Search

The effects of salinity on the photodegradation and mineralization of sulfonamides in the UV/TiO2 system were investigated. The goals of this study were to analyze the effects of pH and salinity on the sulfonamide concentration and total organic carbon (TOC) during the removal of sulfonamides in a UV/TiO2 system. Four sulfonamides -- sulfadiazine (SDZ), sulfamethizole (SFZ), sulfamethoxazole (SMX) and sulfathiazole (STZ) - were selected as parent compounds. The photodegradation and mineralization rates of sulfonamides in the UV/TiO2 system satisfy pseudo-first-order kinetics. Direct photolysis degraded sulfonamides but sulfonamides cannot be mineralized. The photodegradation and mineralization rate constants in all experiments followed the order pH 5 >pH 7 >pH 9. At pH 5, the mineralization rate constants of SMX, SFZ, SDZ and STZ were 0.015, 0.009, 0.012 and 0.011 min-1, respectively. The addition of NaCl inhibited the mineralization of the four tested sulfonamides more than it inhibited their photodegradation. The inhibitory effect of chloride ions on the removal of sulfonamides in the UV/TiO2 system was attributed to the scavenging by chloride ions of hydroxyl radicals (HO•) and holes and the much lower reactivity of chlorine radicals thus formed, even though the chlorine radicals were more abundant than HO•. [ABSTRACT FROM AUTHOR]

This study produced immobilized Cu2O via microwave irradiation. The surface properties of Cu2O were assessed by X-ray diffraction, scanning electron microscopy, and UV-vis spectroscopy. The catalytic activity of the generated Cu2O was examined for bisphenol (BPA) degradation in Cu2O/H2O2 and visible-light/Cu2O/H2O2 systems under various H2O2 concentrations. Cu2O can decompose H2O2 to generate radicals, similar to the Fenton-like process. The BPA degradation rate followed pseudo-first-order kinetics. The optimal H2O2 concentration was 30 mM and the BPA degradation rate under 30 mM H2O2 in the Cu2O/H2O2 and visible-light/Cu2O/H2O2 systems was 1.43 and 2.69 h-1, respectively. The original Cu2O partly oxidized into CuO in the visible-light/Cu2O/H2O2 system and the BPA degradation percentage declined to 51% from 100% after the fifth cycle. [ABSTRACT FROM AUTHOR]

This study applies photo-Fenton and photo-Fenton-like systems to decolorize Cl. Reactive Red 2 (RR2). The oxidants were H2O2 and Na2S2O8 Fe2+, Fe3t and CO2+ were used to activate these two oxidants. The effects of oxidant concentration (0.3-2 mmol/L) and temperature (25-55 °C) on decolorization efficiency of the photo-Fenton and photo-Fenton-like systems were determined. The decolorization rate constants (k) of RR2 in the tested systems are consistent with pseudo-first-order kinetics. The rate constant increased as oxidant concentration and temperature increased. Activation energies of RR2 decolorization in the UV/H2O2/Fe2+, UV/H2O2/Fe3t UV/Na2/Fe2+ and UV/ Na+ systems were 32.20, 39.54, 35.54, and 51.75 kj/mol, respectively. [ABSTRACT FROM AUTHOR]

In this study, Cl. Reactive Red 2 (RR2) was removed from aqueous solutions by chitin. Exactly how the RR2 concentration, chitin dosage, pH, and temperature affected adsorption of RR2 by chitin was then determined. After reaction for 120 mm, the amount of 10 and 20 mg/L RR2 absorbed onto chitin was 5.7 and 7.5 mg/g, respectively. The adsorption percentage increased from 56 to 94% when the chitin dosage was increased from 1.5 to 2.5 g/L. Experimental results indicated that the pseudosecond-order model best represents adsorption kinetics. Adsorption of RR2 increased as the temperature increased; however, it decreased with an increased pH. Experimental results further demonstrated that the Freundlich model is superior to the Langmuir model in fitting experimental isotherms. The ΔH° and ΔS° were 16.34 kJ/mol and 152.10 J/mol K, respectively. ΔH° suggested that adsorption of RR2 onto chitin was via physisorption. [ABSTRACT FROM AUTHOR]

This study utilises a UV/TiO2 system to decolorise C.I. Reactive Black 5 (RB5). The effects of TiO2 dosage, pH, RB5 concentration and light power on the decolorisation efficiency using the UV/TiO2 system were determined. IO4- was employed as an oxidant to increase the photodegradation efficiency of UV/TiO2. The decolorisation rate constants (k) of RB5 in the UV/TiO2 system are consistent with pseudo-first-order kinetics. The k values of 0.1, 0.5, 1.0 and 2.0 g/l TiO2 were 0.53, 0.52, 0.69 and 0.68 h-1, respectively. The rate constant increases with decreasing pH from 10 to 4. The decolorisation rate approximates linear relationship with RB5 concentration, as given by k=1.05[1/RB5]0.98; it varies nonlinearly with light power, as given by k=0.178[power]0.63. The experimental results reveal that the rate of decolorisation obtained using UV/TiO2/IO4-exceeds that obtained using UV/TiO2. [ABSTRACT FROM AUTHOR]

Heavy metals were removed from industrial sludge by traditional and microwave-assisted acid extraction approaches. The effects of acid concentration, extraction time, sludge particle size and solid/liquid (S/L) ratio on copper-extraction efficiency were assessed. Leaching with increased acid concentrations increased the yield of heavy metals from the industrial sludge. In microwaveassisted acid extraction, reducing the S/L ratio and sludge particle size increased copperextraction efficiency. These experimental findings indicate that S/L ratio most strongly influenced microwave-assisted acid extraction. Both traditional and microwave-assisted acid extraction demonstrate that sulfuric acid was an effective extractant, and the copper fraction in extracted sludge shifted from being primarily bound to Fe-Mn oxides and organic-matter partition, to being mostly bound to organic matter, remaining as a residue during acid extraction. [ABSTRACT FROM AUTHOR]