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The implementation of space charge measurements based on thermal perturbation on thin films requires an improvement of the temperature distribution estimation at the surface and in the depth of dielectric materials for getting reliable space charge profile measurements. Absolute temperature variations are needed, both in time and space. The present contribution addresses surface temperature measurements based on either thermoelectric or bolometric effects. Both responses have been measured on coppercoated silicon nitride layers and gold-coated polypropylene films heated with a Nd:YAG laser pulse. It is shown that high temporal resolution thermal response can be obtained through the bolometric response and that the information appears nearly independent on the nature of the coating electrode. The setup developed provides good signal to noise ratio for heated electrodes of a few ohm resistance. Strategies are still to develop to get the temperature profile in the insulating sample layer. [ABSTRACT FROM AUTHOR]

Insufficient crosslinking and water uptake during fabrication or manipulation are known to affect the dielectric response of epoxies. Post thermal treatment may result in the completion of cross-linking, partial removal of water, and aging. In order to study the effect of manufacturing imprecision on dielectric response, several under-cured epoxy-based nanocomposite samples with modified nanoclay fillers were investigated. In addition, the influence of silane coupling agents and the use of ultrasonic waves on the nanoclay intercalation were also studied. The structure of the samples and the extent of cross linking were characterized using X-ray Diffraction (XRD) and Differential Scanning Calorimetry (DSC) respectively. It was found that surface silanization lead to improved clay intercalation and higher extent of intercalation/exfoliation. The influence of post thermal treatment on the dielectric response of the materials was investigated using Broadband Dielectric Spectroscopy (BDS). Once the samples were in a stable dielectric state, relaxation maps were performed. It was found that the samples with silanized nanoclay have the lowest activation energy and they also proved to be the "strongest" vitreous materials. [ABSTRACT FROM PUBLISHER]

In this work, we report the electric investigation of thin gallium nitride films by the thermal step method (TSM). The space charge dynamics was studied using the thermal step method with applied negative step (Δ T = −30 °C). The experimental TSM current indicates the presence of two peaks indicating the presence of two depletion widths in the silicon substrate and the GaN epilayer. The comparison between the theoretical and the measured TSM current indicates a good agreement for times less than 2 s. The divergence for times above 2 s is probably due to a thermoelectric current similar to Seebeck effect, due to the majority charge carriers’ contribution. [ABSTRACT FROM AUTHOR]

Experimental evidence was produced and gathered to demonstrate the distinct nature of nanostructured polymer microcomposites. The case of a polymer composite consisting of a high-content of micrometric quartz with a small adjunct of nanoclay is discussed. Emphasis is put on dielectric behavior studies while some results on thermal characteristics are presented. Overall results strongly support the potential of this class of insulating material for electrotechnical applications. [ABSTRACT FROM AUTHOR]

Proposes a thermal step method (TSM) for space charge measurements under applied direct current field. Review of the principle and the basic equations of the TSM when used on a short circuited flat insulating structure; Determination of the space charge distribution in an insulator under an external direct current field; Experimental setup and validation of the technique.

This work deals with the study of micro and nanosilica filled epoxy resin samples carried out in the framework of CIGRE WG D1.24 cooperative test program. This program focused on chemical, electrical and electrostatic properties of epoxy based nanodielectrics for electrical engineering applications. Epoxy based samples filled with micro and/or nanoparticles of silica were characterized by transmission electron microscopy, dielectric spectroscopy, conduction current and space charge measurements. These mutually complementary techniques were used to examine the effect of the size and quantity of silica particles on the electrical properties of the analyzed materials. The analysis of charge injection, polarization, trapping and conduction phenomena has allowed the modeling of dielectric behavior of the studied materials under multiple stresses. The Schottky Injection and Space Charge Limited Current models were studied to explain conduction phenomena. A composition of micro and nano-sized silica particles accumulating the smallest amount of space charge is also proposed. [ABSTRACT FROM AUTHOR]