1. Rotating Micro-Spheres for adsorption monitoring at a fluid interface.
- Author
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Martín-Roca, J., Jiménez, M., Ortega, F., Calero, C., Valeriani, Ch., Rubio, R.G., and Martínez-Pedrero, F.
- Subjects
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MICROSPHERES , *ADSORPTION (Chemistry) , *ADSORPTION kinetics , *ROTATING fluid , *ANIONIC surfactants , *MAGNETIC particles , *ZETA potential , *FOAM - Abstract
Microspheres forced to rotate in the vicinity of a fluid interface exhibit a roto-translational hydrodynamic mechanism that is strongly hampered by capillary torques as soon as the particles protrude from the interface. Under these conditions, the time evolution in the number of moving spheres provides a direct description of the adsorption kinetics, while microscopy monitoring of particle deceleration informs about the adsorption dynamics. [Display omitted] A broad range of phenomena, such as emulsification and emulsion stability, foam formation or liquid evaporation, are closely related to the dynamics of adsorbing colloidal particles. Elucidation of the mechanisms implied is key to a correct design of many different types of materials. Microspheres forced to rotate near a fluid interface exhibit a roto-translational hydrodynamic mechanism that is hindered by capillary torques as soon as the particles protrude the interface. Under these conditions, the time evolution in the ratio of moving spheres provides a direct description of the adsorption kinetics, while microscopy monitoring of particle acceleration\deceleration informs about the adsorption\desorption dynamics. In this work, the proposed strategy is applied at an air/water interface loaded with spherical magnetic particles negatively charged, forced to rotate by the action of a rotating magnetic field. The proposed method enables the adsorption/desorption dynamics to be followed during the earliest phase of the process, when desorption of a small fraction of particles is detected, as well as to estimate approximated values of the adsorption/desorption constants. The results obtained show that the addition of a monovalent salt or a cationic (anionic) surfactant promotes (inhibits) both adsorption and formation of permanent bonds between particles. [ABSTRACT FROM AUTHOR]
- Published
- 2022
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