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Two types of additive manufacturing (AM) techniques, fused filament fabrication (FFF) and selective laser sintering (SLS), were employed to fabricate specimens from three widely used AM polymers: polylactic acid (PLA), acrylonitrile butadiene styrene (ABS), and polyamide (PA): the first two using FFF and PA using SLS. The single‐edge notch bending (SENB) test was employed to measure the mode‐I fracture toughnesses of bulk and AM specimens in three directions relative to the printing direction. Unlike their bulk counterparts, AM polymers exhibited anisotropic fracture toughness. The degree of anisotropy in FFF‐PLA was much larger than FFF‐ABS and SLS‐PA. The smallest fracture toughness value for each AM polymer was achieved along the transverse printing direction. Different AM techniques affect fracture toughness differently. For instance, FFF is shown to increase PLA's plastic deformation, while SLS reduces PA's ductility. The decrease in fracture toughness is consistently observed when transitioning from bulk polymers to AM ones, reaching as much as 75%. This study provides insights into the fracture toughness of AM parts made via popular plastics, which are crucial for designing structural parts using FFF and SLS processes. Highlights: Additively manufactured polymers always exhibit some anisotropic fracture toughnessDifferent additive manufacturing techniques affect the fracture toughness differentlyFused filament fabrication increases polylactic acid's plastic deformationBut selective laser sintering reduces polyamide's ductility [ABSTRACT FROM AUTHOR]

• Commonly used Tsai-Hill strength criterion mainly predicted the yield strength. • Suggested quadratic strength criterion provided a lower bound of the ultimate strength. • These results were verified by anisotropic ultimate strengths of major 3D printing metals. 3D printing metals have an intrinsic building orientation, so they have some anisotropy in their strength due to the failure between the printing layers with direction dependence that was commonly seen in composite materials. Although the Tsai-Hill composite strength criterion predicted the ultimate strengths of some 3D printing metals made with selective laser melting and laser powder bed fusion (SLM/LPBF), the current study showed that the composite strength criterion was not applicable to the ultimate strength predictions of all 3D printing metals. Our suggested quadratic strength criterion without stress interaction provided conservative strength predictions to ensure safe 3D printing metal applications. Moreover, the shear strength plays a critical role in strength predictions and should be measured accurately. [ABSTRACT FROM AUTHOR]

Unlike isotropic homogenous materials, 3D printing polymers are anisotropic in terms of their strength and fracture toughness properties, according to previous research. Therefore, the lowest strength must be accurately measured before the extensive application of any 3D printing materials. Certain 3D printing materials have been increasingly employed in large structures; therefore, the size effect of their strengths has become very important. In this work, we performed a systematic experimental investigation on the minimum strengths and size effects of four common 3D printing polymers made by fusion deposition modeling and injection molding. Three types of tensile specimens with very different cross-sectional areas were selected. For each material system, two types of specimens with different printing surface angles were employed. The results from 200 specimens demonstrated that the minimum tensile strengths in the build direction of some specimens were only 25% that of the other directions in the same specimens, and 59% of the injection-molded specimens composed of the same material. No general conclusion on the size effects of the tensile strengths could be made for most specimens. Only the strengths along the build direction decreased up to 72% in two types of specific specimens if their cross-sectional areas increased by 60 times. Although their strengths were anisotropic, the stiffness properties of the 3D printing polymers were isotropic. Digital image correlation measurements showed that the Young's moduli of all specimens composed of the same material were similar. A dual-notch mechanics model was employed to explain the anisotropic strengths, and a fractography analysis supported the size effect. [Display omitted] • Tensile strength along the build direction was the minimum strength. • No general conclusion on the size effects of the tensile strengths could be made. • Strengths decreased 72% in only PLA and PC specimens if their areas increased by 60 times. [ABSTRACT FROM AUTHOR]

The present work investigated the development of sand bed scour by submerged circular impinging vertical turbulent jets over a wide regime of jet diameters, exit velocities and impinging distances. The scour hole profiles were recorded with the optical method in order to present dynamic scour hole characteristics and their variation with any time. The results revealed that the scour profiles in the equilibrium state are similar and the geometries of the sour hole in the jet central region are only determined primarily by jet momentum flux. A semi-empirical equation has been developed for the maximum dimensionless scour depth in equilibrium state based on the obtained experimental data and theoretical analysis. The evolution of scour hole is found to be logarithmic, and three phases of temporal evolution were further distinguished. Finally, models for the prediction of variation of scour depth with time have been developed and validated, which could be used to assess the scour effects generated by impinging turbulent jets. The overall temporal evolution of the scour depth can be predicted by the erosion parameter E c and the dimensionless time to reach equilibrium τ ∞ , which is superior to existing models in predicting the scouring process. • The scour hole profiles were recorded with the optical method in order to present dynamic scour hole characteristics. • A semi-empirical equation has been developed for the maximum dimensionless scour depth in equilibrium state. • Models for the prediction of variation of scour depth with time have been developed and validated. [ABSTRACT FROM AUTHOR]

Because additively manufactured materials are increasingly being used in load-bearing structures, strength research has become critical. Surprisingly, numerous studies have reported the tensile strength measurements, but only a few studies have presented meaningful results for the shear strength measurements of additively manufactured polymers. Hence, this paper proposes a combined experimental and numerical investigation of a new interlayer shear strength measurement approach, and it targeted the applications of the same polyamide (PA12) specimens made with fused deposition modeling (FDM) and selective laser sintering (SLS). A necking-shaped shear specimen was developed to measure the pure shear strengths with the aid of a three-dimensional (3D) finite element analysis. The results showed that the specimens made with FDM and SLS exhibited totally different shear failure behaviors. The ultimate shear strength of the FDM-PA specimens had more than a 32% increase over that of the SLS-PA specimens. An interface mechanics assumption was employed to explore the different shear failure mechanisms with the support of a fractography analysis. [ABSTRACT FROM AUTHOR]

Highlights: [•] Synthesis of phenanthroimidazole derivatives with terminal carbazole or pyrene. [•] Photophysical properties of phenanthroimidazole derivatives. [•] Electroluminescent properties of phenanthroimidazole derivatives. [ABSTRACT FROM AUTHOR]

Nanofibers based on phenanthroimidazole derivatives PCC, PDC, and PSC were fabricated by organogelation processes, and their fluorescence sensory properties towards acid were investigated. It was found that the emission of PCC in the nanofiber-based film could be quenched significantly upon exposure to gaseous TFA due to the formation of protonated PCC, in which ICT (intramolecular charge transfer) would occur. On the other hand, TFA vapor led to the emitting colors of PDC and PSC in the nanofiber-based films to turn to yellow and green from sky blue and blue, respectively. Additionally, we found that the decay times of PCC were 0.1 s and 1.9 s in probing the saturated vapor of TFA in nanofiber-based film and in spin-coated film, respectively. The results suggested that the high surface-to-volume ratio and large interspace in the nanofiber-based networks favored the enhanced adsorption, accumulation, and diffusion of gaseous molecules, resulting in such a high performance. [ABSTRACT FROM AUTHOR]

New branched benzothiadiazole-cored conjugated oligomers with terminal carbazoles 1 and 2 have been synthesized. It was found that no obvious shifts of the maximal absorption bands for 1 and 2 were detected in the films compared with those in solutions, indicating weak π-π stacking occurred in the solid states on account of site isolation effect of the branched architectures. Hence, the synthesized oligomers could emit strong red light in the films. Notably, the emission of the films based on 1 and 2 could be quenched obviously upon exposed to gaseous TNT and DNT. The fluorescence quenching efficiency of the oligomer 2 -based film reached 91% when exposed to the saturated vapor of DNT for 3 min at 55 °C. The linear Stern–Volmer plot and the decrease of the fluorescence lifetime of 2 induced by DNT suggested the fluorescence sensing mechanism was due to the photo-induced electron transfer. [ABSTRACT FROM AUTHOR]