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In the contemporary global discourse on environmental and developmental issues, the dual challenges of sustainable green energy and water supply stand paramount. These elements are vitally intertwined with the socio-economic vitality of the world. Notably, regions plagued by freshwater scarcity are increasingly turning to desalination which consists of a reliable and unconventional water source. The intersection of renewable energy with desalination and water purification processes presents a compelling synergy. This approach is particularly pertinent in areas where freshwater shortages coexist with abundant solar energy availability. Additionally, these technologies boast the advantage of low operational and maintenance costs. This paper delves into the design, optimization and financial analysis of a novel, standalone hybrid energy system, integrating photovoltaic and fuel cell technologies, for an agriculture farm situated in Kairouan, Tunisia. Unlike conventional systems, this model foregoes battery storage in favour of hydrogen storage, generated through water electrolysis powered by solar energy. This system harnesses solar energy for direct electrical power generation and hydrogen gas production. A segment of the generated electricity is allocated to electrolysis for green hydrogen production. In times of solar unavailability, the stored hydrogen is reconverted to electricity via a fuel cell. An intriguing aspect of this system is the utilization of saline well water, which, due to its high salt content, necessitates purification through desalination to prevent damage to the electrolysis unit and to render it suitable for agricultural irrigation. [Display omitted] • The production of green hydrogen, water and electricity for agriculture farm in Tunisia is analyzed. • The Levelized cost of green hydrogen produced in the PV farm is 2.25 €/kg. • A PV hydrogen Farm station with a capacity of 140 kW produces 1991 kg of green hydrogen and 235 MW h of electricity yearly. [ABSTRACT FROM AUTHOR]

This paper sheds the light on the future of green hydrogen in Tunisia. So, a detailed economic assessment and evaluation of the Levelized Hydrogen Cost (LHC) and the Net Profit (NP) of a Photovoltaic (PV) Hydrogen Refueling Station (HRS) are presented and discussed. Tunisia is characterized by its high PV potential which makes the production of electricity from solar energy an effective alternative source. However, due to the regulations and issues related to the connection of medium PV scale to the power grid, the energy produced from renewable sources (RS) is still less than 3% of the total produced electricity. On the other hand, the price of hydrocarbon fuels is still increasing. The gap between production and total demand in hydrocarbons has created a deficit in the primary energy balance. Therefore, the production of hydrogen from solar energy for refueling Fuel Cell Vehicles (FCV)s consists of a promising solution to boost the development of the country, reduce hydrocarbon fuels consumption, and protect the environment. The sizing of a small PV-HRS to produce 150 kg of hydrogen per day shows the necessity to install PV systems with a total Direct Current (DC) capacity of 1.89 MWp. The Initial Cost (IC) analysis shows that while the PV system cost represents 48.5% of the total IC, the IC of electrolysers represents 41%. The storage system cost is approximately equal to 3.2% of the total IC. The LHC is equal to 3.32€/kg with a total IC of 2.34 million €. • An economic assessment and evaluation of PV-HRS producing 150 kg of hydrogen in Tunis are presented. • The LHC for the hydrogen produced at PV-HRS is estimated at 3.32€/kg. • The 150 kg PV-HRS has a breakdown of 8 years for a selling price of 8€ per kg of Hydrogen. • The IC and the LHC depend mainly on the prices of the PV panels, electrolyzers, and storage tanks. • Green hydrogen is a promising solution for future transport systems in Tunisia. [ABSTRACT FROM AUTHOR]