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In this work, the synergistic effect of 3D orthogonal woven structure and asymmetric carbon/glass hybridization on impact response was studied by experimental and numerical methods. The hybrid 3D orthogonal woven (H3DOW) composite plates were manufactured on a home-made 3D weaving machine. Impacts with various energies 42.9, 54.9, 66.9 and 78.9 J were applied to carbon (CG) and glass (GC) sides. The impact response was examined using fracture morphology observation and mechanical curves. Yarn-level finite element models including failure criteria and progressive damage law were established in ABAQUS/Explicit to compare the structural deformation and damage behavior. The impact side significantly influences the failure modes of H3DOW materials. GC specimen failed through delamination between carbon layers at non-impact side and subsequent fiber tensile breakage, whereas the crushing damage in the carbon yarn located in the impact-side and large area debonding between yarn and matrix resin in superficial layers was the dominant failure mode in CG specimen. This caused the CG configuration to exhibit better impact resistance with respect to the perforation threshold energy. [ABSTRACT FROM AUTHOR]