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For about two millennia, paper has served as a main medium for preservation of people’s ideas, stories, contracts, and art. This article reviews what is known about the various components that make up paper from the perspective of their long-term stability under typical storage conditions. Literature evidence is considered relative to the susceptibility of different paper components to embrittlement, acid hydrolysis, microbiological attack, and discoloration, among others. The cellulose that makes up a majority of most paper items is demonstrably stable enough to persist for many hundreds of years on the shelves of archival collections, though it is susceptible to acid-catalyzed hydrolysis, which can be accelerated by byproducts of decomposition. Though less attention has been paid to the archival performance of various minor components of modern paper products, evidence suggests that at least some of them are subject to likely breakdown, embrittlement, or decay in the course of prolonged storage. Based on these considerations, one can envision different categories of paper that can be expected to meet different levels of storage stability: ancient recipes for handmade papermaking, e.g. washi and hanji, archival-grade paper products, ordinary modern alkaline paper products, and paper manufactured without concerns for its longevity. [ABSTRACT FROM AUTHOR]

Thermal aging and ultraviolet (UV) irradiation are used as methods to prepare samples of kraft paper spanning its full lifecycle within a high-voltage transformer, from new to end of life. The mechanical break strain is correlated with the degree of polymerization (DP), representing a progressive deterioration of mechanical properties during aging. Subsequent exposure to oil flow mimicking both normal plant operation and reclamation activities shows that aged paper exposed to high rates of flow experiences noticeable surface roughening. Despite this, no measurable erosion occurs even after long-term temperature/flow cycling in used mineral oil containing a notable particulate content. This indicates that kraft paper is unlikely to be eroded by normal reclamation activities, even in a severely aged asset. This confirms the validity of using this approach to extend plant life. [ABSTRACT FROM AUTHOR]

In order to determine the influence of bast fibers isolated from Wikstroemia bark on the durability of paper, self-made paper was prepared using bagasse pulp mixed with Wikstroemia bark pulp using Kaihua paper manufacturing technology. The durability properties of the paper obtained with different proportions of Wikstroemia bark pulp were measured and analyzed. The results showed that Wikstroemia bark can lower the acidity, improve the mechanical strength, and delay the aging of paper. The mechanical strength showed an exponential relationship with the amount of Wikstroemia bark pulp added to the paper pulp. There was a linear positive correlation between the initial polymerization degree of the paper and the amount of Wikstroemia bark pulp, while the molecular fracture rate of the paper with Wikstroemia bark pulp was considerably reduced. Wikstroemia bark fibers are long fibers with high strength. At the same time, Wikstroemia bark fibers differ greatly in length, so the uniformity can meet the requirements. The durability of the paper made from only bagasse pulp was poor, but the overall strength and polymerization degree of the paper improve after being mixed with Wikstroemia bark pulp. [ABSTRACT FROM AUTHOR]

This study conducts thermal aging treatment to study the effect of thermal aging on the PD degradation process of the oil-paper insulation. The partial discharge inception voltages, extinction voltages, carbon mark, and microscopic morphology of samples are analyzed. The results show that thermal aging does not reduce the partial discharge inception voltages of oil-paper but can make the spark produced in the oil-paper more difficult to extinguish. At the initial stage, thermal aging has little effect on the development of partial discharge in normal direction of samples, while in later stages, the effect begins to appear; thermal aging reduces the insulation performance between layers of oil impregnated paper and accelerates the carbon trace growth rate in the horizontal direction. In this model, the first layer is most severely bombarded by electrons, and this layer is most obviously affected by the electric field in the normal direction at the contact point between the electrode and the insulating paper. The lower layer is affected by the horizontal and vertical electric fields; therefore, a large area of fiber looseness occurs on the surface of the oil impregnated paper. The degree of deterioration is proportional to the endurance time and aging time, and the damage degree of oil impregnated paper decreases with the increase of the number of layers. [ABSTRACT FROM AUTHOR]

Embodied theories of cognition consider many aspects of language and other cognitive domains as the result of sensory and motor processes. In this view, the appraisal and the use of concepts are based on mechanisms of simulation grounded on prior sensorimotor experiences. Even though these theories continue receiving attention and support, increasing evidence indicates the need to consider the flexible nature of the simulation process, and to accordingly refine embodied accounts. In this consensus paper, we discuss two potential sources of variability in experimental studies on embodiment of language: individual differences and context. Specifically, we show how factors contributing to individual differences may explain inconsistent findings in embodied language phenomena. These factors include sensorimotor or cultural experiences, imagery, context-related factors, and cognitive strategies. We also analyze the different contextual modulations, from single words to sentences and narratives, as well as the top-down and bottom-up influences. Similarly, we review recent efforts to include cultural and language diversity, aging, neurodegenerative diseases, and brain disorders, as well as bilingual evidence into the embodiment framework. We address the importance of considering individual differences and context in clinical studies to drive translational research more efficiently, and we indicate recommendations on how to correctly address these issues in future research. Systematically investigating individual differences and context may contribute to understanding the dynamic nature of simulation in language processes, refining embodied theories of cognition, and ultimately filling the gap between cognition in artificial experimental settings and cognition in the wild (i.e., in everyday life). [ABSTRACT FROM AUTHOR]

The long-term operation of dry-type transformer bushings at high temperatures can impact the performance of their primary insulation material. This article presents an experimental study of the effect of thermal aging time on electrical treeing in the epoxy resin-impregnated paper. The experimental results show that the electrical treeing pattern along the middle path of the electric field and the interlayer creepage along the average direction of the electric field are closely related to the aging time. Under the effect of thermal aging at 150 °C, the tree-starting voltage of epoxy resin-impregnated paper tends to increase and decrease as the aging time increases. An analysis and discussion of the test results in conjunction with scanning electron microscope (SEM) and energy dispersive spectroscopy (EDS) tests suggest that the destruction of the cross-linked network of the epoxy resin-impregnated paper at 150 °C is a fundamental reason for the significant decrease in the material’s tree-starting voltage and the change in electrical treeing morphology and interlayer creepage. Long-term operation at high temperatures can seriously impact the primary insulation performance of dry-type transformer bushings and requires attention. [ABSTRACT FROM AUTHOR]

Measuring the furan concentration in transformer oil is one of the most common methods of monitoring and evaluating insulation paper and estimating its degree of polymerization (DP). Here, methods for measuring furan concentration, especially ultraviolet-visible (UV-Vis) spectroscopy method, are reviewed on the old transformers oil. The results show that the excessive turbidity of old oils and noise at low wavelengths are the main disadvantages of this method, which reduce the measurements accuracy. The following solutions are proposed to overcome these disadvantages: 1) diluting insulation oil with hexane to reduce absorption intensity and 2) using average absorption at a given wavelength to reduce noise impact. These solutions are applied to the oil samples of ten old distribution transformer. It is observed that the correlation between 2-furaldehyde (2-FAL) concentration and average absorption intensity in 190–600 nm wavelength range is equal to ${R}^{{2}} =0.98$. A mathematical equation for calculating 2-FAL concentration based on average absorption is presented. It has been shown that to reduce the test time, a 190–400 nm range is the optimal measurement wavelength range. The results show that the average difference between the values of DP in the proposed method and the direct measurement method is equal to 77.5. [ABSTRACT FROM AUTHOR]

The carbon oxides (CO2 and CO) in the insulating oil of power transformers come from the thermal aging of cellulosic insulating paper; the CO2/CO ratio can reflect the aging state of cellulosic insulating paper. At present, the formation mechanisms of CO2 and CO in oil-immersed power transformers are still unclear. In this article, the ReaxFF reaction force field is used to simulate the thermal aging process of cellulosic insulating paper, and the main reaction pathways of CO2 and CO molecules formed by cellulose pyrolysis are obtained. The study finds that the amount of CO2 and CO generated is related to temperature. When the pyrolysis temperature continues to rise, the amount of CO2 generated shows a downward trend, while the amount of CO generated continues to increase, and the CO2/CO ratio continues to decrease. The simulation results are consistent with the previous experimental results. Through pathway tracking, it is found that the CO2 and CO molecules are mainly derived from certain specific atoms of cellulose molecules. The COSMO-RS module is used to analyze the change trend of the solubility of CO2 and CO in insulating oil with temperature. The results show that the solubility of CO2 and CO decreases with the increase of insulating oil temperature, which provides theoretical support for accurate application of carbon oxides aging evaluation index at different temperatures. [ABSTRACT FROM AUTHOR]

Timely identification of the aging stage of the transformer can effectively ensure the safe operation of the transformer and prevent the aging fault of the transformer. This work proposes the aging diagnosis of transformer using the Raman spectroscopic recurrence plot combined with learning vector quantization (LVQ) neural network. Oil-paper insulation samples at different aging stages are obtained by accelerated thermal aging tests. Acquisition of Raman spectra of insulating oil is from 800 to 3000 cm−1 and converts to the Raman spectroscopic recurrence plot. The gray-level cooccurrence matrix (GLCM) is used to extract the characteristic information of the Raman spectroscopic recurrence plot. The optimal number of neurons in competitive layer of LVQ neural network is determined by the experimental method. A transformer aging diagnosis model based on the Raman spectroscopic recurrence plot is established. The results show that the diagnostic accuracy of the proposed diagnostic model reached 95%. The Raman spectroscopic recurrence plot has more abundant aging “fingerprint” characteristic information and the proposed diagnostic method shows potential for monitoring oil-paper insulation. [ABSTRACT FROM AUTHOR]

The ecological environment is increasingly damaged due to the impact of mineral oil extraction and leakage. As a kind of sustainable resource, a vegetable oil transformer has bright application prospects in future. However, the stability of vegetable oil has always been a problem to be solved. In addition, the metallic copper inside the transformer has a certain catalytic effect on the deterioration of vegetable oil. In this article, a copper–oil–paper insulation model is established. Based on the molecular dynamics simulation method, the catalytic mechanism of copper on the deterioration of oil-paper insulation is revealed from the microscopic level. Then, the effects of temperature, contact area, and oxygen on the catalytic effect of copper are discussed. The results show that copper could accelerate the decomposition of oil-paper insulation by attracting H atoms and O atoms in oil-paper. The increase in temperature accelerates the progress of the catalytic reaction and aggravates the deterioration of oil-paper insulation. The oxygen concentration has an important influence on the catalytic reaction of copper. As the oxygen concentration increases, the catalytic effect of copper is weakened. The abovementioned research could provide some theoretical reference for further exploration of effective oil-paper insulation deterioration protection technology. [ABSTRACT FROM AUTHOR]

Methanol is considered to be a new chemical marker to estimate the aging state of transformer cellulose insulation paper. The key to improve the assessment accuracy is to establish the precise relationship between the concentration of methanol in oil and degree of polymerization (DP) of insulation paper. The previous research in this area has shortcomings and needs to be further improved. In this article, first, an aging assessment basic model (temperature 20 °C, moisture content of insulation paper 0.637%) is established based on the theoretical derivation of cellulose degradation kinetics, and is calculated by 130 °C thermal aging experiment. Furthermore, the effects of different temperatures (20 °C–90 °C) and moisture contents of insulation paper (0.6%–3.4%) on methanol in oil are studied by diffusion experiment. Based on the above effects, the temperature and moisture correction factors are established by mathematical reduction. What is more, a modified model is proposed by integrating the basic model and the correction factors. Eventually, the verification experiment is randomly prepared to test the accuracy of modified model and the result shows that the relative error of DP is within 7%. The physical meaning and accuracy of aging assessment are improved by model derivation and modification of influencing factors. [ABSTRACT FROM AUTHOR]

Methanol concentration as an aging indicator can assess cellulose aging and estimate cellulose degree of polymerization (DP). Despite the advantages of methanol (MeOH), its major disadvantage is that its concentration in the oil decreases after some time. This point is called the MeOH peak in this article. Therefore, using this indicator when MeOH concentration is reduced leads to incorrect results. When using methanol, the main problem is that whenever the methanol concentration in a transformer is measured, it cannot be identified that the measured concentration belongs to the left or right side of the MeOH peak. If the measured concentration belongs to the right side of the MeOH peak, the estimated DP is incorrect. In this article, an empirical equation is established to estimate the DP value as a function of methanol concentration when methanol concentration belongs to the left side of the MeOH peak. Then, a new index called methanol peak detector index (MPDI) composed of a 2-furfural/MeOH ratio and normalized DP is presented to ensure the validity of the calculated DP value. If it is found that the measured concentration belongs to the left side of the MeOH peak, then the estimated DP by the presented equation is valid. Finally, the application of this method is verified by applying it to measurement data samples indicating the validity of the method. [ABSTRACT FROM AUTHOR]

The generation and distribution of furfural are significantly affected by moisture content in the insulating paper. However, the diffusion mechanism of furfural under moisture effect is not clear, hence, this study investigates the effect of moisture on the diffusion characteristics of furfural by combining macro experiment and micro molecular dynamics simulation. The simulation results demonstrate that the increased moisture content in paper accelerates the diffusion of furfural from paper to oil, which is also proved by the experimental data. Then, the results of interaction energy analysis indicate that the increase of moisture enhances the van der Waals force between oil and furfural. The present findings are expected to improve the theoretical level of furfural analysis, which will facilitate the aging evaluation of the transformer insulating paper based on furfural. [ABSTRACT FROM AUTHOR]

The space charge effect of transformer insulating paper will distort its internal electric field, and its space charge effect will be more prominent under extremely complex working conditions. At present, the micromechanism of charge transport and electric field distortion characteristics of paperboard are not clear under complex working conditions. So in this article, based on the bipolar carrier transport (BCT) model and the dynamic carrier balance model, the effects of high temperature, aging degree, moisture content, and bent degree on charges accumulation in paperboard are studied under dc high voltage by numerical simulation and the measured data needed for simulation. The results show that the higher temperature strengthens the carrier migration, deepens the injection depth of the charge, and aggravates the distortion of electric field intensity in paperboard. The more extended the aging time of paperboard, the greater the internal trap density and the deeper the trap depth, which lead to charges migration difficultly. Increasing water content in the paperboard will accelerate space charges to reach a steady state, while further increasing it will slow down this process, which is related to the shallow trap getting deeper. When the critical part of paperboard is extruded, many traps are introduced, resulting in charges accumulation seriously. The research results can reference the design of paperboard and the maintenance of transformer insulation system. [ABSTRACT FROM AUTHOR]

This article is aimed at quantifying the health condition of the power transformer insulation system through its frequency-domain dielectric characteristic by using the concept of the resistor and fractional calculus. In this regard, the dielectric model of the fractional Poynting–Thomson (PT) is proposed, and a mathematical model for parameter identification of the proposed model is presented. The shuffled frog leaping algorithm (SFLA) is used to realize the parameter identification and the fractional PT model parameters of the oil-paper samples under different insulation health conditions. The influence of moisture and aging on the fractional PT dielectric model parameters is experimentally studied. Results show that, with the increase in the water content within the insulation system, the parameters of the fractional PT model gradually decrease, and there is a strong correlation between the relaxation time and the water content. This facilitates the employment of the fractional PT model parameters to quantify the aging and moisture content of the power transformer insulation system. [ABSTRACT FROM AUTHOR]

The traditional method for transformer moisture diagnosis is to establish empirical equations between feature parameters extracted from frequency domain spectroscopy (FDS) and the transformer’s moisture content. However, the established empirical equation may not be applicable to a novel testing environment, resulting in an unreliable evaluation result. In this regard, it is acknowledged that FDS combined with machine learning is more suitable for estimating moisture content in a variety of test environments. Nonetheless, the accuracy of the estimation results obtained using the existing method is limited by the algorithm’s inability to generalize. To address this issue, we propose an AdaBoost algorithm-enhanced back-propagation neural network (BP_AdaBoost). This study creates a database by extracting feature parameters from the FDS that characterize the insulation states of the prepared samples. Then, using the BP_AdaBoost algorithm and the newly constructed database, the moisture estimation models are trained. Finally, the results of the estimation are discussed in terms of laboratory and field transformers. By comparing the proposed BP_AdaBoost algorithm to other intelligence algorithms, it is demonstrated that it not only performs better in generalization, but also maintains a high level of accuracy. [ABSTRACT FROM AUTHOR]

This paper focuses on the in-depth analysis of the physical mechanism of the broadband frequency domain spectroscopy of oil-paper insulation. The complex permittivity shows two low-frequency dispersion phenomena, and the real part of the complex conductivity exhibits two slope changes under the synergistic effect of aging and moisture. The two slope changes are mainly attributed to the migration characteristics of water molecules and polar aging products with a degradation of the oil-paper insulation, resulting in the transition of the frequency dependence between the DC conductivity and AC conductivity. When the oil-paper insulation deteriorates seriously, the imaginary part of the dielectric modulus shows double relaxation peaks. Physical models of parasitic capacitance and molecular polarity interface polarization are proposed to reveal the physical mechanism of the double relaxation peaks. The left peak of the double relaxation peaks is caused by the accumulation of water molecules and polar aging products at the electrode/insulation interface, and the right peak is due to the charge disturbance of the cellulose molecular chain surface. This paper can provide theoretical support and technical guidance for the condition diagnosis and evaluation of oil-paper insulation. [ABSTRACT FROM AUTHOR]

This paper investigates the behavior of interface charges between oil and oil immersed paper insulations in unaged and aged samples. Combined accelerated thermal and electrical aging experiments of oil immersed paper insulations are conducted to obtain aged oil and aged paper samples. The interface charges between oil and paper samples with different aging status are measured with the Pulsed Electro-acoustic (PEA) method. Zeta potentials in samples with different aging status are determined. It is shown that the amount of interface charge increases with the aging duration, and does not follow the prediction of Maxwell-Wagner-Sillars (MWS) law. This is explained in terms of the increase of the interface charge barrier due to the effect of electric double layer. It is proposed that interface charge may act as an optional characterization parameter for the assessment of oil immersed paper insulations. [ABSTRACT FROM AUTHOR]

Traction transformers are one of the most important equipment in the traction power supply system. Thermal aging of transformer insulation system determines its reliable life. To achieve an estimation of the insulation life of traction power transformers operated under real load condition, the effects of traction loads on the thermal aging of oil-paper insulation in traction transformers were investigated. First, the design principles for the accelerated thermal aging experiment were studied and proposed by considering magnitude (i.e., load rate) and frequency (i.e. spare time and lasting time) of the traction load. Then, an experimental system was established in the laboratory to conduct extensive accelerated thermal aging experiments, in which the traction loads were mimicked by using positive temperature coefficient (PTC) heating plates and a programmable logic controller (PLC). Finally, the experimental results were analyzed and discussed to reveal the effects of traction load on the thermal aging of oil-paper insulation in traction transformers. [ABSTRACT FROM AUTHOR]

Moisture accumulates with the growing aging progress of oil-paper insulation and further shortens the remaining life of the transformer. The frequency-domain spectroscopy (FDS) technique can be used to realize the moisture estimation. However, the moisture estimation results would be unreliable once the aging effect on FDS was ignored. Given this issue, an alternative model including the aging effect is thus proposed using FDS and intelligent algorithm. In this work, the feature parameters of FDS data are used to build the databases for characterizing the aging degree and moisture. Then, the moisture estimation models are developed using the weighted K-nearest neighbor (K-NN) algorithm. The accuracy and applicability of the proposed models are finally discussed in laboratory and field conditions. In that respect, the findings reveal that the reported model is available for moisture estimation of transformer oil-paper insulation under various aging degrees and test temperatures. [ABSTRACT FROM AUTHOR]

The influence of nonuniform aging has not been considered in the prediction of the frequency domain spectroscopy (FDS) of the transformer oil-paper insulation (OPI) when using the finite element method (FEM). Given this issue, the modified simulation model was constructed based on the XY model and FEM. In the current work, the dielectric response property of the pressboards with different aging conditions in the modified model was characterized by its dielectric response parameters measured in the lab. Then the modified simulation model constructed in a 3-D system would be applied to study the effect of both nonuniform aging and the axial geometry on the FDS of OPI. Finally, the feasibility of the proposed models was verified by comparing the measured FDS and the predicted FDS. This article is expected to provide a model for predicting the FDS of the transformer OPI including the effect of nonuniform aging. [ABSTRACT FROM AUTHOR]

Oil impregnated paper in power transformers deteriorates in long-term operation, which leads to the variations of its dielectric characteristics. This paper focuses on investigating the generation mechanism of the dielectric processes in oil impregnated paper and their variations with thermal aging. Firstly, a set of thermally stimulated current tests with bias-voltages were conducted in distinguishing the dielectric processes and revealing their generation mechanism. Secondly, the standard thermally stimulated current spectrum and the M″ spectrum of 0–1000 h aged samples were joint analyzed in investigating the variations of dielectric processes in thermal aging process. Finally, additional experiments of moisture, acidity and microscopic observation were conducted in explaining these variations. It is concluded that three dielectric processes can be found in oil impregnated paper, i.e. the dipole polarization, the interfacial polarization and the electric conduction. These processes are all strengthened with thermal aging. The generation of molecules with strong polarity, the structural changes in insulating paper, and the generation of hydrogen ions are responsible for the strengthening of these processes sequentially. This investigation on distinguishing dielectric processes and obtaining their mechanism can promote further understanding on oil impregnated paper and provide information for insulation design in power transformers. [ABSTRACT FROM PUBLISHER]

As sugar is an important intermediate in the early stage in the degradation of cellulose, this paper proposes to use the concentration of total sugar as an indicator of the degree of aging of insulating paper in an oil-paper insulation system. The oil-paper insulation system was simulated at 90, 100 and 110°C, and total sugar concentration in insulating paper and in transformer oil was measured by spectroscopy. The spectrum of sugar reaction was obtained by spectrometer, and TQ Analyst software was used to process the data. Our experiments have shown that the total sugar concentration increases significantly in the early stage of aging, and there is a linear relationship between the logarithm of total sugar concentration and the degree of polymerization. We obtained the relationship between absorbance and total sugar concentration using the partial least square method and the regression goodness of fit is better than 0.91. [ABSTRACT FROM AUTHOR]

The application of vibration-based condition monitoring methods to power transformers has shown the potential for detecting mechanical transformer failures. The ageing of winding insulation paper, which is a common problem in long-serving power transformers, affects both the electrical and mechanical strength of the windings. This paper is concerned with the vibration features of winding disks with aged insulation paper. The vibration characteristics of single-layer winding disks wrapped with insulation paper are investigated. By examining the vibration frequency responses of winding disks with different degrees of ageing of insulation paper, the effects of aged paper on the vibration behaviors of winding disks are demonstrated. The experimental results show that changes in the vibration responses of winding disks can be related to the ageing of insulation paper, and thus it is possible to detect this failure mode in a power transformer using a vibration-based method. A qualitative explanation for these changes is presented, using the degradation of the mechanical strength of the insulation paper. [ABSTRACT FROM AUTHOR]

Oil-paper insulation ageing of transformer has characteristics of spatial locality due to uneven temperature distribution. The transformer is sealed, it is difficult to obtain the local ageing state of oil-paper insulation by sampling directly. Currently, there are no effective detection method to detect the insulation state of local regions. The oil-immersed paper resistivity inversion method can nondestructively assess the local state of oil-paper insulation. However, the current inversion methods still have shortcomings and need to be improved. In this paper, combining the back propagation neural network (BPNN) and Newton downhill method (NDM), an improved inversion method is proposed to optimize the current inversion method, so as to reduce the effect of initial value on it and make calculated results converge better. Finally, a 3D 10 kV transformer model is established to verify the effectiveness of the proposed method. The resistivity calculated by the improved method show that the method can provide initial resistivity values for technicians and improve the convergence and accuracy of current inversion method, which is more suitable for extending to the engineering practice. [ABSTRACT FROM AUTHOR]

This paper presents an improved method for detecting methanol and the concentration of methanol in transformer oil-paper. Acetonitrile is used as an extractant, and methanol is detected by gas chromatography-mass spectrometry. Experiments show a linear correlation coefficient of this method that reaches 0.99 and the minimum detected concentration of methanol in transformer oil can be as low as 5.57 μg/L. In order to investigate the relationship between the methanol concentration and the degree of aging of insulating paper, an oil-paper insulation simulation system is designed. The experiment shows that there is a linear relationship between the logarithm of methanol concentration and the degree of polymerization, the linear correlation coefficient is greater than 0.94. An actual oil sample from a transformer is used to show that the method can be used to further study the methanol concentration. [ABSTRACT FROM AUTHOR]

The life expectancy of a transformer is closely related to the ageing state of its paper insulation. This paper presents novel markers for ageing characterization of paper insulation in oil-filled transformers based on the dispersion staining colors of cellulose fibres. Accelerated thermal ageing experiments were performed for oil-paper specimens at 120 and 130 °C to obtain aged oil-paper samples of different ageing degrees. The average degree of polymerization (DP), crystallinity index, and refractive index of insulation paper were measured; the experimental results show that an increase in refractive index of insulation paper was observed with the increase of ageing degree. Meanwhile, the dispersion staining colors of cellulose fibres in oil were observed using dispersion staining method; the experimental results show that the refractive index of cellulose fibres detached from insulation paper increases with the increment of ageing degree of insulation paper. Finally, two ageing markers—that is, the primary color ratio-based ratio of blue to red and the primary color ratio-based Mahalanobis distance were presented. Their relationship with DP and ageing time of insulation paper were obtained, and were compared with the corresponding relationship with 2-furaldehyde (2-FAL) and carbon oxides. The proposed ageing markers demonstrate an advantage over 2-FAL and carbon oxides and show potential in ageing state evaluation and residual life prediction of paper insulation in transformers. [ABSTRACT FROM AUTHOR]

In order to develop a novel detection method for the degree of polymerization (DP) of insulating papers, methanol was used as an indicator to explore the relationship between methanol concentration and DP in this paper. After extraction from oil, the methanol was oxidized and reacted with chromotropic acid to generate a purple-red compound. The spectral detection method was used to detect the concentration of methanol by absorbance, and then, the corresponding relationship between the concentration of methanol and the DP of insulating paper was established. Moreover, the detection methods based on furfural and methanol were compared. The results showed that methanol appeared during the initial aging period of the insulation paper, and the linear relationship between the methanol concentration and the DP of insulating paper was good. Compared with furfural, methanol was more sensitive to the change of DP in the early aging period, which proved that methanol could be used as a new type of indicator of insulating paper. [ABSTRACT FROM AUTHOR]

The mechanical performance of two commercial papers used as solid insulation in power transformers, namely standard Kraft and a thermally upgraded Kraft paper, were studied during accelerated aging in Luminol oil at 170 ?C. The results show a relationship between the degree of polymerization and the mechanical properties measured by tensile testing. A linear relationship was found between the mechanical properties of paper, the tensile index (Tidx), and the concentration of methanol present in the oil. The methanol chemical marker has been proven to be an accurate assessment tool for the aging of cellulosic paper. The results show a promising tool for correlating the methanol concentration in oil, as an indirect indicator, with the mechanical performance of the paper. This approach can be used to monitor the real state of the cellulose chains in the power transformer insulation paper. [ABSTRACT FROM AUTHOR]

Furfural content in oil is widely accepted as an effective parameter to mirror aging of insulation paper. However, pressboards are also abundant in transformers, which are always neglected in furfural analysis. Different masses of insulation paper and pressboard produce different amounts of furfural during the aging process. Thus, the furfural content in oil may differ in systems with different oil-paper-pressboard mass ratios. To address this problem, accelerated thermal aging experiments and furfural equilibrium experiments with different oil-paper-pressboard mass ratio systems were conducted under laboratory conditions. Furfural contents in oil, paper, and pressboard were measured. In a simplified oil-paper system, the furfural content in oil differs in systems with different oil-paper mass ratios. Further analysis shows the furfural amount produced by 1 g insulation paper is the same with good repeatability in groups with different mass ratios. Different oil-paper mass ratios change the distribution coefficient of furfural between oil and paper, and an increase in the mass of insulation paper leads to more furfural remaining in the insulation paper. The pressboards in field transformers produce little furfural during the aging process, but absorb part of the furfural from oil, which decreases the furfural content in oil. Therefore, more pressboard in an oil-paper-pressboard system indicates lower furfural content in oil. An increase in insulation paper in the oil-paper-pressboard system causes a decrease in the effect of pressboard on furfural content in oil. [ABSTRACT FROM AUTHOR]

Historical papers are often locally damaged by exogenous influences and/or have endogenously degraded paper areas. The stabilization of such papers is very important because further use of the object can cause additional damage. Different types of nanocellulose are interesting as a novel stabilizing materials for paper due to their close structural relation to the paper matrix. Therefore, the present study investigated whether the treatment of historical papers with nanocellulose suspensions is a novel method for paper stabilization. Two different types of nanocelluloses, bacterial cellulose and a mechanically nanofibrillated cellulose based on wood pulp, were tested with regard to their performance in stabilizing fragile papers. Concerning material handling and application in conservation steps, different ways to modify the suspensions were tested. The resulting suspensions were applied to historical papers from several centuries with different extents of damage. The paper-nanocellulose composites were characterized with regard to their optical and microscopic integrity and by physical and chemical analyses. The treatment of mechanical damage and the consolidation of weakened paper areas could be realized by the application of a nanocellulose suspension without an additional adhesive. The results of the treatment depend on the type of nanocellulose, on the paper material, on processing and application techniques. The paper discusses the applicability and stability of the differently prepared nanocellulose suspensions, also with regard to their mode of application and long-term performance. Advantages and limitations are addressed in detail. [ABSTRACT FROM AUTHOR]

The article concerns the presence of water in insulating systems consisting of cellulose materials impregnated with different electro-insulting liquids. This is a particularly important issue regarding power transformers with their strategic importance for an electrical power system. Water is a serious threat and can be the reason of a dangerous breakdown. Thus there is a need to have insulating system diagnostics in terms of water content. The article discusses the issue of water solubility in different electro-insulating liquids. The author determined the water saturation limits for these liquids. Moreover, the author determined water sorption isotherms for cellulose materials of different aging degree. On the basis of the obtained results, equilibrium curves were constructed for some selected kinds of insulation. The research results presented here allow to improve the reliability of determining moisture in cellulose insulation of various polymerization degree on the basis of water content measurement in an electro-insulating liquid. [ABSTRACT FROM PUBLISHER]

The paper presents the results of a comparative study on accelerated aging of specially designed experimental transformers and their corresponding laboratory models. The experimental transformers are 300 kVA, with insulation in line with medium size and large mineral oil immersed power transformers, having different initial water contents in the standard Kraft paper insulation of ca. 1 and 4 %. These transformers were subjected to the rated current and voltage conditions, operating in the irregular parallel operation, whereby the temperature of windings were measured with fiber optics sensors and kept at 105 °C for 460 days. Each transformer was equipped with a removable tank which allowed access to the outer surface of the HV windings. Laboratory experiments were simulating experimental transformers and were performed in Erlenmeyer flasks, containing oil, paper materials, copper and iron in the same proportions as in the active part of the experimental transformers. The parameters that were monitored during aging were the following: degree of polymerization of paper, hot-spot temperature of transformers, water content in paper, and water and furans content in the oil. Estimations of water content in solid insulation of experimental transformers using frequency domain spectroscopy and the Perrier-Lukic moisture equilibrium chart were performed. The experimental results show that shortening of the insulation life, defined by the value of degree of polymerization, increased 2.5 times with increasing moisture content in the cellulose from ca. 1 to 4 %. For both experimental transformers and laboratory models, the relationships between the paper degree of polymerization and the furans content for dry and wet insulation was developed and is presented in the paper. [ABSTRACT FROM AUTHOR]

Vegetal oils are considered a suitable substitute for mineral oil that is widely used in power transformers as insulation and cooling medium. Due to the fact that more and more power transformers containing this alternative insulating fluid are being constructed a mathematical ageing models is needed to help predict transformer failures. The continued performance of power transformers depends on the condition of its paper insulation mainly. In this sense, this paper analyses Kraft paper degradation through the loss of its mechanical strength. Accelerated thermal ageing test of the paper in two different vegetal oils were carried out at three temperatures during diverse periods of time, in order to obtain information on the kinetics of the ageing degradation of the paper. The evolution of the mechanical properties of paper failure are analysed as a function of temperature and ageing time. In addition, the results obtained are compared with the traditional method of degradation analysis, based on the measurement of the degree of polymerisation. [ABSTRACT FROM AUTHOR]

Age and Ageing is now inviting papers on healthcare improvement for older people. In this article we outline the nature and scope of healthcare improvement and reference improvement models and the tools and methods of improvement science. We emphasise the issues of sustainability, including scale and spread; evaluation – including associated ethical consideration and the involvement of patients and the public in healthcare improvement and associated research. Throughout we refer to resources the authors have found useful in their own work, and provide a bibliography of sources and web-links which will provide essential guidance and support for potential contributors to this new category of submission to Age and Ageing. [ABSTRACT FROM AUTHOR]

In this work, samples of oil-immersed paper with different moisture levels and aging condition were studied. Frequency domain spectroscopy (FDS) of the samples was examined at 40 °C under different excitation voltages. A non-linear phenomenon in frequency domain dielectric response with different moisture contents and aging condition was observed. The non-linear phenomenon appears to be related to the hindrance effect of cellulose on the movement of ions and the Poole-Frenkel effect on the concentration of ions. With aging, the nonlinear loss peaks at different frequencies caused by the effect of nonlinear conductance and interface polarization appear in the FDS results. The non-linear phenomenon was modeled and verified experimentally. The characteristic parameters and quantitative method to estimate moisture content and the degree of aging degree of oil-immersed paper can be obtained by the proposed method. [ABSTRACT FROM AUTHOR]

The applicability of using 2-furfural (2-FAL) and methanol as aging markers for synthetic ester impregnated paper insulation was investigated through laboratory aging experiments at temperatures of 80, 100 and 120 ?C. Methanol in the synthetic ester increased linearly with paper aging until degree of polymerisation (DP) reached 400. During this period concentration of methanol in oil was higher than that of 2-FAL, which proved the concept of using methanol to indicate early paper aging in the synthetic ester. However, the rate of methanol increase against the reduction of DP in the synthetic ester was about three times higher than that seen in mineral oil. This is due to a difference in the partitioning of the marker between oil and paper. Since the synthetic ester is more polar than the mineral oil, it attracted more methanol molecules from the paper, resulting in a higher concentration of methanol in oil for the same reduction of DP. In addition, a reduction in methanol was observed at the later stage of paper aging at 120 ?C. This could be due to either a change in the partitioning between oil and paper, or an esterification reaction which consumes methanol in the system. [ABSTRACT FROM PUBLISHER]

In this work, thermal aging aspects of mineral oil, ester oils (synthetic and natural), mixed oil have been reported. All the samples were thermally stressed at 110°C, 140°C, 160°C, and 185°C for 2 weeks each. Concentration of dissolved decay contents in oil, flash point of insulation oil, and linear thermal expansion coefficients of solid insulation with aging have been studied using ultraviolet visible spectroscopy, flash point and dilatometry analysis respectively. Change in functional groups of the insulation oils with aging have been understood by Fourier Transform Infrared Spectroscopy analysis. Additionally, diffusion of oil-moisture mixture into paper with aging and corresponding effect on dielectric strength of paper has been also examined. Further, design and monitoring aspects of ester and mixed oil filled transformers have been also emphasized. It is observed that ester dielectric fluids and ester content as an additive in mineral oil improves the performance of solid insulation. Importantly, blended oil offer an advantage of retarding the degradation of oil as well as solid insulation accompanied by reduced cost of oil when compared to pure synthetic esters. [ABSTRACT FROM AUTHOR]

The effects of aging on response time were examined in a paper-based lexical-decision experiment with younger (age 18-36) and older (age 64-75) adults, applying Ratcliff's diffusion model. Using digital pens allowed the paper-based assessment of response times for single items. Age differences previously reported by Ratcliff and colleagues in computer-based experiments were partly replicated: older adults responded more conservatively than younger adults and showed a slowing of their nondecision components of RT by 53 ms. The rates of evidence accumulation (drift rate) showed no age-related differences. Participants with a higher score in a vocabulary test also had higher drift rates. The experiment demonstrates the possibility to use formal processing models with paper-based tests. [ABSTRACT FROM AUTHOR]

Furfural content in oil is a valuable indicator of cellulose paper degradation and is widely utilized in aging assessment for power transformers. However, with the same aging degree of insulation paper, the actual furfural content in oil is influenced by temperature because furfural partitioning behavior in the oil-paper insulation system of power transformers changes with temperature. Thus, correction of the temperature effect on furfural partitioning is crucial for accurate assessment of the aging of power transformers. In this research, oil-paper samples with different furfural contents were prepared through an accelerated thermal aging test. A furfural equilibrium experiment was conducted at different temperatures to construct a furfural partitioning diagram. The mass fraction of furfural in oil and paper was calculated. Results showed that the mass fraction of furfural in oil increases with temperature rising and aging deepening, which means that furfural tends to migrate from paper to oil at high temperatures and deep aging conditions. The change in furfural partitioning between oil and paper at different temperatures causes a deviation in paper aging assessment. To correct the temperature effect on furfural partitioning, a furfural correction factor was developed to normalize furfural contents in oil at different temperatures to a reference temperature. The furfural correction factor was verified by experimental data and then introduced into the relation between degree of polymerization of paper and furfural content of oil. Verification results showed that the corrected equation can enhance the accuracy of paper aging estimation at different temperatures. The findings of this work indicated temperature effect on furfural partitioning should be considered when determining the furfural thresholds and evaluating the aging condition of power transformers. [ABSTRACT FROM PUBLISHER]

The degradation of oil-impregnated paper induced by partial discharge (PD) seriously affects the life of power equipment. In order to investigate the relationship between partial discharge and the degradation of oil-impregnated paper, PD characteristics and trap parameters of the impregnated paper are measured. In this work, a cavity discharge model is adopted and samples with different degrees of polymerization (DP) are fabricated using thermally accelerated aging to simulate transformers with different lifetimes. For each sample, phase resolved partial discharge (PRPD) spectrograms are recorded for various partial discharge times. The characteristics of partial discharge are analyzed, and the trap parameters of specimens are obtained by the thermally stimulated depolarization current (TSDC) method. Following this, the microstructures of the samples are observed using a scanning electron microscope (SEM). It is found that the damaging breakdown process of oil-immersed paper can be divided into three stages: initial stage, developing stage and pre-breakdown stage. There also exist two levels of trap on the surface of oil-impregnated paper: shallow (0.10-0.59 eV) and relatively deep (0.60-0.90 eV) energy. Importantly, the thermal aging makes the trap energy deeper while electrical aging makes the trap energy shallower. [ABSTRACT FROM AUTHOR]

The traction transformer of a high-speed railway is long-term subjected to the effects of impulse traction loads, such that the aging status of a multilayer insulation paper between high and low voltage windings is non-uniformly distributed due to the non?uniform distribution of temperature. To enhance the use of the frequency domain dielectric spectroscopy (FDS) method in engineering, this paper studies the effects of non-uniform thermal aging on the frequency domain dielectric spectrum of multilayer insulation paper. Based on the experimental designs and preparation of experimental materials, the frequency domain dielectric spectrum of a multilayer insulation paper with uniform and non-uniform thermal aging distribution was tested. Afterwards, the effects of non-uniform thermal aging on the frequency domain dielectric spectrum of multilayer insulation paper were discussed and analyzed based on the tested results. The results show that: 1) The effects of the non-uniform distribution of DP (cellulose structure) can be ignored. The non-uniform distribution of the aging byproducts (except moisture) has limited effects on the tested results, which is far less than the effects of moisture. The non-uniform distribution of moisture is the dominant factor and affects the results. 2) In terms of insulation paper with a defined aging status, its order in the multilayer insulation paper does not affect the tested results. 3) The tested results of the insulation samples with a non-uniform aging distribution can no longer reflect the moisture content of the wettest section, and the evaluated moisture content is slightly higher than the average moisture content of the multilayer insulation paper. [ABSTRACT FROM PUBLISHER]

Aging of transformer paper insulation is commonly investigated through indirect measurements conducted in the oil, e.g. furanic compounds. In addition to the conventional indicators, recent investigations showed that alcohols like methanol and ethanol in oil could be used as paper aging indicators. This paper focuses on the applicability of these new paper aging indicators in a novel, gas-to-liquid (GTL) technology based transformer oil through an accelerated laboratory aging experiment. The experiment was conducted at 120 °C for up to 280 days. A conventional mineral oil was also tested as a reference. Kraft paper aged in both oil types showed similar reductions in degree of polymerization (DP) and tensile strength (TS). Amount of methanol in oil is higher than that of 2-FAL in oil when DP is over 375, confirming the promise of using methanol as an early paper aging indicator. Both the new paper aging indicator, methanol and the conventional paper aging indicator, 2-FAL are applicable for the GTL oil without any modifications. In addition, oil only aging experiments showed that oil does produce methanol but it is negligible compared with oil paper aging experiment; however the amount of ethanol measured in the present oil paper aging experiment is believed to be originated from oil oxidation rather than from paper aging. [ABSTRACT FROM PUBLISHER]

Voltage-time (v-t) characteristic plays an important role during the insulation coordination of a power system. Power transformer is the crucial equipment in the design of a reliable power system. During the operation of a transformer, Oil Impregnated Paper (OIP), the widely used winding insulation of transformer, undergoes significant irreversible aging. Aging alters the dielectric properties of the OIP reducing it's withstand capability. Hence in this work, the impulse v-t characteristic of fresh OIP and 8 years service aged OIP of the same manufacturer are compared. Moreover, when the transformers are directly connected to Gas Insulated Substations (GIS) and during the switching operation of vacuum circuit breakers, OIP is stressed by Very Fast Transient Overvoltage (VFTO). In addition, transformers are subjected to repeated impulses generated during multiple lightning strokes, switching operations of circuit breakers and HVDC converters. Various studies have pointed out the adverse effect of VFTO and repeated impulses on transformer insulation. Therefore, the effects of VFTO and repeated impulses (both LI and VFTO) on the v-t characteristics of fresh and service aged OIP are quantitatively assessed and discussed with reference to the Basic Impulse Insulation Level (BIL) and protection level of the transformer insulation. [ABSTRACT FROM AUTHOR]

The long-term effect of gamma irradiation on paper was studied. Three types of paper (pure rag, mixed rag and mechanically prepared woodpulp) were subjected to three treatments: gamma irradiation, accelerated dry aging, and radiation followed by aging. The effects of these treatments on the physical properties of the paper samples were assessed by measuring alterations in mechanical strength as determined by changes in folding endurance and tear resistance when compared to the untreated control samples. It was found that gamma irradiation caused a decrease in the mechanical strength of the papers similar to that resulting from accelerated dry aging. A synergistic effect was found when both irradiation and accelerated aging were performed on the paper samples, demonstrated by an even greater decrease in both fold endurance and tear resistance than that resulting from either gamma irradiation or accelerated dry aging alone. [ABSTRACT FROM AUTHOR]

Abstract: A set of inks was analyzed using Py/GC/MS technique. They were prepared following some ancient Armenian recipes and then analyzed after being dried in air to obtain solid samples. A simple analytical procedure was adopted which excludes any treatment of the samples and consists in introducing the solid sample directly into the injector of the furnace pyrolyzer. Inks were also written on whatman paper by calamum and analyses of papers containing ink were carried out. A real sample analysis was reported. Comparing the pyrograms it was possible to discriminate fragments derived from ink, from that formed by the decomposition of paper by the influence of ink. In order to understand the origin of the fragments formed during the pyrolysis of inks the standard compounds used to prepare them were carried out, too. [Copyright &y& Elsevier]

Thermal aging of insulation paper occurs during transformer operation, with the water produced during aging accelerating the thermal aging process. Insulation paper aging largely determines the operational life of a transformer pressboard; accordingly, research pertaining to insulation paper enhancement is significant with respect to the functional safety of transformers. Within molecular research, particularly that focusing on molecular simulation, appropriate force field selection is paramount in order to acquire accurate results, in addition to appropriately reflecting cellulose thermal stability and associated degradation mechanisms. In the current study, two diverse cellulose models (water only; water, dicyandiamide, melamine and polyacrylamide) are developed and analyzed. Numerous model variables, including the diffusion coefficient of water and cellulose chain distance, are collated, in order to examine the effects of amines on the thermal stability of cellulose. Additionally, a novel insulation paper is formulated by combining traditional insulation paper with three diverse amines; an accelerated aging experiment is thus undertaken, comparing traditional and modified insulation paper samples at 110 °C, together with periodic assessment of both microwater content and the degree of polymerization (DP). Results indicate that during transformer operation, a higher degree of elasticity is associated with the modified insulation paper, thus significantly increasing its toughness and extensibility, in parallel with decreasing it brittleness. Results also show that the DP associated with cellulose comprising the modified insulation paper decreases at a reduced rate, with measured water content significantly less than that of traditional insulation paper. Simulation results are consistent with experimental findings. Therefore, it may be concluded that the thermal aging properties of cellulose significantly improve upon addition of dicyandiamide, melamine, and polyacrylamide as thermal stabilizers. [ABSTRACT FROM AUTHOR]

Due to its excellent performance, oil-paper insulation has been widely used in many power apparatuses including converter transformer of high voltage direct current (HVDC) system. Space charge accumulation phenomena may significantly distort local electric field inside transformer and cause oil-paper insulation overstressing. As a result of long term operation, oil-paper gradually degrades. In most severe cases, the breakdown of insulation system may occur. In this work, the effect of space charge on breakdown characteristics of aged oil-paper insulation is investigated. Oil-paper samples with different aging states are obtained by thermally accelerated aging for various periods of time, categorized by the degree of polymerization (DP) of 1107 (new), 725, 504, 376 and 241, respectively. Experimental results show that the breakdown voltage of oil-paper samples without pre-stressing remains almost constant with thermal degradation. After the homo-polarity pre-stress, when the DP value is higher than ∼300 (from 1107 to 376), the breakdown voltage has an increasing tendency with an increase in thermal degradation. On the contrary, the breakdown voltage presents a decreasing tendency after the hetero-polarity pre-stress. When the DP is lower than ∼300 (DP241), the changes of breakdown voltage does not remain the same trend as previous samples after pre-stressing. Meanwhile, space charge distributions in different aged samples are measured by the pulsed electro-acoustic (PEA) method, and the trap parameters are correspondingly evaluated. It has been experimentally demonstrated that special attention should be paid to space charge accumulation and aging state of oil-paper insulation, which may lead to severe insulation accidents. [ABSTRACT FROM AUTHOR]

The relation between ageing and space charge is a hot area, but there is little direct evidence. In this paper, oil-paper samples were exposed to 20-kV/mm DC electrical field, 130°C temperature or both 20-kV/mm DC electrical field and 130°C temperature separately. Charge transport through them was analyzed at intervals by the pulsed electroacoustic (PEA) method. We find that the quantity of trapped charge increases with stressing durations, no matter what kind of stress oil-paper is exposed to. That indicates that energy release through space charge movement, such as charge trapping/detrapping and recombination, is another reason for traps generation besides deterioration caused by thermal ageing. However, because the difference in cellulose degradation mechanism among them, charge transport dynamics are thereby different under different stressing conditions. Space charge accumulates faster inner electrothermally stressed oil-paper than that inner another two kinds of oil-paper, and the sign of trapped charge is positive if oil-paper is electrically or electro-thermally stressed. The latter behavior is discussed in terms of electromagnetic dynamics due to cavity within oil-paper once there is external electric field. [ABSTRACT FROM PUBLISHER]

A new biodegradable dielectric fluid for transformers, palm fatty acid ester (PFAE), with better cooling performance and oxidation stability than conventional mineral oil (MO) was developed in 2008. The aging of thermally upgraded paper (TUP) in PFAE was evaluated, comparing to MO and natural ester (FR3). The electrical properties of aged dielectric fluids were compared. Sealed aging SUS tanks containing copper, silicon steel, TUP, and PFAE, MO and FR3 (partly) in a nitrogen environment were aged at 130 °C-170°C for 20-120 days, with low concentrations of oxygen and moisture strictly controlled. Paper degradation after aging was determined using the degree of polymerization measurements. The gas production characteristics during the aging process were also compared. The results show that the TUPs in PFAE age at slower rates than those in MO, while at faster rates than those in FR3. Under the possibly low initial concentration of oxygen and water in the fluids in the absence of other material which may produce water during aging process, the limit service temperature for TUP in MO and PFAE with expected 30-year lifetime (DP450) would possibly reach 109°C and 113°C, respectively. Life estimation results show that the lifetime of the TUP in PFAE aging at 110°C would be at least 1.6 times the lifetime of the TUP in MO, if DP450 was set as the end-of-life point of the TUP. Aged PFAE exhibits highest breakdown voltage among the three types of dielectric fluid. Much lower acid value of aged PFAE than FR3 reveals that PFAE has better hydrolytic stability, which could ensure the safe operation of transformers. The aging mechanism is proposed. [ABSTRACT FROM PUBLISHER]