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Agricultural activities contribute significantly to the pollution of groundwater through the incomplete absorption of nitrogen (N) and phosphorus (P). Understanding the vertical migration patterns of N and P in soil solution is crucial for controlling groundwater quality. This study is based on monitoring data of soil solution nitrogen and phosphorus at different depths (30 cm, 60 cm, 100 cm) in the Huixian Wetland Experimental Area in the Li River Basin from March to December 2021. The vertical distribution patterns of nitrogen and phosphorus in soil solution in the study area are elucidated from three aspects: seasonal variations, karst types, and land use. The results indicate that the following: (1) NO3−-N is the predominant form of nitrogen, generally decreasing with increasing soil depth, while NH4+-N concentrations show slight increases and TP concentrations remain relatively stable. Overall, NO3−-N and TN concentrations tend to accumulate at 30 cm and 60 cm depths during both irrigation and non-irrigation seasons, with no distinct distribution patterns observed for NH4+-N and TP. (2) During the irrigation season, the migration distance of NO3−-N in non-karst landforms is mainly at 60 cm, while in peak forest plains, it is mainly at 100 cm, with no clear trend observed in NO3−-N concentrations in peak cluster depressions. In non-irrigation seasons, the distribution of NO3−-N content in non-karst landforms and peak cluster depressions is mainly 30 cm > 60 cm > 100 cm. The downward migration distance of NH4+-N generally follows the order of peak cluster depressions > peak forest plains > non-karst landforms. (3) During the irrigation season, NO3−-N concentrations in paddy fields remain relatively high at 100 cm, while in drylands, NO3−-N concentrations generally follow the pattern of 30 cm > 60 cm > 100 cm but may exhibit anomalous increases or decreases at 60 cm and 100 cm depths during heavy rainfall. [ABSTRACT FROM AUTHOR]

The Lijiang River Basin is a humid, subtropical, karst landform in China and is listed as a World Heritage Site. However, with the rapid development of urbanization and tourism activities in recent years, it faces increasingly severe non-point source pollution. To understand the temporal and spatial variations in nitrogen and phosphorus pollution discharge and the changes in river water quality, the Jingui Small Basin, in the upper reaches of the Lijiang River, was chosen as a representative system. Changes in nitrogen and phosphorus concentrations were continuously monitored in the main river channel and the river water quality was evaluated using the comprehensive water quality identification index method. The results indicated that there were obvious seasonal changes in nitrogen and phosphorus discharge loads in the basin. Both nitrogen and phosphorus discharge loads were higher in the crop-growing season than in the non-growing season. No significant difference in nitrogen and phosphorus discharge load between different scales was found, and the scale was not the key factor affecting the nitrogen and phosphorus discharge load of Jingui River. As the river flowed from the initial water source to the outlet of the basin, water quality was characterized by the spatial pattern of the upper reaches > the middle reaches > the lower reaches. Except for the water quality at the outlet of the basin in November and December, which reached Class V, the comprehensive water quality of each sub-basin reached the target water quality of the water function zoning from May to December. The elucidation of the nitrogen and phosphorus pollution discharge patterns in the Jingui River and the changes in water quality provide a reference for the control and management of agricultural non-point source pollution in the Lijiang River Basin. [ABSTRACT FROM AUTHOR]

Nitride perovskite LaWN3 has been predicted to be a promising ferroelectric material with unique properties for diverse applications. However, due to the challenging sample preparation at ambient pressure, the crystal structure of this nitride remains unsolved, which results in many ambiguities in its properties. Here, the authors report a comprehensive study of LaWN3 based on high‐quality samples synthesized by a high‐pressure method, leading to a definitive resolution of its crystal structure involving nitrogen deficiency. Combined with theoretical calculations, these results show that LaWN3 adopts an orthorhombic Pna21 structure with a polar symmetry, possessing a unique atomic polarization along the c‐axis. The associated atomic polar distortions in LaWN3 are driven by covalent hybridization of W: 5d and N: 2p orbitals, opening a direct bandgap that explains its semiconducting behaviors. The structural stability and electronic properties of this nitride are also revealed to be closely associated with its nitrogen deficiency. The success in unraveling the structural and electronic ambiguities of LaWN3 would provide important insights into the structures and properties of the family of nitride perovskites. [ABSTRACT FROM AUTHOR]

Maintaining good water quality in the Lijiang River is a scientific and practical requirement for protecting and restoring the environmental and ecological value of the river. Understanding the influence of non-point source pollution on the water quality of the Lijiang River is important for water quality maintenance. In this study, the pollutant flux in the upper reaches of the Lijiang River was calculated based on water quality monitoring, non-point source pollution, and point source pollution statistics. The Z–Q relation curve method, hydrologic analogy method, and contour map method were used to estimate the flow of the Lijiang River. We then constructed a water quantity–water quality balance model of the upper reaches of the Lijiang River based on an equilibrium equation of water quantity and a modified one-dimensional steady-state model of the river. Water quality changes in the upper reaches were simulated for a wet, normal, and dry season. The simulation errors were all within −30% to 30%, which was in line with the pollution simulation requirements of the Standard for hydrological information and hydrological forecasting (GB/T 22482-2008). The simulated reliability of each water quality indicator is at a high level, based on the calculated Nash–Sutcliffe efficiency coefficient. The overall model simulation results were good. The simulation results show that the impact of non-point source pollution on the water quality of the upper reaches of the Lijiang River was greater than that of point source pollution. The effect of different types of non-point source pollution on the water quality of the Lijiang River was as follows: rural domestic pollution > urban household pollution without centralized treatment > pollution from agricultural cultivation. This study provides technical support for the long-term hydrology and water quality monitoring of the Lijiang River and provides a basis for the reduction in non-point source pollution and the continuous improvement of the water quality in the Lijiang River Basin. [ABSTRACT FROM AUTHOR]

We analyzed the characteristics of main karstic/non-karst reaches of the Lijiang River to uncover the causes behind different flood behaviors by providing a better understanding of the flood formation. Having 63 years of rainfall-runoff data and applying the HEC-HMS model, geo/hydrological features were investigated. The available reservoir capacity of karts (ARCK) was included through soil moisture accounting loss data to assess its impact. In particular, the expected instantaneous peak discharge rates/times were found largely imbalanced with generated unit hydrographs. Moreover, significant gaps among the floods' features for different subbasins in terms of required peak modifications (2-4 times larger for mid-upstream, respectively) were mainly associated with the unique karst structure and initial condition due to various ARCK in rainy/dry seasons. Besides, notable dissimilarities between the wedge/prism storage volumes and the hydrograph's wave traveling/receding time were observed owing to the geomorphological conditions. Although the contribution rates of drivers in karst flood formation cannot be quantitively modeled, based on our results the ARCK emerged to play a substantial role on the forecasted results, comparatively. Our results suggest that since ARCK varies, taking it into account (as initial abstraction) results in a more reliable estimation. This was underpinned by the results in which the unmodified simulations had a qualified rate of 52% accuracy on average and increased to 67.5% after the ARCK inclusion. This work adds to the body of evidence illustrating that in karst hydrology, ignoring the situational circumstances in modeling might lead to inaccuracies in flood forecasting for such dynamic watersheds. [ABSTRACT FROM AUTHOR]

In this study, we investigated the influence of different simulations on the transport of shallow groundwater nitrogen in the Mudong River watershed of the Huixian Wetland, a karst wetland. Based on GMS (Groundwater Modeling System) software, the equivalent porous media model was used to simulate the transport of total nitrogen under different conditions in the study area. Two years of field monitoring data in the study area provided the input for the modeling. The SWAT (soil and water assessment tool) model was used to divide the study area into sub-basins. The initial concentration flux index W is first introduced in the equivalent porous medium model to calculate the initial concentration. The simulation results showed the difference between the simulated and monitored values of total nitrogen concentration was between 20% and 40% in 22.2% of the cases, and less than 20% in 66.7% of the cases, indicating that the solute transport model has good applicability in the Huixian Wetland. Parameter sensitivity analysis showed that fertilizer application was the main factor influencing total nitrogen. A 25% reduction in fertilizer application reduced total nitrogen emissions by 31.5% in sub-basin S3 and 22.5% in sub-basin S4. These reductions were greater than the abatement effect of changing land cover and managing river pollution. The pollution plume of total nitrogen was reduced by 38.5% in the southern part of sub-basin S3 (Mudong Lake) and by 40.2% in the western part of sub-basin S4 (Blacksmithing Village). The average concentration was reduced by 2.04 mg/L and 1.22 mg/L, respectively. This study shows that reasonable control of double-season rice nitrogen fertilizer application and appropriate land cover modification can help reduce total nitrogen emissions from wetlands in the Li River watershed and ensure the sustainable development of the local economy and groundwater. [ABSTRACT FROM AUTHOR]

Emerging functionalities in two-dimensional materials, such as ferromagnetism, superconductivity and ferroelectricity, open new avenues for promising nanoelectronic applications. Here, we report the discovery of intrinsic in-plane room-temperature ferroelectricity in two-dimensional Bi2TeO5 grown by chemical vapor deposition, where spontaneous polarization originates from Bi column displacements. We found an intercalated buffer layer consist of mixed Bi/Te column as 180° domain wall which enables facile polarized domain engineering, including continuously tunable domain width by pinning different concentration of buffer layers, and even ferroelectric-antiferroelectric phase transition when the polarization unit is pinned down to single atomic column. More interestingly, the intercalated Bi/Te buffer layer can interconvert to polarized Bi columns which end up with series terraced domain walls and unusual fan-shaped ferroelectric domain. The buffer layer induced size and shape tunable ferroelectric domain in two-dimensional Bi2TeO5 offer insights into the manipulation of functionalities in van der Waals materials for future nanoelectronics. Tunability of ferroelectric domain structure is significant in ferroelectric materials. Here, the authors present in-plane ferroelectricity in 2D Bi2TeO5 in which the ferroelectric domain size and shape can be continuously tuned by the Bi/Te ratio. [ABSTRACT FROM AUTHOR]

The objective of this work was to modify the HEC-HMS flood prediction for the karstic watershed of the Lijiang River, South China, through the quantitative inclusion into the model of the available reservoir capacity of karst (ARCK) as a case study. Due to the complexities caused by hidden drainage networks in karst hydrology, as a new approach, soil moisture accounting loss was used to reflect the ARCK in flood forecasting. The soil moisture loss was analyzed against daily rainfall runoff data across 1.5 years by using an artificial neural network via phyton programming. Through the correlations found among the amounts of soil moisture and river flow fluctuations in response to precipitation and its intervals, coefficients were introduced to the model for output modifications. ARCK analysis revealed that while heavy rainfalls with longer intervals (i.e., 174 mm/2d after 112 days of the dry season) may not cause considerable changes in the river flow magnitude (0.1–0.64 higher owing to high ARCK), relatively small rainfalls with higher frequency (i.e., 83 mm/4d during the wet season) can cause drastic raise of river flow (10–20 times greater at different stations) due to lower ARCK. Soil moisture accounting loss coefficients did enhance the model's simulated hydrographs accuracy (NSE) up to 16% on average as compared to the initial forecasting via real data. However, the modifications were valid for flood events within a few years from the soil moisture observation period. Our result suggested that the inclusion of ARCK in modeling through soil moisture accounting loss can lead to increased prediction accuracy through consistent monitoring. [ABSTRACT FROM AUTHOR]

In view of the premature convergence of particle swarm optimization (PSO) that is often caused by the loss of diversity, an improved cooperative PSO (ICPSO) is proposed. The method can dynamically combine the optimum values of the particles themselves, the global particles and the optimum values in groups, use the current optimization stage to dynamically adjust the shared proportion of information and effectively fuse various reference information, which can obtain superior global and local optimization performance. Additionally, to improve the diversity of the algorithm, a dynamic adjustment method using the grouping coefficient r for the convergence rate is put forward. This method makes the algorithm have a more appropriate convergence rate while improving the convergence precision and enhancing the performance of the algorithm. Finally, the algorithm is used to optimize a neural network. The convergence condition and convergence rate of the algorithm are assessed by theoretical analysis and simulation experiments. The results show that ICPSO has more advantages in its diversity and the adjustment of the convergence rate compared to other related algorithms. Regarding neural network optimization, the training speed and optimization precision of the ICPSO-BP neural network are the highest, which has reached the best and average level of classification accuracy 98.5%, 96.3% for 20 iterations in Iris, and 98.7%, 95.1% in Wine. Its average iteration times score the best in five problems out of six. [ABSTRACT FROM AUTHOR]

The Uragen giant sandstone-hosted Zn–Pb deposit has a proven reserve of 5.90 Mt metals in the southern ore zone and potentially 10 Mt metals for the whole deposit, and orebodies are strictly confined to the bleached clastic rocks of the Lower Cretaceous red beds. The bleaching has been used to guide lead–zinc exploration; however, its nature and origin, as well as the relationship with Zn–Pb mineralization, remains unclear, although it is closely related to regional oil–gas infillings. Detailed field investigation and petrographic observation, TESCAN-integrated mineral analyzer (TIMA), and X-ray fluorescence (μ-XRF) analysis of the red and bleached sandstone at the same sedimentary layer demonstrate that the bleaching is mainly caused by the reductive dissolution of hematite pigment, which probably resulted from the interaction with H2S formed by in situ sulfate reduction during hydrocarbon migration. The calcite cements in the bleached sandstones show δ13C and δ18O values of −5.36~−5.94‰ and 20.94~27.91‰, respectively, and these samples fall close to the evolution line of decarboxylation of organic matter in δ13C-δ18O diagram, also suggesting a genetic relationship between the bleaching and hydrocarbon-bearing fluids. Petrol–mineral composition changes and sulfide characteristics of red, bleached, mineralized zones, as well as pyrite locally replaced by coarse-grained galena in the mineralized zone, imply that the bleaching may occurred before Zn–Pb mineralization. Mass balance calculation and μ-XRF analysis indicate that large amounts of Fe and minor Zn were extracted from red beds with little or no sulfates; however, the red beds with abundant sulfates may be a sink for leached ore metals during the bleaching process. We therefore propose that the former accumulations of iron sulfides and reduced sulfur in the bleached zones may provide an ideal chemical trap for later Zn–Pb mineralization, and the bleached zones with high ∑S contents are the favorable prospective targets of the Uragen-style sandstone-hosted Zn–Pb deposits. [ABSTRACT FROM AUTHOR]

Metal halide perovskites have gained huge research interest within few decades due to their optoelectronic applications. Recently, inorganic metal halide perovskites CsPbX3 (X = Cl, Br, I) has shown the improved stability with promising optical and electrical properties. We report the enhancement of PL intensity and the extension of carrier lifetime from strained CsPbBr3 microwires in air environment. PL intensity is enhanced more than fivefold for all the studied microwires under strain than the original. Maximum enhancement in PL intensity of more than 25-fold has been observed from a wire with lateral width of 630 nm. Based on the experiment and simulation results, we conclude that tensile strain can improve the oxygen adsorption by the defects on the surface of CsPbBr3 microwires, which will suppress the non-radiative transitions and enhance the light emission efficiency. These findings demonstrate that the strain engineering is an effective way to improve the performance of CsPbBr3 microstructures for optoelectronic applications. [ABSTRACT FROM AUTHOR]

Textile-reinforced concrete (TRC), a new composite material commonly used for repair and reinforcement of engineered structural surfaces, is easily affected by high temperatures in the event of fire. Therefore, when investigating the fire resistance of this material, it is important to evaluate and improve its high-temperature mechanical properties. In this study, ordinary portland cement and high-alumina cement TRC were prepared, with various proportions of metakaolin used to replace the cement, to investigate the changes in the mechanical properties of TRC and its deterioration mechanism. The experimental results showed that metakaolin improved the mechanical properties of ordinary portland cement sheets at low temperatures, with optimum substitutions of 15% and 20% in ordinary portland cement and high-alumina cement, respectively. Moreover, basalt fiber woven mesh was shown to significantly improve the ductility and flexural properties of TRC sheets, and high-alumina cement-based TRC exhibited superior bending properties at 800°C with 216.4% ultimate improvement over ordinary portland cement. The results of microscopic analysis and X-ray diffraction (XRD) experiments revealed that the decrease in the high-temperature mechanical performance of the TRC sheets was caused by a combination of high-temperature damage to the matrix concrete, deterioration or oxidative deterioration of the fibers themselves, and damage to the bonding surface of both the concrete and the fibers. At high temperatures, the microstructure of the high-alumina cement TRC was tighter and bonded more effectively to the basalt fiber grid. [ABSTRACT FROM AUTHOR]

Ferroelectric materials have been a key research topic owing to their wide variety of modern electronic and photonic applications. For the quick exploration of higher operating speed, smaller size, and superior efficiencies of novel ferroelectric devices, the ultrafast dynamics of ferroelectrics that directly reflect their respond time and lifetimes have drawn considerable attention. Driven by time‐resolved pump‐probe spectroscopy that allows for probing, controlling, and modulating dynamic processes of ferroelectrics in real‐time, much research efforts have been made to understand and exploit the ultrafast dynamics of ferroelectric. Herein, the current state of ultrafast dynamic features of ferroelectrics tracked by time‐resolved pump‐probe spectroscopy is reviewed, which includes ferroelectrics order parameters of polarization, lattice, spin, electronic excitation, and their coupling. Several potential perspectives and possible further applications combining ultrafast pump‐probe spectroscopy and ferroelectrics are also presented. This review offers a clear guidance of ultrafast dynamics of ferroelectric orders, which may promote the rapid development of next‐generation devices. [ABSTRACT FROM AUTHOR]

Beyond the absence of long-range magnetic orders, the most prominent feature of the elusive quantum spin liquid (QSL) state is the existence of fractionalized spin excitations, i.e., spinons. When the system orders, the spin-wave excitation appears as the bound state of the spinon-antispinon pair. Although scarcely reported, a direct comparison between similar compounds illustrates the evolution from spinon to magnon. Here, we perform the Raman scattering on single crystals of two quantum kagome antiferromagnets, of which one is the kagome QSL candidate Cu3Zn(OH)6FBr, and another is an antiferromagnetically ordered compound EuCu3(OH)6Cl3. In Cu3Zn(OH)6FBr, we identify a unique one spinon-antispinon pair component in the E2g magnetic Raman continuum, providing strong evidence for deconfined spinon excitations. In contrast, a sharp magnon peak emerges from the one-pair spinon continuum in the Eg magnetic Raman response once EuCu3(OH)6Cl3 undergoes the antiferromagnetic order transition. From the comparative Raman studies, we can regard the magnon mode as the spinon-antispinon bound state, and the spinon confinement drives the magnetic ordering. Spinon excitations of a Kagome quantum spin liquid are expected to give rise to a magnetic continuum in Raman spectroscopy. Here, the authors report a magnetic Raman continuum in the Kagome spin liquid candidate Cu3Zn(OH)6FBr, in contrast to a sharp magnon Raman peak in the Kagome antiferromagnet EuCu3(OH)6Cl3. [ABSTRACT FROM AUTHOR]

When considering the factors affecting the spatial and temporal variation of nitrogen and phosphorus in karst watersheds, the unique karst hydrogeology as an internal influencing factor cannot be ignored, as well as natural factors such as meteorological hydrology and external factors such as human activities. A watershed-scale field investigation was completed to statistically analyze spatial and temporal dynamics of nitrogen and phosphorus through the regular monitoring and collection of surface water and shallow groundwater in the agricultural-dominated Mudong River watershed in the Huixian Karst Wetland over one year (May 2020 to April 2021). Our research found that non-point source pollution of nitrogen (84.5% of 239 samples TN > 1.0 mg/L) was more serious than phosphorus (7.5% of 239 samples TP > 0.2 mg/L) in the study area, and shallow groundwater nitrogen pollution (98.3% of 118 samples TN > 1.0 mg/L) was more serious than surface water (68.6% of 121 samples TN > 1.0 mg/L). In the three regions with different hydrodynamic features, the TN concentration was higher and dominated by NO3−-N in the river in the northern recharge area, while the concentrations of TN and TP were the highest in shallow groundwater wells in the central wetland core area and increased along the surface water flow direction in the western discharge area. This research will help improve the knowledge about the influence of karst hydrodynamic features on the spatial patterns of nitrogen and phosphorus in water, paying attention to the quality protection and security of water in karst areas with a fragile water ecological environment. [ABSTRACT FROM AUTHOR]

Spatio-temporal dynamics of riverine nitrogen (N) and phosphorus (P) in karst regions are closely linked to hydrological conditions, human activities and karst features in upstream catchments. From October 2017 to September 2019, we undertook 22 sampling campaigns in 11 nested catchments ranging from 21.00 to 373.37 km2 in Huixian karst wetland to quantify forms, concentrations, and fluxes of riverine total nitrogen (TN) and total phosphorus (TP), and to identify spatial and temporal variations of nutrients transfer from upstream to downstream, tributaries (Mudong River and Huixian River) to the main stem (Xiangsi River) in the dry and wet seasons. Considering the hydrological conditions, human activities and karst features within upstream catchments, the following three spatial and temporal variations of riverine nutrients were found over the monitoring period: (1) the dynamics of riverine nitrogen and phosphorus varied seasonally with hydrological conditions; (2) the spatial disparities of riverine nitrogen and phosphorus were induced by different human activities within catchment scales; (3) the dynamics of riverine nitrogen and phosphorus varied similarly at spatial scale restricted by karst features. The findings from this study may improve our understanding of the influence of hydrological conditions, human activities and karst features on nitrogen and phosphorus variations in river waters at different spatial and temporal scales in the Huixian karst wetland basin, and will help managers to protect and restore river water environments in karst basin from a catchment-scale perspective. [ABSTRACT FROM AUTHOR]