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Mold deterioration of historical documents in archives and libraries is a frequent and complex phenomenon that may have important economic and cultural consequences. In addition, exposure to toxic fungal metabolites might produce health problems. In this work, samples of broths of fungal species isolated from the documentary material and from indoor environmental samples of the Archive of Bogotá have been analyzed to investigate the presence of mycotoxins. High resolution mass spectrometry made possible to search for a large number of mycotoxins, even without reference standards available at the laboratory. For this purpose, a screening strategy based on ultra-high pressure liquid chromatography coupled to quadrupole-time of flight mass spectrometry (UHPLC–QTOF MS) under MS E mode was applied. A customized home-made database containing elemental composition for around 600 mycotoxins was compiled. The presence of the (de)protonated molecule measured at its accurate mass was evaluated in the samples. When a peak was detected, collision induced dissociation fragments and characteristic isotopic ions were also evaluated and used for tentative identification, based on structure compatibility and comparison with literature data (if existing). Up to 44 mycotoxins were tentatively identified by UHPLC–QTOF MS. 34 of these tentative compounds were confirmed by subsequent analysis using a targeted LC–MS/MS method, supporting the strong potential of QTOF MS for identification/elucidation purposes. The presence of mycotoxins in these samples might help to reinforce safety measures for researchers and staff who work on reception, restoration and conservation of archival material, not only at the Archive of Bogotá but worldwide. [ABSTRACT FROM AUTHOR]

IoT environments are continuously changing. Changes may come from the service, connectivity, or physical layers of the IoT architecture. Therefore, to function appropriately, the system needs to dynamically adapt to its environment. In previous work, we posited eight challenges to foster adaptation through all architecture layers of IoT systems. In this paper, we address the challenges to manage the inclusion of new devices and devices' transient connection , by means of dynamic adaptations incorporated into our proposed software architecture for adaptive IoT systems. To manage dynamic adaptations, we extend the reference IoT architecture with our specialized components. In particular, we use (1) ontologies and instances to represent the domain knowledge; (2) a matching algorithm to pair services and IoT devices, taking into account their functional requirements, quality attributes and sensors properties; and (3) a match update algorithm used whenever sensors become (un)available. We evaluate the effectiveness of our solution with respect to the accuracy of matching services and IoT devices, and the response to environment changes. • This paper presents a new adaptive architecture for IoT Systems. • Ontology matching algorithm-based architecture to manage transient connections. • Functional, non-functional, and QoS matching algorithm between IoT components. • Matching algorithm with better precision and recall compared with the gold-standard. • Architecture deployed in a real case study for a SUDS system in the city of Bogotá. [ABSTRACT FROM AUTHOR]