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The metallurgical sector is one of the most emission- and energy-intensive industries. The possibility of using fossil carbon substitutes has been investigated to reduce the environmental impact of the steelmaking sector. Among others, biochar emerged as a promising fossil coal/coke substitute. We conducted a literature review on biochar use in the metallurgical sector and its potential environmental benefits. The possibility for biochar as a coal/coke substitute is influenced by the source of biochar production and the process within which it can be used. In general, it has been observed that substitution of biochar ranging from a minimum of 5% to a maximum of 50% (mostly around 20–25%) is possible without affecting, or in some cases improving, the process, in coke making, iron sintering, blast furnaces and electric furnaces application. In some studies, the potential CO2 reduction due to biochar use was estimated, ranging from 5% to about 50%. Despite there still being an area of further investigation, biochar appeared as a promising resource with a variety of uses in the metallurgical sector, contributing to the lowering of the environmental impact of the sector. [ABSTRACT FROM AUTHOR]

In order to achieve more effective and inclusive environmental and economic benefits, local industrial symbiosis programs need to be expanded to a regional scale. Research on regional industrial symbiosis (RIS) covers technical and non-technical aspects that have not yet been studied in detail. The goal of this paper is to identify the main topics and trends in this field of research. After proofreading of 956 Scopus-indexed documents extracted by keyword-search, 112 papers were selected as the core literature for the quantitative review. The sample represents a 22-year period (1997–2019), with over 63% of the articles published since 2015. The majority of case studies (64%) took place in Europe, China, the USA, and Australia. By applying social network analysis (SNA), keyword co-occurrence relations were investigated in the Gephi environment for distinguishing the main topics. The visualized network has a core-periphery structure. Six main subtopics were detected: industrial symbiosis and regional learning, waste minimization assessments, urban industrial symbiosis (UIS) and life cycle thinking, energy efficiency, operational carriers, and social aspects. Further document clustering demonstrated the division of papers in two groups representing differences in the geographical distribution of case studies, resources to be exchanged, and the organization of networks. The evolution of the sample in recent years was also examined, and its leading edges and weaker dimensions were identified. Additionally, a detailed content review is provided, which led to the mapping of main achievements and software tools under each subtopic. • Regional industrial symbiosis differs methodologically from other resource synergies. • The vast literature on this topic is reviewed based on social network analysis. • Six principal themes are detected in two separate clusters of papers. [ABSTRACT FROM AUTHOR]

[Display omitted] Identify sustainable biological sewage sludge (BSS) management represents a current challenge. In this work, pre-thickened BSS taken from a large-scale urban wastewater treatment plant (WWTP) was fed continuously for about 9 months to a semi-industrial scale thermophilic biological fluidized bed reactor (TBFBR) operating in alternate conditions. The BSS treated in TBFBR was strongly reduced (89–92%) and the production was evaluated in 0.0007–0.0023 kg kg CODremoved −1 d−1 and 0.0004–0.0014 kg kg CODremoved −1 d−1 of TS and VS, respectively. The 92% of the P-PO 4 3- and P-org precipitated in inorganic form and accumulated in thermophilic biological sludge (TBS). In basic soils with chelating activity, phosphorus contained in TBS presented a higher bioavailability (84.0 ± 25.3%) with respect to untreated sludge. The analysis of four diverse scenarios highlighted that TBFBR located after pre-thickening could save 73–96% of operating costs with respect to current situation. [ABSTRACT FROM AUTHOR]

The depletion of nitrogen and phosphorus represents a significant problem. Two real high strength wastewaters were treated by Thermophilic Aerobic Membrane Reactor (TAMR), an advanced biological process, obtaining significant removal of pollutants. Unlike the previous works, this paper does not focus on the optimization of the performance of the TAMR, but it studied the possible reuses of liquid (permeate) and solid (biological excess sludge) matrices to recover organic carbon, nitrogen and phosphorus and promote a circular economy model. The high nitrogen content of permeate can be exploited stripping ammonia with performances higher than 80% in best conditions to produce ammonium sulphate (useful as fertilizer). Moreover, the respiromeric tests demonstrated that permeate can be used in conventional active sludge systems as external source of organic carbon granting similar denitrification rate as methanol. In the sludge residue extracted from TAMR a significant presence of organic carbon and phosphorus (as hydroxyapatite) were revealed demonstrating the feasibility of recover this residue in land application. A preliminary management costs estimation showed that TAMR, coupled with a stripping and adsorption system to recover nutrients, is economically sustainable. Image 1 • Chemical oxygen demand (42–78%) and phosphorus (70–79%) were removed. • More than 80% of ammonia in permeate can be stripped to produce ammonium sulphate. • Permeate and methanol allow similar denitrification rate. • Hydroxyapatite was detected in sludge of thermophilic aerobic membrane reactor. • Preliminary management costs analysis highlights the economic feasibility. [ABSTRACT FROM AUTHOR]

Minimizing the biological sewage sludge (BSS) produced by wastewater treatment plants (WWTPs) represents an increasingly difficult challenge. With this goal, tests on a semi-full scale Thermophilic Alternate Membrane Biological Reactor (ThAlMBR) were carried out for 12 months. ThAlMBR was applied both on thickened (TBSS) and digested biological sewage sludge (DBSS) with alternating aeration conditions, and emerged: (i) high COD removal yields (up to 90%), (ii) a low specific sludge production (0.02–0.05 kgVS produced/kgCODremoved), (iii) the possibility of recovery the aqueous carbon residue (permeate) in denitrification processes, replacing purchased external carbon sources. Based on the respirometric tests, an excellent biological treatability of the permeate by the mesophilic biomass was observed and the denitrification kinetics reached with the diluted permeate ((4.0 mgN-NO3−/(gVSS h)) were found comparable to those of methanol (4.4 mgN-NO3−/(gVSS h)). Moreover, thanks to the similar results obtained on TBSS and DBSS, ThAlMBR proved to be compatible with diverse sludge line points, ensuring in both cases an important sludge minimization. [ABSTRACT FROM AUTHOR]