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Glass with different chemical compositions, deriving from separate collection, has been used as fine aggregate to formulate cementitious mortars, substituting natural sand. Glass coming from cathode-ray tube monitors, fluorescent lamps, and crystal glass (from production of home décor items) along with glass deriving from soda-lime glass containers, which has been taken as a reference, have been investigated. Glass solubility has been determined in alkaline environment similar to the one inside the cementitious composite. Alkali silica reaction has been tested on glass modified cement mortar in different accelerated conditions. Mortar samples containing glass with chemical composition different with respect to soda-lime glass are subjected to alkali silica reaction. This behaviour is largely dependent on the ratio among modifier and stabilizer oxides in the glass. The same ratio affects glass solubility and consequently composition of expanding gels when alkali silica reactions take place. [ABSTRACT FROM AUTHOR]

Alkali activation of fly ash can be considered as one of the more promising alternative systems to traditional hydraulic binders, particularly if the process can be carried out at room temperature. With the aim of finding the best solution chemistry for room temperature activation, two types of fly ash have been activated using Na 2 O/SiO 2 molar ratio ranging from 0.12 to 0.20. It was found that the behaviour of the resultant geopolymer and mortars in the fresh and hardened state is more influenced by the type of fly ash, in particular by their fineness and mineralogical composition, than by the increasing proportion of sodium silicate solution in the mix. [ABSTRACT FROM AUTHOR]

Abstract: Recycling industrial waste to produce new materials is a driving path to promote a sustainable development. Alkali activation can be a very effective tool to reach this goal especially when the starting material can be carbon fly ash and blast furnace slag instead of calcined natural clays such as metakaolin. With the aim to further increase the type of waste to be used as precursor and to promote a new recycling route, alkali activated materials based on partial substitution of metakaolin with ladle slag, deriving from the refining process of steel produced by arc electric furnace technology, are reported. In particular, being ladle slag rich in Ca-containing crystalline phases, its effect on the consolidation process has been investigated by means of microstructure analysis carried out with XRD, SEM and MIP techniques. The results show that ladle slag are activated by alkaline solutions and participate in gels formation. Indeed, an optimization in terms of ladle slag content (60–80wt.%) and the coexistence of different types of gels (3D aluminosilicate, C-S-H and Ca-rich aluminosilicate) have been envisaged. [Copyright &y& Elsevier]

Abstract: The effects of bulk composition and microstructure on strengthening mechanisms and fracture resistance were investigated for metakaolin based geopolymers. Crack initiation and propagation under mechanical and environmental stresses were correlated to pore size distribution and bulk composition. Based on IR spectra and porosity analysis, it was observed that capillary pores and the nature of alkali-aluminosilicate hydrated named polysialates (H–M–A–S) determine cracks initiation site in the Al-rich geopolymer samples with low Si/Al molar ratio (range 1.23–1.5). These samples exhibited low flexural strength, Young modulus and Impact toughness as well as delayed failure under environmental stresses. Increasing the Si/Al molar ratio (range 1.79–2.42) improved the flexural strength and Impact toughness. Formation of more polymerized H–M–A–S phases contributed to strengthening the matrices and hinder axial cracks; consequence of toughening mechanisms developed by the coarsening on molecular scale of H–M–A–S. [Copyright &y& Elsevier]

Abstract: Recently, many efforts have been made to recycle waste of different nature as constituents of sustainable concrete. This practice produces large environmental benefits that can be further extended if deleterious chemical side-reactions, deriving from the use of some types of waste and/or raw materials, could be prevented and suppressed. This paper presents the combined action of different ceramic wastes partially replacing natural sand and cement, respectively. Alkali silica reaction (ASR) promoted by boron–silicate and lead–silicate glass used as fine aggregates (⩽4mm) is limited and controlled by using a new type of blended cement based on a siliceous residue coming from sludge produced by the polishing of porcelain stoneware tiles. The results of expansion tests carried out in accelerated conditions together with mechanical and microstructure characterisations of mortar samples highlight the combined action of the investigated wastes. Indeed, the blended cement containing porcelain stoneware polishing residue can be effectively exploited as valid alternative to pozzolan cement. [Copyright &y& Elsevier]

Abstract: Blended cements are largely used for concrete: they are usually considered cements with a low environmental impact, as they require less clinker than ordinary Portland cement (OPC). Different constituents can be used as supplementary clinker component usually leading to cement with high resistance to outdoor environment. Polishing residue (PR), coming from porcelain stoneware tiles production, can be successfully used as new constituent for blended cement, however its action for enhancing the durability of cement matrix must be assessed. With this purpose, electrochemical tests (half cell potential, impressed voltage and linear polarization techniques) have been carried out on steel reinforced mortar samples, prepared using a 25% PR based cement and 100% OPC as binder and exposed to a 3.5% NaCl solution. The corrosion resistance results and microstructure analysis highlight better durability performances for PR based cement than those exhibited by OPC, mainly for curing time >28days. [Copyright &y& Elsevier]

Abstract: The alkali–silica-reaction (ASR) expanding behavior of different types of glass, all derived from cullet with different chemical composition, has been investigated. The glass reactivity was determined in different alkaline solutions based on sodium and/or calcium hydroxide to simulate concrete environment. The expansion of mortar containing different amounts of the investigated glass as fine aggregate has been carried out in different conditions: data collected underline a different response of glass towards the alkaline environment. Soda–lime glass shows negligible expansion, lead–silicate glass always generates expanding trends while boro–silicate glass has different behaviors depending on its colour. An attempt to link the behavior to the solubility and chemical reactivity of the glass is proposed. [Copyright &y& Elsevier]

The topic of sustainability of reinforced concrete structures is strictly related with their durability in aggressive environments. In particular, at equal environmental impact, the higher the durability of construction materials, the higher the sustainability. The present review deals with the possible strategies aimed at producing sustainable and durable reinforced concrete structures in different environments. It focuses on the design methodologies as well as the use of unconventional corrosion-resistant reinforcements, alternative binders to Portland cement, and innovative or traditional solutions for reinforced concrete protection and prevention against rebars corrosion such as corrosion inhibitors, coatings, self-healing techniques, and waterproofing aggregates. Analysis of the scientific literature highlights that there is no preferential way for the production of "green" concrete but that the sustainability of the building materials can only be achieved by implementing simultaneous multiple strategies aimed at reducing environmental impact and improving both durability and performances. [ABSTRACT FROM AUTHOR]

While cast geopolymers are deeply investigated, geopolymers shaped by pressing are still rather unexplored. This work aims at developing one-part pressed geopolymers investigating the influence of parameters such as Na/Al molar ratio, water content and pressure load on the physical, microstructural and durability properties of the hardened geopolymers. Geopolymers were prepared by dry mixing and cured at 70 °C for 24 h and at room temperature for further 6 days. Density, water absorption, porosity features, microstructure and durability have been determined for all the samples. The results show that Na/Al molar ratio, water content and pressure load are key parameters to control the properties of one-part geopolymers. Their optimization can allow to obtain geopolymers suitable for microfiltration flat membrane support. Finally, the best performances in terms of durability are obtained when using the highest pressure load (20 MPa) and water content (15%). [ABSTRACT FROM AUTHOR]

This study investigated the potential application of geopolymeric material for the separation of oil-in-water emulsions in wastewater treatment. For the first time, an asymmetric membrane made of geopolymers was developed for this specific separation process. The performances of the geopolymeric membrane in oil separation were compared with those obtained by a commercial ceramic membrane. The study also aimed at exploring the effects of emulsion formulation and emulsion properties (surfactant type and concentration, pH, and zeta potential) and membrane parameters (surface charge and material) on permeate volumetric flux and chemical oxygen demand (COD) rejection. Emulsions were prepared using 3% (w/v) dodecane oil in distilled water, with surfactant concentrations of 1x and 10x critical micelle concentration (CMC) and three surfactants of different nature (Oleth-10, Brij 76, and CTAB) at pH values of 2, 5, and 8. Results showed that for the best operating conditions of the geopolymeric membrane, initial and final permeate flux values of 42 and 26 L h−1 m−2, respectively, were achieved. COD rejection values ranged from 95.0 to 99.4% using the geopolymeric membrane thus indicating a very similar behavior between geopolymeric and ceramic membranes. These findings suggest that geopolymers are promising to produce membranes for oil-in-water emulsion microfiltration, promoting an interesting alternative for the treatment of industrial wastewater more sustainable in terms of environmental effects and costs compared to ceramic membranes. • Novel geopolymeric asymmetric membrane was synthetized. • Geopolymer selective layer was successfully deposited on pressed geopolymer support. • The geopolymeric membrane showed excellent fluxes and removal efficiencies. • Flux and rejection properties vary with surfactant concentration and emulsion pH. • Geopolymer membrane performs similarly to a commercial microfiltration ceramic one. [ABSTRACT FROM AUTHOR]

This research reports the investigations of threshold reactivity limit of blends of pegmatite with different calcined clays as well as the influence of calcined clay source on the geopolymerization kinetic, microstructural, and physicomechanical properties of feldspathic mineral-based inorganic polymer composites. These composites were designed from 85 to 94 wt% of the solid solution of pegmatite and calcined clay. The three-point flexural and compressive strengths, porosity, and microstructure as well as heat evolution rate of geopolymerization reactions of resulting composites were affected by the type of calcined clay. The four calcined clays provided the highest mechanical properties of the composites when added in the range of 12-15 wt%. Specifically, the values of flexural and compressive strengths ranged from 32 to 34 MPa and 101 to 105 MPa, respectively, for geopolymer composites with 15 wt% of metakolin added, while they ranged from 38 to 42 MPa and 106 to 107 MPa with 12 wt% of meta-hallosyte added. The polycondensation/polymerization process of calcined clay developed sufficient amounts of N-A-S-H and polysialate geopolymer to cover the incongruently dissolved fine particles of pegmatite. The resulting microstructure was dense and compact with the lower cumulative pore volume at about 91 mm3/g. It was concluded that designing the pegmatite/clay-based geopolymer composites with high mechanical strengths and low porosity resulted in sustainable, low energy consumption and environmental-friendly materials for civil engineering. [ABSTRACT FROM AUTHOR]

In the recent century, geopolymer materials have grown significantly due to their unique properties applicable in many different fields. In the present work, the heat evolution, thermal and mechanical behavior of inorganic geopolymer composites (IPCs), based on solid solution of feldspathic minerals (pegmatite and granite) or sand quartz that were altered by a low fraction (15–20 mass%) of calcined clay (metakaolin or calcined halloysite). The isothermal calorimeter tests revealed that the heat flow evolution (dQ/dt) of mix design of different compositions was low compared to standard geopolymer materials due to low reactivity in alkaline medium of solid solution used. It was also found that the integrated heat flow during the geopolymerization decreases with the crystallinity of solid solution. The thermogravimetric analysis of all the samples revealed two main changes, before 120 °C and between 700 and 890 °C. The changes are attributed to the loss of water molecules and crystallization of albite and nepheline, respectively with an overall loss of mass which varies from 14.0 to 21.6%. The heating microscope up to 1200 °C shows a shrinkage of 50% for D3C4 and R2C1 samples. The study of mechanical and physical behaviors of geopolymer composites with different compositions showed that samples based on pegmatite and MK developed higher strengths (42.11 MPa and 106.75 MPa for flexural and compression) associated with lower water absorption (7.01%). The high strengths obtained were due to the combination of denser and homogeneous microstructure of IPCs. These materials are potential candidates for eco-friendly construction materials. [ABSTRACT FROM AUTHOR]

This study reports on the possibility of applying one-part pressed geopolymers as a support for microfiltration membranes. The mineralogical, physical, mechanical, microstructural and hydraulic properties of the investigated materials are presented. Metakaolin-based geopolymeric membrane flat supports were synthesized by uniaxial pressing a dry-mixed powder (Si/Al = 1.45, Na/Al = 0.9, Na/Si = 0.62, H 2 O = 12%), with pressure between 2 and 20 MPa and a curing temperature of 70 °C. Mixing and pressing optimization resulted in samples with a total open porosity up to 39%, a modal pore diameter up to 23.5 μm and a flexural strength up to 20.4 MPa. Permeation measurement with demineralized water and ethanol-water solutions were carried out using a dead-end geometry membrane apparatus. A hydraulic permeability up to 31.3 · 103 L h−1 m−2 bar−1 has been obtained. Furthermore, permeation tests using water-ethanol solutions have demonstrated that the material is hydrophilic. These results highlighted the potential of geopolymers as microfiltration support. • Pressed one-part geopolymers are suitable to be used as membrane supports. • Geopolymer membrane supports possess a peculiar threshold pressure. • Geopolymer supports have similar characteristics to ceramic membrane supports. [ABSTRACT FROM AUTHOR]

Ceramic tile manufacturing is a highly energy-intensive process. Concerns about carbon emissions and energy costs make energy management crucial for this sector, which holds a leading role in Italian industry. The paper discusses the energetic and environmental performance of cogeneration (CHP) in the ceramic industry, where prime mover exhaust heat is supplied to a spray-dryer system, contributing to the satisfaction of the thermal demand and decreasing natural gas consumption. A thermodynamic model of a dryer unit, validated against real data, has been set-up to provide a detailed representation of the thermal fluxes involved in the process. Then, the thermal integration with two types of CHP prime movers of similar electric size (4 MW) is investigated. Energetic results show that the gas turbine can contribute up to 81% of dryer thermal consumption, whilst internal combustion engine contribution is limited to 26%. A methodology was ad-hoc defined for the environmental assessment of CHP, accounting for global (CO2) and local (CO and NOX) emissions. Results confirm that CHP units guarantee reduction of CO2 and NOX compared to separate generation, with maximum values equal to 81 g/kWhth and 173 mg/kWhth, respectively; CO emission is decreased only in the case of gas turbine operation, with savings equal to 185 mg/kWhth. [ABSTRACT FROM AUTHOR]

This paper presents the comparative results obtained from X-ray and neutron pair distribution function (PDF) analysis aimed at determining the variability in aluminosilicate glass chemistry in five types of class F fly ash (FA). Results have been discussed in light of the complementary information provided by the two methods in order to give a comprehensive overview of FA structure at the nanoscale. The analysis of short range correlations reveals that the bulk glassy structure of FA sources differing in chemical composition are relatively similar, but some specific distinctions in atomic structure are visible in those containing high levels of amorphous VI-coordinated aluminum (e.g., amorphous mullite/alumina), iron and/or carbon (with similar local bonding environment to graphite). The obtained experimental results fill a deficit in literature in the atomic structure and associated variability for class F FA, which is extensively used in several industrial applications including as raw material in alkali-activated cements. [ABSTRACT FROM AUTHOR]

Present concerns about global warming due to the greenhouse emissions in the atmosphere have pushed the cement industry to research alternatives to ordinary Portland cement (OPC). Geopolymer binder may constitute a possible breakthrough in the development of sustainable materials: understanding the effectiveness and the influences of superplasticizers on geopolymer systems is one of the essential requirements for its large-scale implementation. This study aims to investigate the possibility of using commercially available chemical admixtures designed for OPC concrete, to improve fresh properties of fly ash-based geopolymers and mortars. A special emphasis is laid upon evaluating their influence on mechanical and microstructural characteristics of the hardened material realized under room-temperature curing conditions. Results indicate that the addition of a polycarboxylic ether-based superplasticizer, in the amount of 1.0 wt. % by mass of fly ash, promotes an improvement in workability without compromising the final strength of the hardened material. Moreover, the addition of the polycarboxylic ether- and acrylic-based superplasticizers induces a refinement in the pore structure of hardened mortar leading to a longer water saturation time. [ABSTRACT FROM AUTHOR]

The addition of fibres to a brittle matrix is a well-known method to improve the flexural strength. However, the success of the reinforcements is dependent on the interaction between the fibre and the matrix. This paper presents the mechanical and microstructural properties of PVA and basalt fibre reinforced geopolymers. Moreover low density and thermal resistant materials used as insulating panels are known be susceptible to damage due to their poor flexural strength. As such the thermal and fire resistance properties of foamed geopolymers containing fibre reinforcement were also investigated. The results highlight that the presence of PVA fibres greatly increased the flexural strength and the toughness of the geopolymer composite, while the presence of basalt fibres improved the flexural behaviour of the composite after high temperature exposure. [ABSTRACT FROM AUTHOR]

• Protectiveness of fluoropolymer coating (FA-MS) on patinated bronze was assessed. • FA-MS coating covered the patinated bronze with a transparent layer few μm thick. • Good durability of FA-MS on bronze artwork was observed in real outdoor exposure. • Brushing was an efficient method for removing FA-MS without altering bronze patina. The application of protective coatings for the conservation of outdoor metallic artworks is currently considered the best approach actively employed. This paper focuses on the evaluation of the protectiveness of an optimised fluorosilane (FA-MS) coating with low occupational hazard impact and high inhibition efficiency. FA-MS coating was applied on a typical historical as-cast bronze (Cu-Sn-Zn-Pb), artificially patinated by synthetic acid rain dropping, to simulate natural unsheltered patinas. Subsequently, the patinated bronze was coated by brushing and then artificially aged by synthetic rain dropping. In order to investigate the coating-patina system, a multi-analytical approach was applied including scanning electron microscopy coupled with elemental analysis (FEG-SEM with EDS), microstructural analysis of cross-sections produced by Focused Ion Beam milling (FIB) and X-ray Photoelectron Spectroscopy (XPS). The coating homogenously covered the whole patinated surface producing a transparent layer few μms thick. The weathering solutions were also analysed for the assessment of metallic cations release. FA-MS showed excellent protective performances for the patinated bronze exposed to simulated outdoor conditions. Very high values of inhibiting efficiency in terms of metal release in the weathering solutions (up to 99%) were measured. In order to investigate all the necessary requirements for application in conservation field, the durability of FA-MS was also tested on a real bronze artistic casting, in terms of limiting the alloy composition changes (measured by in situ XRF) over time. A good durability of the coating was observed during the ongoing field exposure test. Lastly, reversibility of FA-MS was investigated by applying different mechanical cleaning methods, such as brushing and blasting. The reversibility was assessed by the evaluation of the morphology (colour change, surface roughness and optical microscopy) and the composition (SEM-EDS and Py-GC-MS chromatography) of the cleaned surfaces. Cleaning by brushing proved to be an efficient method for removing this coating without significantly altering the bronze patina. [ABSTRACT FROM AUTHOR]

Alkali-activated fly ashes have been proposed for various applications where resistance against high temperatures is required, yet several details regarding the response of these materials to heat-exposure need to be clarified. In the present study, heat-induced cracking in fly ash-based alkali-activated pastes and lightweight mortars was analyzed by in-situ acoustic emission (AE) detection during complete heating-cooling cycles (up to ∼1100 °C), augmented by thermogravimetry and ex-situ SEM and XRD analyses. The applicability of the lightweight mortars as passive fire protection coatings was assessed by recording temperature-time curves of mortar-coated steel plates. Cracking during heating was limited and associated exclusively with the dehydration of the materials in the temperature range ∼90–360 °C. However, samples heated to temperatures above ∼600 °C exhibited intense cracking on cooling. This was attributed to differential deformations caused by local sintering and partial melting at the glass transition temperature, and subsequent quenching on cooling. [ABSTRACT FROM AUTHOR]

The aim of this work is to evaluate the cleanability performances of lapped porcelain stoneware surfaces with and without protective treatments. The knowledge of the material cleanability is an important selection parameter in buying tiles. However, an objective basis for testing and assessing this property still is lacking. In this study, standardized and laboratory tests to evaluate the cleanability performance of lapped porcelain stoneware products have been carried out and compared. Cleanability tests were performed by applying two different soiling suspensions, optimized for tile surfaces and reproducing chemical and mechanical actions simulating the working conditions and traditional cleaning operations. Surface characteristics (microstructure, topography, roughness) were analyzed before and after cleanability tests. The results showed a good correlation between different behavior in terms of cleanability and the microscopic and topographic characteristics of lapped tile. Respect to international standardized tests specific for ceramic tiles, such as stains resistance test, the laboratory procedures to evaluate the surface cleanability are able to better show cleanability improvements of lapped tiles with protective treatments. [ABSTRACT FROM AUTHOR]

Graphical abstract Highlights • Fly ash was successfully alkali activated at room temperature. • The use of expanded perlite and H 2 O 2 allowed obtaining lightweight mortars. • Numerical simulations predicted a satisfactory fire behaviour. • Alkali activated lightweight mortars were able to outperform cement-based ones. Abstract Alkali activated lightweight mortars, obtained by room temperature activation of coal fly ash, were studied as passive fire protection systems for steel elements. Physical, mechanical and thermal properties were investigated as a function of the compositional Si/Al molar ratio and of the amount of lightweight aggregate and foaming agent. Experimental findings were used as input data to assess their fire resistance by finite volume simulations. Results pointed out that the optimized alkali activated lightweight mortars are able to outperform alternative commercial cement-based mortars, thus representing a promising technology. [ABSTRACT FROM AUTHOR]

The compaction behavior of spray-dried powders has turned into concern in porcelain stoneware manufacturing due to the increasing diffusion of large slabs. It is necessary to fill a knowledge gap between the compaction behavior with conventional presses and novel technologies. For this purpose, eighteen industrially-manufactured spray dried bodies were characterized for specific properties connected to the compaction behavior (curves of bulk density, intergranular and intragranular porosity in function of applied load, apparent yield strength). In addition, the firing behavior was investigated in order to reveal any effect of dry bulk density on firing shrinkage and bulk density of fired samples. Powder compressibility is within 50% and 55% (Carr index) and is primarily controlled by moisture. Two regimes are found: low pressure (fast density increasing by granule cave in and closure of intergranular porosity) and high pressure (slow density gain by downsizing microporosity). A peculiar mechanism is unveiled: granules squeeze in the low-P regime and further densification is achieved through microfracture around individual agglomerate. A phenomenological model is illustrated for the compaction of spray-dried powders. In conclusion, the performance of spray dried bodies during compaction is crucial to control the uniformity, in terms of porosity and bulk density, which has important repercussions on the properties of final slabs, especially differential shrinkages and deformation during firing due to density gradients. [ABSTRACT FROM AUTHOR]

The technological behavior of porcelain stoneware bodies during deposition and pressing of large slabs depends on the rheological properties of spray-dried powders and the way they affect compaction. Although the literature offers some insights into the characteristics of spray-dried powders for ceramic tiles, no data are available on bodies utilized by novel technologies for large slabs (>4 m 2 ). In order to fill this gap, a systematic approach to properties and behavior of spray-dried powders for porcelain stoneware slabs was carried out. For this purpose, twenty industrially-manufactured spray-dried powders were characterized for intrinsic features (particle size and agglomerate size distribution; shape and moisture distribution in function of agglomerate size) and rheological properties (mass flow, static and dynamic angles of repose, poured and tap density, Hausner ratio). The effect of intrinsic characteristics on the flowability of powders was appraised, as the mutual relationships between the rheological parameters, in order to unveil the best parameters to be used in ceramic tile production. Two broad classes of spray-dried powders occur with a finer and a coarser agglomerate size distribution. Results reveal that ceramic powders are free-flowing, with rheological properties fluctuating in a rather narrow range of values, which makes hard to see significant relationships among the various methods (the only strict correlation is between mass flow rate and tap density). Flowability mainly depends on the occurrence of coarser aggregates, particularly those irregular in shape, stemming from coalescence of three or more individual agglomerates. A phenomenological description of how the spray-dried powders behave in the deposition on tape and the early stage of compaction is outlined. [ABSTRACT FROM AUTHOR]

Air- and formulated lime mortars with pulverized brick waste were synthesized with addition of two organic waste-based additives: spent cooking oil and albumen. The addition of spent oil in the mortar induced significant hydrophobic effects, but decreased permeability values and setting kinetics. Parallel additions of oil and albumen in lime mortars significantly increased their hydrophobicity and superficial durability without retarding their setting time thanks to role of fatty acids and unfolded proteins under alkaline conditions. The parallel valorization showed high potentials in synthesis of restorative mortars design with low environmental impact and high respect to the feature of historic mortars. [ABSTRACT FROM AUTHOR]

This review presents “a state of the art” report on sustainability in construction materials. The authors propose different solutions to make the concrete industry more environmentally friendly in order to reduce greenhouse gases emissions and consumption of non-renewable resources. Part 1—the present paper—focuses on the use of binders alternative to Portland cement, including sulfoaluminate cements, alkali-activated materials, and geopolymers. Part 2 will be dedicated to traditional Portland-free binders and waste management and recycling in mortar and concrete production. [ABSTRACT FROM AUTHOR]

Steel fiber reinforced geopolymer matrix (S-FRGM) composites are explored as a new tool in strengthening applications of reinforced concrete (RC) structures. The suitability of fly ash geopolymers as the matrix employed in S-FRGMs is investigated in this paper. Geopolymer matrix is used to embed galvanized steel fibers and bond the composite to a concrete substrate. By varying the molar concentration of the NaOH activating solution, three different geopolymer matrices are obtained and the influence of the alkaline environment on the bond behavior between fibers and matrix is examined. Physical, mechanical, and microstructural properties of the three matrices are measured and related to the interfacial bond behavior of S-FRGM-concrete joints. Results show that the decrease of the molar concentration of the NaOH activating solution leads to an increase of the interfacial bond behavior between matrix and fibers, which in turn improves the effectiveness of the composite action of the strengthening system. [ABSTRACT FROM AUTHOR]

The suitability of new lime mortars for restorative rendering applications was investigated. Air-, formulated- and hydraulic-lime mortars were synthesized with inclusion of two different types of spent sunflower cooking oils and, when necessary, brick waste powder as pozzolanic addition. The results of spent cooking oils addition in the mortars exhibited promising hydrophobic effects, such as sorptivity reduction up to 60 times and improvement of superficial durability. Addition of high-oleic acid cooking oil in 13 wt% in the formulated and hydraulic lime mortars significantly increased their hydrophobicity without worsening their mechanical strengths. All the investigated mortars exhibited appropriate indexes as restorative materials. [ABSTRACT FROM AUTHOR]

Porcelain stoneware tiles are industrially processed by using high sintering temperatures and fast firing cycles that result in products characterized by an almost impervious surface layer surrounding a rather porous bulk material. Since mechanical properties are affected by porosity, the knowledge of the material stiffness is an important parameter to define the service behavior of tiles. In the present investigation, porcelain stoneware samples having different closed porosity were investigated in order to understand the influence of the porosity on the elastic constants of the materials. Based on the quantitative XRD phase composition, elastic constants have been calculated via Voigt-Reuss-Hill averaging, and the influence of porosity has been taken into account via power-law and exponential relations. It is shown that the effective elastic constants predicted by exponential and power-law relations are in agreement with experimental values. It may be concluded that for this class of materials, in the porosity range below 14–16%, both exponential and power-law relations are helpful tools to design tiles with controlled microstructure and tailored mechanical properties. [ABSTRACT FROM AUTHOR]

The response to thermal variations is the primary cause of marble deterioration in ancient and modern buildings. In this study, the thermal behavior of Carrara marble after consolidation by an innovative hydroxyapatite-based treatment was investigated in comparison with ammonium oxalate and ethyl silicate. Samples were subjected to heating-cooling cycles up to 80 °C. All the consolidating treatments were found to be fairly compatible, as in no case the residual strain after the thermal cycles was found to increase compared to the unweathered untreated marble. Anyway, the hydroxyapatite-treatment has the advantage of causing the highest increase in marble cohesion and the lowest residual strain, besides being more chromatically compatible and durable than the alternative commercial consolidants. [ABSTRACT FROM AUTHOR]

This paper aims at evaluating how the FRP/brick debonding force is influenced by brick mechanical properties (compressive, tensile and flexural strength) and physical-microstructural properties (surface roughness, porosity, pore size distribution, rate of water capillary suction). The depth of epoxy resin penetration into bricks and the thickness of brick layer detached at the end of bond test were also determined, in order to investigate the role of resin penetration into the brick on the FRP performance. All the tests were carried out on different brick surfaces (namely “bed” and “face”), to account for possible brick anisotropy. The results of the study point out that brick mechanical properties alone are not sufficient to accurately predict the maximum debonding force, but a better estimation can be achieved taking into account also brick surface roughness and resin penetration depth. If brick anisotropy is not considered, in some cases a remarkable overestimation of the maximum debonding force may be found. [ABSTRACT FROM AUTHOR]

Alkali-activation of brick waste has recently been proposed as a sustainable route to develop pastes/mortars with tailored mechanical properties and pore system. In this study, the suitability of using pastes from brick waste alkali-activation for repointing existing masonries (i.e., filling the most external part of mortar joints, lost due to deterioration processes) was investigated. Five different formulations (having SiO 2 /Al 2 O 3 molar ratio ranging from 1.4 to 0.4) and two different curing temperatures (room temperature and 50 °C) were investigated. Open porosity and efflorescence formation were found to decrease for decreasing SiO 2 /Al 2 O 3 ratio. Curing at high temperature generally favored geopolymerization and reduced efflorescence formation. Pastes with SiO 2 /Al 2 O 3 =0.8 and 0.9 exhibited open porosity and water vapor permeability fairly similar to those of historic lime-based mortars, thus proving to be potentially compatible with them. Further optimization of the mix design seems however necessary to reduce the formation of efflorescence. [ABSTRACT FROM AUTHOR]

This work investigates the effects of the structure, the bulk chemical composition and amount of the aluminosilicate fines on the strength development, pore refinement, water permeability, moisture control capacity and the microstructure of inorganic polymer concretes (IPC). The amorphous fines, one from pumice and another from recycled glass, presented sponge-like microstructure with tortuous pore network that maintained the presence of fine capillary pores while semi-crystalline feldspar sludge, the third type of fine aggregates used for this study, showed more dense and compact microstructure that explain the higher strength enhancement. Both amorphous and semicrystalline fines contributed to decrease the porosity, improve the strength and microstructure. However, based on the moisture control capacity and the durability indicators, the fine aggregate derived from semicrystalline feldspar was found to be more appropriate and efficient for the development of IPC at short time scale of curing. Pumice fine aggregate was found to be effective only with a long term curing. [ABSTRACT FROM AUTHOR]

[Display omitted] • Reclaimed asphalt pavement (RAP) was tested as aggregate replacement for concrete. • Five types of RAP sourced by different Italian collection sites were characterized. • RAP shows irregular porous surface due to bitumen covering the natural aggregate. • RAP shows hydrophobic behavior. • RAP exhibits dimensional stability and frost resistance. A study about the performances of reclaimed asphalt pavement (RAP) sourced from 5 different Italian collection sites is presented to evaluate RAP as aggregate for concrete. Several RAP properties were investigated: physical properties (particles size distribution, water absorption, porosity, wettability), microstructure by microscopy, dimensional stability (drying shrinkage of mortar and concrete with 100% of RAP as aggregates) and durability assessment by freezing-thawing cycles. Several differences between RAP and natural aggregates used for concrete were highlighted. The use of RAP as recycled aggregate for concrete is a promising route, but a complete characterization is needed to ensure concrete performance and durability. [ABSTRACT FROM AUTHOR]

Foaming to reduce the density of geopolymeric materials is increasingly being reported in the literature as it has been shown to be effective in improving their insulating properties. However, there is no consistency in foaming methods and as such this study was performed to compare methods in order to better understand their effect on the properties of geopolymers. A surfactant and two chemical foaming agents (hydrogen peroxide and aluminium powder) were added to a fly ash based geopolymer matrix. Surfactant was also combined with each of the chemical foaming agents in order to stabilise the foam in the geopolymer matrix and to reduce coarse pores. The physical, mechanical and microstructural properties of the low density geopolymers are presented and the effects of the foaming agents' characteristics on the hardened product is discussed, as well as the relative merits of the different procedures to synthesise the foamed geopolymer. It was found that homogeneous microstructures with small pores can be obtained by adding surfactant and hydrogen peroxide. The combination of hydrogen peroxide (0.1wt%) and surfactant (1.0wt%) produced geopolymer foams with density and compressive strength values of 0.94g/cm³ and 4.6MPa, respectively. [ABSTRACT FROM AUTHOR]

This paper examines the phase transformation, pore evolution, microstructural and mechanical changes that occur in inorganic polymer cement (IPC) in the presence of three different grade of fine aggregates (Φ<100μm) of ladle slag, nepheline syenite and quartz sand. Experimental results indicate that polycondensation was enhanced in nepheline syenite based specimens, compared to quartz sand, due to the increase in H M A S phases in relation to the dissolution and interaction of amorphous/disordered fraction of aggregates. H C S and H C A S with H M A S phases were identified in the ladle slag based specimens. The formation of these new phases reduced both the cumulative pore volume and pores size. The apparent increase in volume of capillary pores in ladle slag based specimens was explained by the residual bubbles from the carbonates included in raw slag. The flexural strength of the inorganic polymer cement increases from 4MPa to 4.2, 4.8 and 6.8MPa with the addition of 20wt% of quartz sand, nepheline syenite and ladle slag respectively. These values increase significantly between 28 and 180days of curing (9.1MPa for ladle slag and 10.0MPa for nepheline syenite). It was concluded that fines can be used to remove the HM and poorly bounded alumina oligomers in metakaolin based inorganic polymer matrices and improve the interfacial zone for the design of an optimum grade and high-performance composites. [ABSTRACT FROM AUTHOR]

Abstract: Old reinforced concrete (RC) structures often exhibit unsatisfactory performances in terms of both residual serviceability and seismic behavior. The durability requirements were not considered at all at the age of design and construction, exposing such structures to severe decay in aggressive urban and/or industrial environment; in the meantime, the use of plain steel bars (with poor bond strength) was common at the age of construction and this jeopardizes the RC performance under cyclic load reversals like those induced by earthquakes. In this paper, the deep impregnation of cement-based mortars and concrete with a solution of ethyl silicate and with electrochemical treatments by means of a solution of sodium carbonate was investigated, with a twofold aim: (1) increasing the bond strength of the embedded plain steel bars in existing structures without any need for demolition and (2) increasing the durability and safety of the reinforced concrete elements. Both the treatments are already exploited in other fields: ethyl silicate solutions are widely used for stone consolidation (and only recently proposed for concrete surface protection), while migration of sodium carbonate under DC voltage is used for RC realkalization. In the present study these treatments are expected to penetrate inside mortar and concrete and to modify their microstructure, hence improving their properties. The effects of the treatments are investigated by comparing the characteristics of treated and untreated mortar and concrete samples reinforced with plain bars, in terms of penetration inside the samples, pull-out strength, water absorption, pore size distribution, carbonation resistance and corrosion resistance. [Copyright &y& Elsevier]

Waste generated in ceramic tiles manufacturing is not usually recycled inside the productive plant, but rather disposed to landfill. This paper deals with ceramic residues from polishing and glazing processes, as constituents for innovative blended cements. New binders made up of 75% CEM I 52.5 R and 25% residues were chemically, physically, and mechanically characterized with reference to EN 197-1 requirements and the results compared with ordinary Portland cement. Mechanical strength development and microstructure of the relevant mortar have been investigated up to 90 days of curing, and the behavior of polishing and glazing residues as cement constituents is reported. [ABSTRACT FROM AUTHOR]

Morphology of the crack surface of surgical bone cements has seldom been studied in the past despite the clinical relevance of cement failure. Previous studies on a specific cement type suggest that crack morphology depends on crack propagation rate. The objectives of this work were: (i) to develop a quantitative indicator for describing crack morphology; and (ii) to assess if dependency on crack-propagation rate is affected by cement formulation. Known crack surfaces were obtained from specimens under controlled loading conditions. Crack surface roughness was measured for different crack-propagation rates, and compared against the amount of cleaved pre-cured beads (measured with a semi-automated procedure based on micrographs). Such indicators were extremely robust, operator-independent, highly correlated, and sensitive to the type of fracture. Moreover, it was found that crack surface morphology heavily depends upon cement composition. Thus, crack surface roughness is proposed as a method for quantitatively identifying crack morphology, and finally classifying fracture type. [ABSTRACT FROM AUTHOR]

This research reports on the influence of particle size and distribution on the physical, mechanical and microstructural features of solid solutions (feldspathic materials) based inorganic polymer composites (IPCs). Both granite and pegmatite were ground to different degree of finess making four different granulometry with particles of 63, 80, 125 and 200 μm. The respective mixes receive 15 wt% of metakaolin and were activated with a well designed alkaline solution. Matrices obtained showed high compressive and flexural strengths in the range 101.2–131.3 MPa, and 29–35.5 MPa, respectively. It was observed that the optimum mechanical performance of these matrices can be achieved through a mix-design of different grades of granulometry. This was suggested by mechanism combining reactivity and particles packing. In fact, although it can be expected that the finess of the combination of the particles size under 63 μm might present the better reactivity, it is showing that the combination of fine, medium and coarse particles is efficient in achieving denser and tougher microstructure. Lower cumulative pore volume (17 mL g−1) of the composites based on pegmatite, value not far from that of natural stones, resulted in a higher impact resistance of 3.03 J. It was concluded that designing the feldspathic rock-based composites with high strengths appear as sustainable, low energy consumption and environmentally-friendly materials for the structural construction. [Display omitted] • The replacement of fine particles by coarse ones contributed to the reinforcement of the network of IPCs. • The particle size of aluminosilicates has significant effect on microstructure and mechanical properties of IPCs. • The addition of 50 wt% of particles between 125 and 200 μm increased the mechanical strengths. • The better flexural strength of pegmatite and granite-based IPCs obtained were 30.6 and 32.5 MPa respectively. • A clear correlation was being established between porosity, mechanical strength and impact energy. [ABSTRACT FROM AUTHOR]

• The fracture properties of three alkali-activated mortars are studied. • Low values of fracture energy might be associated with the presence of unreacted FA. • The fracture energy depends on the type of aggregate used. • Digital image correlation can be used to estimate the size of the FPZ. Results of three-point bending tests on notched beams cast with three alkali-activated mortars that differ by the type and size of the aggregates are presented. Digital image correlation is used to estimate the size of the fracture process zone. The fracture energy is computed by means of the work-of-fracture method and found to be strongly dependent on the type of aggregate used and does not differ whether the LDVT or DIC load-deflection curves are used. Finally, low values of the fracture energy in alkali-activated mortars might be associated with the presence of unreacted fly ash. [ABSTRACT FROM AUTHOR]

The objective of this paper is to review the current knowledge on the development of nanostructured zirconia-based ceramics and composites suitable for application in dentistry. Isi Web of Science, Science Direct, Scientific.net databases, and Google were searched electronically for the period of 1980 to the present, matching the keywords "nano" with the keywords: "Zirconia, ZrO2, Y-TZP, and dental, dentistry". A total of 74 papers were found, with the majority coming from Asia, indicating a more active scientific interest on the topic in this geographic area, followed by Europe, South America, and North America. The research shows, even though the scientific activity on nanostructured ceramics was intense in the last fifteen years, the development of fully dense zirconia-based nanoceramics is yet at an initial stage, most of all from the point of view of the clinical applications. It has been demonstrated that nanostructured ceramics can show improved properties because of the reduction of the grain size to the nanoscale. This is also true for zirconia-based nanoceramics, where some improvements in mechanical, optical, as well as resistance in low-temperature degradation have been observed. Potential applications of this class of material in the dental field are discussed, summarizing the results of the latest scientific research. [ABSTRACT FROM AUTHOR]