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The characteristics of colored dissolved organic matter (CDOM) as well as the concentrations and stable isotope composition (δC) of dissolved organic carbon (DOC) were characterized in several large rivers of Africa including the Congo, Niger, Zambezi, and Ogooué basins. We compared the spatial and temporal patterns of dissolved organic matter (DOM) quantity and quality along with various environmental gradients, including hydrology, river size, catchment vegetation, and connectivity to land. The optical proxies used include the absorption coefficient at 350 nm, the specific ultra-violet absorbance, and the spectral slope ratio ( S = 275-295-nm slope divided by 350-400-nm slope). Our results show that land cover plays a primary role in controlling both DOC concentration and optical properties of DOM in tropical freshwaters. A higher cover of dense forest in the catchment leads to a higher quantity of highly aromatic DOM in the river network, whereas an increasing savannah cover results in lower DOC concentrations and less absorptive DOM. In addition to land cover, the watershed morphology (expressed by the average slope) exerts a strong control on DOC and CDOM in tropical rivers. Our results also show that the percentage of C3 and C4 vegetation cover is not an accurate predictor for DOM and CDOM quality in rivers due to the importance of the spatial distribution of land cover within the drainage network. The comparison of our results with previously published CDOM data in temperate and high-latitude rivers highlights that DOM in tropical freshwaters is generally more aromatic, and shows a higher capacity for absorbing sunlight irradiance. [ABSTRACT FROM AUTHOR]

We analyze past and future trends in nitrogen (N), phosphorus (P), and carbon (C) export by rivers to the coastal waters of Africa as calculated by the Global Nutrient Export to WaterShed (NEWS) models for the period 1970-2050. Between 1970 and 2000 the total nutrient export by African rivers increased by 10-80%. For future years (2000-2050) we calculate an increase in the total loads of dissolved forms of N and P, but decreasing trends for dissolved organic C and particulate forms of N and P. There are large regions that deviate from these pan-African trends. We explore the regional patterns and the underlying processes, in particular for the Nile, Zaire, Niger, and Zambezi. In the future, anthropogenic sources may, in large parts of Africa, become larger contributors to riverine nutrient loads than natural sources. [ABSTRACT FROM AUTHOR]