1. Biodiesel production from waste cooking oil through transesterification using novel double layered hydroxide catalyst.
- Author
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Mothil, S., Devi, V. Chitra, Raam, R. Sathish, Asmitha, P., Gokul, A., and Balakumar, B.
- Subjects
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CATALYSTS , *LAYERED double hydroxides , *FLAME ionization detectors , *CHEMICAL processes , *BIODIESEL fuels , *TRANSESTERIFICATION , *WASTE treatment , *HYDROTHERMAL deposits - Abstract
Mg-Al hydrotalcite was synthesized using co-precipitation aqueous solution of Mg(NO3)2.6H2O and Al(NO3)3.9H2O followed by hydrothermal treatment at 110°C for 12 hours. In layered double hydroxide, the divalent cations in the brucite like layers are reinstated by trivalent cations, also this is known as hydrotalcite. Hydrotalcite plays an important role as catalysts for many process and as various other applications. Hydrotalcite has various applications as anion exchanger, antacid in medical field, and also in various waste water treatment methods. This novel catalyst can be used effectively in organic chemical synthesis and processes like Aldol condensation, Claisen–Schmidt condensation, Knoevenagel condensation and in various oxidation reactions. In this study, Mg-Al hydrotalcite was utilized for transesterification of waste cooking oil. Biodiesel was synthesized through single stage transesterification process using methanol (20:1 to 40:1) and Mg-Al hydrotalcite by continuously stirring for 1.5 – 3.5 hours at 80-160°C. The suspended impurities in waste cooking oil are first removed using a filter and heated to 120°C to remove moisture. The objective was to maximize the yield of biodiesel by varying the process conditions (methanol-to-oil molar ratio, temperature, time) and heterogeneous Mg-Al hydrotalcite catalyst. Biodiesel conversion was determined by estimating and evaluating methyl ester content (FAME, %) by gas chromatography with flame ionization detector (FID). [ABSTRACT FROM AUTHOR]
- Published
- 2021
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