Search

Magnetostriction and its inverse effect (also referred to as a magnetomechanical effect) in the Tb0.3Dy0.7Fe2 alloy have been investigated based on the three dimensional Stoner–Wohlfarth model in this paper. The solutions of direction cosines of magnetization under a compressive stress and a field both applied along the [112] axis have been obtained by following a conventional minimization procedure in which the nonlinear equations for equilibrium conditions have been solved numerically. With a more accurate computation presented here, some new theoretical results have been achieved. These results are in good agreement with experimental observations reported previously. In the demagnetized state the resultant anisotropy for the alloy is determined by the combination of the magnetocrystalline and stress-induced anisotropy energies, and degenerates from cubic into uniaxial at a critical stress. When a field is applied to the alloy along the [112] axis, the alloy under the compressive stress is more difficult to magnetize and can attain a maximum change in bulk magnetostriction at the critical stress. The main reason for the large bulk magnetostriction is that the fractional occupancy of the [111] or [111]-oriented domains increases from 1/8 to 1/2 with the stress. This more accurate computation has been proposed for similar investigations and the results will also be helpful for a better understanding of the magnetostriction in materials such as the FeGa alloys. [ABSTRACT FROM AUTHOR]

Amorphous Fe(II)-Fe(III) hydroxy complex with flower-like nanostructure was synthesized by ferric reduction using a microwave-assisted ethylene glycol approach. Here we investigated the correlation between its chemical composition and the removal rate for Congo red (CR) dye. The results showed that the amorphous complex had similar reduction and anion exchange capacities to the green rust. Due to the synergistic effect of attractive electrostatic interaction, anion exchange, ferrous redox and hydrogen bonding, the Fe(II)-Fe(III) hydroxy complex exhibited strong adsorption of CR with an estimated adsorption capacity up to 513 mg g-1. In contrast, the Fe(III) hydroxy complex had an adsorption capacity of 296 mg g-1 because of the predominant mechanism based on the electrostatic interaction. The present study provides a facile synthesis of nanostructured iron hydroxy complex, with superior performance in adsorbing CR. [ABSTRACT FROM AUTHOR]

A strain-driven orthorhombic (O) to rhombohedral (R) phase transition is reported in La-doped BiFeO3 thin films on silicon substrates. Biaxial compressive epitaxial strain is found to stabilize the rhombohedral phase at La concentrations beyond the morphotropic phase boundary (MPB). By tailoring the residual strain with film thickness, we demonstrate a mixed O/R phase structure consisting of O phase domains measuring tens of nanometers wide within a predominant R phase matrix. A combination of piezoresponse force microscopy (PFM), transmission electron microscopy (TEM), polarization-electric field hysteresis loop (P-E loop), and polarization maps reveal that the O-R structural change is an antiferroelectric to ferroelectric (AFE-FE) phase transition. Using scanning transmission electron microscopy (STEM), an atomically sharp O/R MPB is observed. Moreover, X-ray absorption spectra (XAS) and X-ray linear dichroism (XLD) measurements reveal a change in the antiferromagnetic axis orientation from out of plane (R-phase) to in plane (O-phase). These findings provide direct evidence of spin-charge-lattice coupling in La-doped BiFeO3 thin films. Furthermore, this study opens a new pathway to drive the AFE-FE O-R phase transition and provides a route to study the O/R MPB in these films. [ABSTRACT FROM AUTHOR]

In this study, controllable morphology evolution of hexagonal strontium ferrite (SrFe12O19) micro/nano-crystals has been demonstrated. Single phase strontium ferrite platelets with hexagonal morphology were successfully prepared by conventional ceramic process. In the hexagonal crystals, it is revealed that the anisotropic growth rate is changed, with the increasing of ball milling time, from relatively high rate along the <001> direction (c-axis) to direction, leading to the morphology evolution. Moreover, the optimal saturation magnetization (MS) is 69.5 emu/g, which is intensely close to the theoretical value (72 emu/g). This study provides the direct evidence of the enhanced reaction activity induced by high energy ball milling in strontium hexaferrite platelets and the obtained SrFe12O19 particles are promising for the hard magnet application and the magnetoelectric electronics. [ABSTRACT FROM AUTHOR]

A wealth of fascinating phenomena have been discovered at the BiFeO3 domain walls, examples such as domain wall conductivity, photovoltaic effects, and magnetoelectric coupling. Thus, the ability to precisely control the domain structures and accurately study their switching behaviors is critical to realize the next generation of novel devices based on domain wall functionalities. In this work, the introduction of a dielectric layer leads to the tunability of the depolarization field both in the multilayers and superlattices, which provides a novel approach to control the domain patterns of BiFeO3 films. Moreover, we are able to study the switching behavior of the first time obtained periodic 109° stripe domains with a thick bottom electrode. Besides, the precise controlling of pure 71° and 109° periodic stripe domain walls enable us to make a clear demonstration that the exchange bias in the ferromagnet/BiFeO3 system originates from 109° domain walls. Our findings provide future directions to study the room temperature electric field control of exchange bias and open a new pathway to explore the room temperature multiferroic vortices in the BiFeO3 system. [ABSTRACT FROM AUTHOR]

The density of the heat flow due to quenching in high-pressure gas (nitrogen) is computed with the help of the finite-element method and FLUENT software based on a mathematical model of turbulent flow. The effects of temperature and pressure on the characteristics of the nitrogen medium and the variation of the thermal radiation properties of metallic materials as a function of the temperature are considered. [ABSTRACT FROM AUTHOR]