Search

We show that the transmission of light through metallic hole arrays supported by a glass substrate can be tuned by depositing a controlled number of Langmuir–Blodgett layers on top of the hole array. Enhanced transmission is achieved when the number of overlayers is such that the surface plasmon-polariton modes on the two sides of the metal hole array have matched wavevectors. Dye molecules introduced into some of these overlayers allow us to explore the relationship between molecular fluorescence and the transmission properties of the structure, through measurement of the fluorescence lifetime of the molecules. We find there to be little change in the fluorescence lifetime between enhanced and non-enhanced transmission regimes and offer an explanation of our findings in terms of changes in the photonic mode density. [ABSTRACT FROM AUTHOR]

We present experimental results showing the variation in photoluminescence from an organic material emitted through a thin metal film as successive dielectric overlayers are added to the far side of the metal. The intensity of the emission from the structure is examined as the surface plasmon–polariton (SPP) modes associated with the two metal surfaces evolve with increasing overlayer thickness from individual to coupled SPP modes. The SPP modes are scattered to produce light by the addition to the metal film of wavelength-scale periodic microstructure. We show that the addition of a dielectric overlayer of an appropriate thickness to the metal film is accompanied by an increase in the intensity of the emission by a factor of 3 over a similar structure with no dielectric overlayer, and by a factor of 50 over a similar planar structure. We show that this increase in emission is mediated via coupled SPP modes. [ABSTRACT FROM AUTHOR]

We used cavity quantum electrodynamic effects to determine the orientation of a species of organic dye molecule located in a microcavity environment. We used the Langmuir-Blodgett technique to fabricate well-controlled multilayer structures into which we incorporated dye molecules with well-defined layer positions. Comparing the results of fluorescence lifetime measurements and radiation patterns with theoretical calculations allowed us to determine both the orientation and the quantum efficiency of the dye molecules. [ABSTRACT FROM AUTHOR]