross‐linking process enhances the interaction between aramid nanofibers and Al2O3 nanosheets, significantly improving the electrical performance, and flame retardance of the material, and the relative dielectric constant increases 16‐fold. The triboelectric nanogenerator constructed with this material achieves a power density of 3.97 W m−2, and maintains high triboelectric output at 260 °C. Finally, a self‐powered detection system collects high‐temperature gas energy and drives sensors is designed. This research presents a novel strategy for high‐performance triboelectric materials, showing significant potential for self‐powered devices. [ABSTRACT FROM AUTHOR]

Drawing inspiration from nature has served as a crucial driving force behind human progress, enabling groundbreaking advancements and cross‐disciplinary integration through the emulation of biological superhydrophobic phenomena. Bioinspired superhydrophobic triboelectric materials stand out among advanced triboelectric materials due to their unique hydrophobic properties, exceptional moisture resistance, and remarkable electrical performance. However, the inherent complexity of natural phenomena and the need for refinement in bioinspired design pose significant challenges in the development of bioinspired superhydrophobic triboelectric materials. This comprehensive review delves into bioinspired superhydrophobic triboelectric materials from the perspectives of theoretical underpinnings, fabrication strategies, and cutting‐edge applications. Rooted in the interaction mechanisms between water molecules and triboelectric materials, the importance of enhanced hydrophobic properties is elucidated. A systematic overview of bioinspired superhydrophobic triboelectric materials’ construction strategies is presented, offering fresh perspectives and insights into the development and application of high‐performance triboelectric nanogenerators (TENGs). Finally, the current challenges and untapped opportunities in bioinspired superhydrophobic triboelectric materials are summarized to fully unlock their potential for applications in TENGs. [ABSTRACT FROM AUTHOR]

The seamless integration of advanced triboelectric nanogenerators with fiber material has propelled the rapid advancement of intelligent wearable electronics. The overheating and mechanical abrasion associated with prolonged operation poses a significant challenge for conventional fiber‐based triboelectric materials. Aramid fibers, characterized by high thermal stability, ultra‐high mechanical strength, and excellent insulating properties, can effectively compensate for the limitations of triboelectric materials. However, the intrinsic advantages of aramid fiber triboelectric materials and their general structural design strategies have not yet to be comprehensively elucidated. In this review, the synthesis methods and development history of aramid fiber triboelectric materials in recent years are summarized. Importantly, the unique advantages and development potential of aramid fibers as triboelectric materials are systematically discussed, particularly regarding high‐temperature resistance, high strength, and electrical insulation. Furthermore, the latest advancements in the structural design and performance modulation of aramid fiber triboelectric materials are presented. The aramid fiber‐based self‐powered wearable electronics in high‐temperature warning, impact monitoring, and human energy harvesting are summarized. Finally, the challenges and opportunities facing the future development of aramid fiber‐based triboelectric nanogenerators are discussed. [ABSTRACT FROM AUTHOR]

Non‐contact intelligent sensing technology is a key player in the data acquisition and environmental monitoring framework of the Internet of Everything, laying the groundwork for the realization of highly integrated intelligent network systems. However, environmental factors continue to be a major challenge in the process of real‐time monitoring and feedback of objects, constraining the stability and accuracy of the sensing signals. In this study, a hierarchical spatial assembly strategy is implemented to effectively integrate an intermediate energy storage layer with superhydrophobic surfaces (CA = 162 ± 2.5°), resulting in the development of a moisture‐resistant triboelectric structural materials with stable monitoring and tracking capabilities. The moisture‐resistant self‐powered sensor constructed from this triboelectric structural material operates effectively in extreme humidity conditions (99% RH) with a full‐scale output retention rate of 95.2%, and is capable of accurately sensing human activity from the distance of 3 m. Importantly, the sensor can also effectively detect vehicle states during operation and perform real‐time monitoring of the vehicle's surrounding environment. This study not only overcomes the long‐standing challenges of accuracy and stability in high humidity for sensors but also advances the development of sustainable, interconnected intelligent systems for the Internet of Everything in extreme environmental conditions. [ABSTRACT FROM AUTHOR]

The rapid development of wearable electronics has placed higher demands on the design strategies of triboelectric materials. Aerogels have the potential to become advanced triboelectric materials, however, traditional design strategies often require complex processes and additional chemical cross‐linking agents to improve the stability of the gel structure, which limits its practical application. In this work, a scalable and sustainable self‐assembly drive strategy is proposed for the design of bio‐based triboelectric aerogels with multi‐scale winding structures. Interestingly, the autoacceleration effect, which is regarded as "unfavorable" during the autocatalytic polymerization of supramolecules, is rationally exploited to provide the supramolecules within the matrix with an abundance of multiple hydrogen bonds at the same time as their rapid gelation occurs. Thanks to this, the aerogel film exhibits ultra‐high tensile strength (104 MPa) and remains undeformed after resisting an impact of 8000 times its own weight. Highly robust triboelectric aerogel films are used to build wearable self‐powered sensors with ultra‐fast response in complex environments (48 ms), while enabling real‐time interaction between the wearer and the information network. The design idea of " turning a detriment into an asset " in this work provides a new idea for the material construction of highly robust wearable sensors. [ABSTRACT FROM AUTHOR]

Highlights: Typical structures/working mechanisms of gel-based triboelectric nanogenerators and performance advantages of gel materials reviewed. Optimization of hydrogels, organogels, and aerogels for triboelectric nanogenerators in flexible sensing summarized. Applications, challenges, and future development directions of gel-based triboelectric nanogenerators in flexible sensing are discussed. The rapid development of the Internet of Things and artificial intelligence technologies has increased the need for wearable, portable, and self-powered flexible sensing devices. Triboelectric nanogenerators (TENGs) based on gel materials (with excellent conductivity, mechanical tunability, environmental adaptability, and biocompatibility) are considered an advanced approach for developing a new generation of flexible sensors. This review comprehensively summarizes the recent advances in gel-based TENGs for flexible sensors, covering their principles, properties, and applications. Based on the development requirements for flexible sensors, the working mechanism of gel-based TENGs and the characteristic advantages of gels are introduced. Design strategies for the performance optimization of hydrogel-, organogel-, and aerogel-based TENGs are systematically summarized. In addition, the applications of gel-based TENGs in human motion sensing, tactile sensing, health monitoring, environmental monitoring, human–machine interaction, and other related fields are summarized. Finally, the challenges of gel-based TENGs for flexible sensing are discussed, and feasible strategies are proposed to guide future research. [ABSTRACT FROM AUTHOR]

Material designs for wearable sensors are increasingly important due to variable application scenarios and environmental disturbances. The high temperatures pose a significant challenge to the performance of sensing materials. The reasonable anisotropic structure in materials is recognized as a promising approach to address this challenge. Precise control of the orientation of the material remains difficult, owing to the entropy effect. In this work, a tunable anisotropic triboelectric aerogel via an in situ coupled magnetic alignment and protonation reduction strategy is demonstrated. The designed orientation with a fitting degree of 98% can effectively suppress electron thermionic emission, which enables the surface charge density to reach 75 µC m−2 at 300 °C. Such a perfect coordination between self‐powered sensing and thermostability innovates multifunctional wearable sensing design at high temperatures, allowing aramid‐based aerogel to be a candidate for advanced sensing materials for applications in the military and aerospace fields. [ABSTRACT FROM AUTHOR]

[Display omitted] • Layer-ordered aerogel film is built as triboelectric materials inspired by wood. • Layer-ordered aerogel film excels in triboelectric output at extreme humidity. • The aerogel film is greatly stable on triboelectric output at wide humidity ranges. • The aerogel film achieves 95.3% of original output after recycling 3 times. The water molecules adhering to the surface of the triboelectric layer will take away the surface charge when traditional triboelectric nanogenerators (TENGs) operate in the high-humidity environment, resulting in a reduction in triboelectric performance, which significantly constrains the advancement of TENGs. Herein, a green triboelectric material of chitosan/polyvinyl alcohol longitudinal aerogel film (CP-LAF) with excellent humidity adaptation and triboelectric properties (9 cm2, 214 V, 18.25 μA) was prepared by a process of directional freeze-drying assisted mechanical compression with the idea from the anisotropic structure of natural wood. The triboelectric properties of TENGs are enhanced by their layered-ordered porous structure and rough surface. At the same time, it is reusable due to the inherent properties of the components. More importantly, the CP-LAF-based TENG has strong adaptation and stability to a high-humidity environment. Its output voltage at 99 % relative humidity (RH) is 1.6 times that of 50 % RH owing to the triboelectrification involving a large number of water molecules and the increase in the contact area caused by material softening. Additionally, its electrical performance decreases very little after 5000 working cycles. Meantime, it suggests excellent application advantages in energy harvesting and self-powered sensing. This design strategy has the potential to solve the problem of the degradation of traditional triboelectric materials in high-humidity environments. The material provides a stimulating example for the design and preparation of green triboelectric materials that can withstand different humidity environments. [ABSTRACT FROM AUTHOR]