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Antecedentes: la producción de papel está soportada principalmente en la madera debido a su alto contenido de celulosa. Sin embargo, actualmente se buscan fuentes alternativas que desestimulen el uso de este recurso favoreciendo la protección de los recursos naturales. La producción de cacao es una actividad económica importante en Colombia, sin embargo, genera grandes cantidades de residuos orgánicos. La cascarilla de cacao es uno de los residuos más significativos de la industria del cacao y representa alrededor del 12 % del peso total de la semilla. Objetivo: evaluar las propiedades fisicoquímicas del papel obtenido a partir de la cascarilla de cacao de la variedad TCS 01. Métodos: se identificó y cuantificó la composición de celulosa, hemicelulosa y lignina de la cascarilla de cacao. Se realizó un diseño experimental para analizar las condiciones de extracción y elaboración del papel obtenido de la celulosa de la cascarilla y se evaluaron seis parámetros de calidad basado en la norma NTC 5342 (muestreo para determinar la calidad de papel y cartón): adsorción, tensión, escritura, color, textura y apariencia. Resultados: se obtuvo un porcentaje de celulosa, hemicelulosa y lignina de 12,5, 21,5 y 15,6 % en peso respectivamente. A partir del diseño experimental para la elaboración del papel, se observó que a una temperatura de 80°C y durante 8 horas se obtuvo el mejor tratamiento, mostrando las mejores características de calidad y cumpliendo lo requerido por la NTC 5342. Se observó que la masa límite de celulosa fue de 4,21 g de muestra húmeda la cual tuvo una absorción de 3,5 ml de agua. Los ensayos de tensión mostraron resultados de 8,2 N en las muestras de papel. Conclusiones: aunque el material obtenido no cumple a cabalidad con las características necesarias para catalogarse como papel, este material puede ser utilizado en la producción de envases y embalajes donde se requiere resistencia mecánica moderada o en la producción del material llamado “cartón paja”. Además, su alta adsorción medida en la prueba realizada indica que este material podría ser utilizado como absorbente en las industrias alimentaria o de construcción. [ABSTRACT FROM AUTHOR]

This article describes the structural characterization of the husk of modified rice through the process of advanced oxidation with the reagent Fenton; the transformation was carried out with the intention of increasing the number of active sites on the material's surface, and consequently to generate an absorbent with a greater capacity for the removal of Cr (VI) ions in solution, compared to the husk of natural rice. The characterization of modified material was determined through distinct experimental techniques that include the analysis of the functional groups present on the absorbent's surface through infrared spectroscopy with diffuse reflectance, (DRIFT), likewise, a surface morphology analysis of the husk through a scanning electron microscope (SEM), a compositional analysis and thermogavimetric (TGA). All of these tests were carried out before and after the modification process. The results of the DRIFT point towards a slight shift and attenuation in the vibration frequencies of the functional groups implicated in the structural modification, whereas the SEM analysis indicated noticeable changes in the morphology of the absorbent material. Meanwhile, the compositional analysis showed considerable changes in the percentage of the material components, whose presence was confirmed through the TGA analysis, after decomposing at the expected temperatures. In short, all results confirm the structural modification of the absorbent tested. [ABSTRACT FROM AUTHOR]

Peat is an organic material that has been widely used as an efficient and low-cost adsorbent. As many studies tend to focus on temperate peats, there is a lack of knowledge about the adsorption mechanism of tropical peats. This paper investigates the use of two Brazilian peats (Cravinhos - C and Luis Antônio - LA) from the Mogi-Guaçu river basin for the adsorption of lead (Pb), zinc (Zn), and cadmium (Cd), in order to contribute to the use of local and easy access materials to remediate contaminated sites. The peats adsorbed a high percentage of cations, especially Pb cations (100.0-46.3%), with commercial peat C showing higher adsorption than peat LA. The removal order was Pb2+ > Cd2+ = Zn2+ for C and Pb2+ > Zn2+ > Cd2+ for LA. The batch data for both peats and for all metals were better fit by the Langmuir isotherm, with adsorption capacities (qm) for Pb, Zn, and Cd of 37.3134, 29.0674 and 21.2890 mmol kg-1 in peat C and 21.7391, 14.2550 and 3.6460 mmol kg-1 in LA, respectively, values comparable to those of other peats and biosorbents. The studied peats are considered efficient, alternative and low-cost adsorptive materials for these metals. The proximity of peatlands to areas with high potential for contamination necessitates the use of local materials to reduce remediation costs. [ABSTRACT FROM AUTHOR]

During polymer injection in enhanced oil recovery processes, polymeric molecules are attached to the rock surface as a result of a series of interactions between both components, leading to concentration decrease on the injected batch. This phenomenon, known as adsorption [18], can be estimated by analytical models and depends on several factors like the type of rock, degree of hydrolysis and polymer concentration, reservoir temperature, salinity of formation water, among other aspects. This paper shows the results of 144 statics tests where salinity (NaCl and CaCl2) and polymer concentration were taken as the parameters to be changed in order to determine which analytical model is the most accurate for the prediction of experimental results. The abnormal adsorption tendency with NaCl, indicates that the grater salinity value, the lesser adsorption value concentrations. This is mainly due to the response of the kaolinite substrate to flocculation. [ABSTRACT FROM AUTHOR]

In this paper, the process for the synthesis of LTA and/or FAU zeolites from waste materials from mining and manufacturing industry from Antioquia (Colombia) was described. The product was used as adsorbent for the removal of Cr (III) in solutions prepared in the laboratory. The waste materials were characterized by X-ray fluorescence, and X-ray diffraction. The zeolites were characterized by X-ray diffraction, X-ray fluorescence, scanning electron microscopy (SEM) and BET area. Absorption data in Cr(III) removal tests were obtained by elemental composition from atomic absorption spectroscopy, and evaluated by Langmuir, Freundlich and Temkin models, and four kinetics models. The results showed the formation of zeolites from waste materials, and effective in adsorption tests of Cr (III). [ABSTRACT FROM AUTHOR]

Natural gas contains different types of gases such as methane, ethane, propane, butane, nitrogen and carbon dioxide, which methane is the main component. The separation of carbon dioxide from natural gas makes effective its use as domestic fuel, industrial and automotive fuel. The use of porous materials, which are able of preferentially adsorbing the CO2, is an alternative to obtain pure natural gas that allow the above mentioned applications. The traditionally used materials as CO2 adsorbents are activated carbon, zeolites and metal-organic frameworks (MOFs). In this paper, the CO2 adsorption capacity using zinc oxide nanoparticles (ZnONPs) is evaluated. These materials are attractive adsorbents, due to their low cost and great capacity of functionalization. [ABSTRACT FROM AUTHOR]

Air Conditioning with renewable energy is a key issue in the region's energy policy. The high temperatures usually attributed to climate change and the increase of the standard of living in society continues increasing energy demand in order to establish the conditions for thermal comfort in buildings. Solar air conditioning, although it contains a mature technology, its level of market introduction and acceptance by designers of buildings is exhaustive. This paper discusses the feasibility of these projects, identifies non-technological type barriers that hinders such use and implementation of solar energy for air conditioning systems, and finally, it approaches some criteria and recommendations to overcome these obstacles. [ABSTRACT FROM AUTHOR]

In this paper was studied the use of low-cost materials obtained from plants remains and modified organic matrices to replace the use of conventional methods for removal of heavy metals. So avoiding subsequent problems such as the generation of chemical sludge, and creates an alternative use for materials considered as waste. It is well known that the presence of some of the active components in these materials allow them to efficiently capture metal ions, however, it was found that other factors like pH of solution and concentration of metals also influence this process. In general, acid treatment and a subsequent transformation of materials to active carbon increases sorption capacity. Also, it is the pseudo second order model and the Langmuir isotherm that are the equations most used to describe kinetics and the adsorption behavior. [ABSTRACT FROM AUTHOR]

This paper describes the use of flower wastes (carnation, rose and daisy) as a potential, alternative and low-cost adsorbent for the removal of Acid Blue 9 (AB9). The best conditions to achieve an efficient adsorption were evaluated in a batch process. With an acidic pH of 2.0, a removal exceeding 90% was obtained using concentrations of AB9 of 15.0 mgL-1 and a dosage of adsorbent of 4.0 gL-1. The equilibrium of the process was modeled using the Langmuir and Freundlich isotherms, obtaining a better fit with the latter one. Kinetic studies indicated a better fit of the process to a pseudo-second order model and negligible effect of temperature. In addition, the bromatological characterization of the adsorbent is shown. [ABSTRACT FROM AUTHOR]

Leachates produced in the closed landfill Curva de Rodas in Medellin, Colombia are catalogued as mature leachates. These are characterized as poorly biodegradable waste containing organic compounds such as fulvic and humic acids, heavy metals, ammonia, nitrogen, and salts. In this paper five possible physicochemical leachate treatments are evaluated: adsorption with five types of granular activated carbon (GAC), adsorption with zeolite type A, Fenton oxidation, chemical precipitation by Ca(OH)2, and coagulationflocculation with aluminum sulfide type A. The treatments are compared in terms of their capacity to remove Chemical Oxygen Demand (COD) and color. GAC adsorption removals of up to 39% for COD and 50% for color were achieved. In the case of the adsorption with zeolite type A, negligible removals of COD and color were achieved (3% and 7% respectively). Removals using the Fenton oxidation and neutralization with NaOH reached up to 95% for COD and 97% for color. When additionally neutralized with raw leachate the removals were up to 79% for COD and 87% for color. Finally in the chemical precipitation tests, removals of 27% for COD and 63% for color were achieved. Clearly, Fenton oxidation was identified as the most appropriate treatment process. [ABSTRACT FROM AUTHOR]

In recent years the asphaltene deposition of films on metal surfaces has been of great studies because they provide valuable information about the adsorption of asphaltene. This paper presents a study by light microscopy and scanning electron asphaltene films, grown on substrates of gold deposited on a surface electro brass. Samples were prepared with oil extracted asphaltene Ayacucho precipitated in n-hexane at a ratio (1:20) and various concentrations prepared by using as solvents: toluene, isopropyl benzene (cumene) and tetrahydrofuran. The deposition of the films was done using the technique of Spin Coating on the same conditions of speed and spin time. Finally we observed that asphaltene films prepared with cumene came the defect type "groove" with toluene, circular patterns were observed type "coffee rings" and finally diluted with tetrahydrofuran was presented on the surface discontinuity. [ABSTRACT FROM AUTHOR]

In this paper we identified the best conditions for the removal of Acid Blue 9 dye (AB9) using flower wastes (FW) as an adsorbent were determined using a full factorial 2³ and a Box-Behnken design for further optimization. Adsorbent dose (D), dye concentration (C) and contact time (t), were the assessed variables. The dye content was quantified by UV-Vis spectrometry. The statistical model presented an adequate adjustment coefficient (R² = 99,18%), allowing to achieve a removal of 98,5% with a dosage of 7,8 gL-1, dye concentration of 7,11 mgL-1 and contact time of 104 min. These results suggest that flowers wastes are an alternative and potential adsorbent material for the treatment of dissolved acid dyes. [ABSTRACT FROM AUTHOR]

An important oil production impact is the increase of environmental pollution due to discharge of water formation. This paper presents a study of oil adsorption onto hydrophobic silica, i.e., silica nanoparticles impregnated with Colombian vacuum residue (VR) at 2 and 4 wt% and onto zeolite and impregnated zeolite nanoparticles (2 and 4wt% of VR) to reduce the amount of O/W emulsion. The Langmuir and Freundlich adsorption models were used to fit the experimental information of the adsorption isotherms. Initial crude oil concentration ranges from 200 to 2000 mg/l. Oil concentration, after adsorption, was determined by using an UV-vis spectrophotometer. The highest oil removal was obtained with impregnated silica nanoparticles, yielding values of 200 mg/g, with 100% oil removal, 9 mg/g more than the value obtained by modified zeolite of 191 mg/g at the same initial concentration. Pseudo-first-order and pseudo-second-order models were used to fit the experimental data of the adsorption kinetics, with better results for the pseudo-second order model. [ABSTRACT FROM AUTHOR]

Benzothiazoles, such as benzothiazole (BT), 2-hydroxybenzothiazole (OHBT), and 2-methylbenzothiazole (MeBT) are toxic and poorly biodegradable organic compounds, frequently present in wastewater from rubber related applications. Activated carbon adsorption has been identified as an attractive treatment to removing those contaminants. This paper presents experimental results on the effect of chemical surface properties of activated carbon on the adsorption mechanism of benzothiazoles. Activated carbons with different surface chemical composition were prepared from a Filtrasorb-400 activated carbon. Pre-treatment of activated carbon included de-oxygenation and ozonation with different ozone doses. Experimental results showed that high surface concentration of oxygenated electron withdrawing groups produced a significant reduction on carbon adsorption capacity of benzothiazoles. The results suggest that adsorption mechanism of benzothiazoles would mainly take place by π-π dispersion interactions between the π-electrons of aromatic ring of benzothiazole molecules and the π-electrons of carbon graphene layers. When pH was higher than point of zero charge (pHPZC) of the activated carbon, repulsive electrostatic interactions appeared between adsorbate and ionised oxygenated surface groups, lowering the carbon adsorption capacity of benzothiazoles. [ABSTRACT FROM AUTHOR]

This paper compares experimental results on methylene blue (MB) removal systems based on ozone oxidation, zeolite adsorption, and simultaneous adsorption-oxidation using ozone in the presence of natural zeolite. The effect of pH (2-8), and the presence of radical scavengers (sodium acetate) on process rates and removal efficiencies are assessed at laboratory scale. The experimental system consisted of a IL differential circular flow reactor and an ozone generator rated at 5 g O3/h. Results show that ozone oxidation combined with zeolite adsorption increases the overall MB oxidation rate with respect to ozonation process and zeolite adsorption. In presence of free radical scavenger only a 25% of reduction on MB removal rate are observed in the simultaneous treatment, as compared with 70% when ozonation treatment is used, suggesting that MB oxidation reactions take mainly place on the zeolite surface. [ABSTRACT FROM AUTHOR]