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Phosphine could be a key molecule in the understanding of exotic chemistry that occurs in (exo)planetary atmospheres. While phosphine has been detected in the Solar System's giant planets, it has not been observed in exoplanets to date. In the exoplanetary context, however, it has been theorized to be a potential biosignature molecule. The goal of our study was to identify which illustrative science cases for PH3 chemistry are observable with a space-based mid-infrared nulling interferometric observatory like the Large Interferometer for Exoplanets (LIFE) concept. We identified a representative set of scenarios for PH3 detections in exoplanetary atmospheres that vary over the whole dynamic range of the LIFE mission. We used chemical kinetics and radiative transfer calculations to produce forward models of these informative, prototypical observational cases for LIFEsim, our observation simulator software for LIFE. In a detailed, yet first order approximation, it takes a mission like LIFE: (i) about 1 h to find phosphine in a warm giant around a G star at 10 pc, (ii) about 10 h in H2 or CO2 dominated temperate super-Earths around M star hosts at 5 pc, (iii) and even in 100 h it seems very unlikely that phosphine would be detectable in a Venus-Twin with extreme PH3 concentrations at 5 pc. Phosphine in concentrations previously discussed in the literature is detectable in 2 out of the 3 cases, and it is detected about an order of magnitude faster than in comparable cases with James Webb Space Telescope. We show that there is a significant number of objects accessible for these classes of observations. These results will be used to prioritize the parameter range for the next steps with more detailed retrieval simulations. They will also inform timely questions in the early design phase of a mission like LIFE and guide the community by providing easy-to-scale first estimates for a large part of detection space of such a mission. [ABSTRACT FROM AUTHOR]

Context. NOTT (formerly Hi-5) is a new high-contrast L′ band (3.5–4.0 µm) beam combiner for the VLTI designed with an ambitious aim to be sensitive to young giant exoplanets down to 5 mas separation around nearby stars. The performance of nulling interferometers in these wavelengths is affected both by fundamental noise from the background and contributions of instrumental noise. This motivates the development of end-to-end simulations to optimize these instruments. Aims. The aim of this study is to enable a performance evaluation of NOTT and inform the design of such instruments with current and future infrastructures in mind, taking into account the different sources of noise and their correlation. Methods. SCIFYsim is an end-to-end simulator for single-mode-filtered beam combiners, with an emphasis on nulling interferometers. We use it to compute a covariance matrix of the errors. We then use statistical detection tests based on likelihood ratios to compute compound detection limits for the instrument. Results. With the current assumptions as to the performance of the wavefront correction systems, the errors are dominated by correlated instrumental errors down to stars of magnitude 6–7 in the L band, beyond which thermal background from the telescopes and relay system becomes dominant. Conclusions. SCIFYsim is suited to anticipating some of the challenges of design, tuning, operation, and signal processing for integrated-optics beam combiners. The detection limits found for this early version of NOTT simulation with the unit telescopes are compatible with detections at contrasts up to 105 in the L band at separations of 5–80 mas around bright stars. [ABSTRACT FROM AUTHOR]