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Mineralogical and gemmological data of two intensely coloured chrysoberyls from Brazil are presented. Both samples are twinned, and they appear violet-purple or purple in daylight, and reddish purple or red-purple in incandescent light. They have good transparency, but appear very dark in reflected light due to their enriched chromium contents. In one sample, an average of 1.54 wt.% Cr2O3 was measured, together with 0.60 wt.% Fe2O3. The high Cr content is responsible for a reduced transmission in the blue-green range of the visible spectrum, which causes a shift in the daylight coloration from blue-green for typical Cr-bearing chrysoberyl (alexandrite) to violet-purple or purple for such samples with distinctly higher Cr values. [ABSTRACT FROM AUTHOR]

Fine gem-quality, purplish-red garnets from the Tocantins State, Brazil, were investigated for their crystal chemistry and optical properties by several spectroscopic techniques, including electron microprobe analysis, Mössbauer, Raman spectroscopy and optical absorption. Although most garnets are purplish-red, some specimens show color zoning, with deep red color in the core and purple in the outer parts. Electron microprobe analysis showed that these garnets are principally almandine-pyrope solid solution at the rim. However, at the red core, they contain also up to 7 % of spessartine. Mössbauer spectroscopy reveals that the iron content is predominantly Fe (>99 %) in the natural garnets. The optical absorption spectra are dominated by spin-allowed and unusual high-intense spin-forbidden transitions from eightfold coordinated Fe(II) in the near infrared and visible spectral region, respectively. For the red core, in addition, three sharp bands centered in the blue part of the visible spectral range and a broad charge transfer band in the near-UV region are observed. All garnets with purplish colors show also a remarkable color-changing effect from purple in daylight light to red in incandescent light called alexandrite-like effect. Heat treatments in the 700-900 °C temperature range in oxidizing and reducing atmospheres lead to reversible and irreversible color changes which are discussed based on the microscopic changes in the Fe ion coordination and valence states. [ABSTRACT FROM AUTHOR]

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The article focuses on history of kunzite, a variety of spodumene that can be recognize for its pink and lilac to bluish-purple color. It states Fred M. Sickler is credited as the discovery of spodumene gem because he is the first to present an example of the mineral to George F. Kunz. It also mentions that kunzite was discovered at Simmons mine, Pala Chief Mine, and Vanderberg mine. It also mention that there were kunzite finds in California, Brazil, and Madagascar.

New U–Pb zircon and 40Ar–39Ar K-feldspar data are presented for syn-sedimentary volcanogenic rocks from the Neoproterozoic Maricá Formation, located in the southern Brazilian shield. Seven (of nine) U–Pb sensitive high-resolution ion microprobe analyses of zircons from pyroclastic cobbles yield an age of 630.2±3.4 Ma (2σ), interpreted as the age of syn-sedimentary volcanism, and thus of the deposition itself. This result indicates that the Maricá Formation was deposited during the main collisional phase (640–620 Ma) of the Brasiliano II orogenic system, probably as a forebulge or back-bulge, craton-derived foreland succession. Thus, this unit is possibly correlative of younger portions of the Porongos, Brusque, Passo Feio, Abapã (Itaiacoca) and Lavalleja (Fuente del Puma) metamorphic complexes. Well-defined, step-heating 40Ar–39Ar K-feldspar plateau ages obtained from volcanogenic beds and pyroclastic cobbles of the lower and upper successions of the Maricá Formation yielded 507.3±1.8 Ma and 506.7±1.4 Ma (2σ), respectively. These data are interpreted to reflect total isotopic resetting during deep burial and thermal effects related to magmatic events. Late Middle Cambrian cooling below ca. 200 °C, probably related to uplift, is tentatively associated with intraplate effects of the Rio Doce and/or Pampean orogenies (Brasiliano III system). In the southern Brazilian shield, these intraplate stresses are possibly related to the dominantly extensional opening of a rift or a pull-apart basin, where sedimentary rocks of the Camaquã Group (Santa Bárbara and Guaritas Formations) accumulated. [ABSTRACT FROM AUTHOR]

Several letters to the editor are presented in response to articles including "Mineral Oddities" by Robert Cook in the January/February 2009 issue and "Spessartine from Navegadora Mine, Minas Gerais, Brazil" by John White in the January/February 2009 issue, and one which calls for papers for the Gem and Mineral Show on February 13, 2010.

The Boqueirão granitic pegmatite, alias Alto da Cabeça pegmatite, is situated in Borborema Pegmatitic Province (BPP) in Northeast Brazil. This pegmatitic province hosts globally important reserves of tantalum and beryllium, as well as significant quantities of gemstones, including aquamarine, morganite, and the high-quality turquoise-blue "Paraíba Elbaite". The studied lithium-cesium-tantalum Boqueirão granitic pegmatite intruded meta-conglomerates of the Equador Formation during the late Cambrian (502.1 ± 5.8 Ma; 40Ar/39Ar plateau age of muscovite). The pegmatite exhibits a typical zonal mineral pattern with four defined zones (Zone I: muscovite, tourmaline, albite, and quartz; Zone II: K-feldspar (microcline), quartz, and albite; Zone III: perthite crystals (blocky feldspar zone); Zone IV: massive quartz). Huge individual beryl, spodumene, tantalite, and cassiterite crystals are common as well. Microscopic examinations revealed that melt inclusions were entrapped simultaneously with fluid inclusions, suggesting the magmatic–hydrothermal transition. The magmatic–hydrothermal transition affected the evolution of the pegmatite, segregating volatile compounds (H2O, CO2, N2) and elements that preferentially partition into a fluid phase from the viscous silicate melt. Fluid inclusion studies on microcline and associated quartz combined with microthermometry and Raman spectroscopy gave an insight into the P-T-X characteristics of entrapped fluids. The presence of spodumene without other LiAl(SiO3)2 polymorphs and constructed fluid inclusion isochores limited the magmatic–hydrothermal transition at the gem-bearing Boqueirão granitic pegmatite to the temperature range between 300 and 415 °C at a pressure from 1.8 to 3 kbar. [ABSTRACT FROM AUTHOR]