1. Adopting the sol–gel auto-combustion approach to synthesize the La3+ substituted hexagonal ferrites suitable for permanent magnets and high-frequency applications.
- Author
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Hussain, Abrar, Sadiq, Imran, Mustafa, Ghulam Muhammad, Aboubakar, Muhammad, Sadiq, Farhan, Saeed, Samreen, Shahbaz, Muhammad, Abbas, Nadir, Ahmad, Muhammad Irfan, Riaz, Saira, and Naseem, Shahzad
- Abstract
In a recent study, La
+3 substituted T-type hexagonal ferrites S r 2 − x L a x F e 8 O 14 with concentration of (0.0 ≤ x ≤ 0.2) with increment of 0.05 step length was fabricated by sol–gel auto-combustion route. XRD results revealed that with the increment in the substitution of La+3 ions, the lattice parameters (a) and (c) decreased, and hence the unit cell volume decreased. The crystallite size was observed to vary in the range of 20.21–29.30 nm. The dielectric constant was observed to decrease as a function of frequency mean while the dielectric constant values declined with La3+ ions substitutions. The ac conductivity of samples enhanced with the increase in applied frequency. The FTIR spectra exhibited the absorption bands at different wave numbers (447, 570, and 1532 cm−1 ) indicating the stretching vibration of carbon-oxygen and metal-Oxygen ions within material. In the P-E graphs, the samples divulged the lossy behavior and this lossy behavior varied inversely with doping concentration. The decrease in lossy behavior was observed with the La3+ contents which unveiled the enhancement in resistivity of the samples. The saturation magnetization decreased with the substitution of La3+ contents which was reasoned to the spin canting effect of rare earth ions. The law of approach to saturation magnetization (LAS) was applied for fitting the magnetic curves and the results showed coincidence between the experimental and theoretical results. The coercivity of the samples increased drastically with La3+ ions substitution and the samples converted from soft magnetic materials to hard magnetic materials. The samples with high coercivity values might be suitable for high-density storage devices. Highlights: A series of T-hexaferrites was prepared by sol-gel auto combustion method. The XRD analysis confirmed the single phase for all samples. The c/a ratio of these samples falls in the range of Hexaferrites. The dielectric properties changes with the increase of La3+ contents. Magnetic properties varies with La3+ contents. [ABSTRACT FROM AUTHOR]- Published
- 2024
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