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Provides information on a study of the effect of ortho substituents on the direction of 1,2-migrations in the rearrangement of 2-exo-arylfenchyl alcohols. Methodology used to conduct the study; Indepth look at the preparation of arylfenchyl alcohols; Results of the study; Discussion on the results.

Investigates the diastereoselective conjugate addition of dilithiated secondary amines to cyclopent-2-enone. Utility of conjugate additions to organic synthesis; Conjugate additions of lithiated allylic systems; Structural features of dilithiated secondary amides; Nature of lithium coordination; Reaction mechanism.