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1. Asymmetric Allylic Alkylation of Cyclic Vinylogous Esters and Thioesters by Pd-Catalyzed Decarboxylation of Enol Carbonate and β-Ketoester SubstratesWe thank the National Science Foundation and the National Institutes of Health, General Medical Sciences (Grant GM13598) for their generous support. J.X. was supported by Abbott Laboratories Fellowships. Mass spectra were provided by the Mass Spectrometry Regional Center of the University of California—San Francisco supported by the NIH Division of Research Resources. We thank Chirotech (now Dow) for their generous gifts of ligands and Johnson Matthey for gifts of Pd salts.

2. Asymmetric Allylic Alkylation of Cyclic Vinylogous Esters and Thioesters by Pd-Catalyzed Decarboxylation of Enol Carbonate and β-Ketoester SubstratesWe thank the National Science Foundation and the National Institutes of Health, General Medical Sciences (Grant GM13598) for their generous support. J.X. was supported by Abbott Laboratories Fellowships. Mass spectra were provided by the Mass Spectrometry Regional Center of the University of California—San Francisco supported by the NIH Division of Research Resources. We thank Chirotech (now Dow) for their generous gifts of ligands and Johnson Matthey for gifts of Pd salts.

8. Palladium-Catalyzed DYKAT of Vinyl Epoxides: Enantioselective Total Synthesis and Assignment of the Configuration of (+)-Broussonetine G ( DYKAT= dynamic kinetic asymmetric transformation. We thank the National Science Foundation and the National Institutes of Health (GM-13598), the Eli Lilly Corporation (fellowship to DBH), and the Deutsche Forschungsgemeinschaft (fellowship to MJW) for their generous support of our programs. We also thank Dr. Maiko Shibano and Prof. G. Kusano (Osaka University of Pharmaceutical Sciences) for NMR spectra and their donation of a sample of natural broussonetine G. Mass spectra were provided by the Mass Spectrometry Regional Center of the University of California-San Francisco supported by the NIH Division of Research. )

9. Palladium-Catalyzed DYKAT of Vinyl Epoxides: Enantioselective Total Synthesis and Assignment of the Configuration of (+)-Broussonetine G ( DYKAT= dynamic kinetic asymmetric transformation. We thank the National Science Foundation and the National Institutes of Health (GM-13598), the Eli Lilly Corporation (fellowship to DBH), and the Deutsche Forschungsgemeinschaft (fellowship to MJW) for their generous support of our programs. We also thank Dr. Maiko Shibano and Prof. G. Kusano (Osaka University of Pharmaceutical Sciences) for NMR spectra and their donation of a sample of natural broussonetine G. Mass spectra were provided by the Mass Spectrometry Regional Center of the University of California-San Francisco supported by the NIH Division of Research. )

10. An Enantioselective Biomimetic Total Synthesis of (−)-Siccanin ( We thank the National Science Foundation and the National Institutes of Health, General Medical Sciences (GM-13598) for their generous support of our programs. Mass spectra were provided by the Mass Spectrometry Regional Center of the University of California, San Francisco, supported by the NIH Division of Research Resources. )

11. An Enantioselective Biomimetic Total Synthesis of (−)-Siccanin ( We thank the National Science Foundation and the National Institutes of Health, General Medical Sciences (GM-13598) for their generous support of our programs. Mass spectra were provided by the Mass Spectrometry Regional Center of the University of California, San Francisco, supported by the NIH Division of Research Resources. )

12. Regioselective Hydrosilylation of Propargylic Alcohols: An Aldol Surrogate ( We thank the National Science Foundation and the National Institutes of Health, General Medical Science (GM-13598), for their generous support of our programs. Z.T.B. is a Stanford Graduate Fellow. Mass spectra were provided by the Mass Spectrometry Regional Center of the University of California–San Francisco supported by the NIH Division of Research Resources. )

13. Regioselective Hydrosilylation of Propargylic Alcohols: An Aldol Surrogate ( We thank the National Science Foundation and the National Institutes of Health, General Medical Science (GM-13598), for their generous support of our programs. Z.T.B. is a Stanford Graduate Fellow. Mass spectra were provided by the Mass Spectrometry Regional Center of the University of California–San Francisco supported by the NIH Division of Research Resources. )

14. Vanadium-Catalyzed anti-Selective Additions of Allenols to Imines ( We thank the National Science Foundation and the National Institute of Health, General Medical Sciences (GM13598), for their generous support of our programs. Mass spectra were provided by the Mass Spectrometry Facility of the University of California, San Francisco, supported by the NIH Division of Research Resources. C. J. thanks The Swedish Foundation for International Cooperation in Research and Higher Education (STINT). )

15. Vanadium-Catalyzed anti-Selective Additions of Allenols to Imines ( We thank the National Science Foundation and the National Institute of Health, General Medical Sciences (GM13598), for their generous support of our programs. Mass spectra were provided by the Mass Spectrometry Facility of the University of California, San Francisco, supported by the NIH Division of Research Resources. C. J. thanks The Swedish Foundation for International Cooperation in Research and Higher Education (STINT). )

18. Stereocontrolled Total Synthesis of (+)-Streptazolin by a Palladium-Catalyzed Reductive Diyne CyclizationWe thank Professor D. L. Comins for kindly providing us with the spectroscopic data for 1, and the National Institutes of Health (GM 033 049) and the National Science Foundation for their generous financial support. C.K.C. is a Stanford Graduate Fellow. Mass spectra were measured by the Mass Spectrometry Facility, University of San Francisco, supported by the NIH Division of Research Resources.

19. Stereocontrolled Total Synthesis of (+)-Streptazolin by a Palladium-Catalyzed Reductive Diyne CyclizationWe thank Professor D. L. Comins for kindly providing us with the spectroscopic data for 1, and the National Institutes of Health (GM 033 049) and the National Science Foundation for their generous financial support. C.K.C. is a Stanford Graduate Fellow. Mass spectra were measured by the Mass Spectrometry Facility, University of San Francisco, supported by the NIH Division of Research Resources.

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