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The precipitates and the intergranular corrosion behavior of a UNS N08028 nickel–iron–chromium alloy sensitized at different temperatures were studied by employing transmission electron microscopy, Kelvin probe force microscopy and other methods. It was found that sigma precipitates appeared at the grain boundaries of the alloy being sensitized. There was a Cr-depleted zone and a low-potential zone around these precipitates. The potential difference between the sigma precipitates and the low-potential zone was 102 mV, and this increased with the growth of the sigma precipitates. At this potential difference, the migration of the vacancies in the passive film accelerated significantly, and then the protectiveness of the passive film decreased. The intergranular corrosion mechanism of the steel has also be discussed. [ABSTRACT FROM AUTHOR]

Copyright of Advances in Atmospheric Sciences is the property of Springer Nature and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

Based on the strict radiative transfer algorithm, a new method is developed to derive the precipitable water vapor (PWV) and aerosol optical depth (AOD) from the ground-based direct sun irradiance measurements. The attenuated direct irradiance from 300 to 1700 nm was measured by a pair of grating spectroradiometers, MS711 and MS712 produced by EKO Instruments, located at the Institute of Atmospheric Physics (IAP), Chinese Academy of Sciences (CAS), Beijing (39.98 ∘ N, 116.38 ∘ E), from June 2020 to March 2021. Compared with regular sun photometers such as CE-318 and POM, EKO instruments can measure a wider range of continuous spectra, but their field of view (FOV) is also relatively large. In the PWV inversion of this work, a strong water vapor absorption band around 1370 nm is introduced to retrieve PWV in a relatively dry atmosphere. The circumsolar radiation (CSR) of the EKO instruments is corrected to reduce the influence of scattering from a relatively larger FOV on the AOD inversion. The PWV and AOD inversion results obtained by MS711 and MS712 are compared with the synchronous data of the CE-318 sun photometer. The two retrieval results are highly consistent. The correlation coefficient, mean bias, and standard deviation of PWVEKO and PWVCIMEL are 0.999, -0.027 cm (-2.42 %), and 0.054 cm (3.93 %), respectively, and the relative deviations of the differences between the two are slightly larger for drier air (PWV < 0.5 cm) and lower solar elevation angle. The correlation coefficients of AODEKO and AODCIMEL at 380, 440, 500, 675, 870, and 1020 nm are greater than 0.99, and the relative deviations vary between -6.59 % and 4.27 %. [ABSTRACT FROM AUTHOR]

In our previous taste-masking study, we found that Acesulfame K (AK) had a better taste-masking effect than other high-efficiency sweeteners for several representative bitter natural drugs in aqueous decoction. Furthermore, we performed a preliminary taste-masking study of AK for representative bitter API Berberine Hydrochloride (BH) and found that it had a good taste-masking effect. We also found that flocculent precipitation was generated in the BH solution, but it was not clear whether it was related to the good taste-masking effect. This study was conducted to explore the taste-masking effect and mechanism of AK on BH. The taste-masking effect of AK on BH was evaluated based on the Traditional Human Taste Panel Method and the electronic tongue evaluation method. DSC, XRD, and molecular simulation techniques were used to explore the mechanism of AK on BH, from the macro level and molecular level, respectively. When evaluating the taste-masking effect, we found that 0.1% AK had the best taste-masking effect on BH, while higher concentrations had a worse taste-masking effect. DSC and XRD revealed that the flocculent precipitation was a complex AK-BH. Finally, by simulating the binding of AK, BH, and TAS2R46 receptors, we found the unique taste-masking mechanism of AK. The sweet taste stimulus of AK can mask the bitter taste stimulus of BH, and AK can generate AK-BH with BH to reduce the contact between BH and bitter taste receptors. Additionally, it could block the expression of the TAS2R46 receptors. [ABSTRACT FROM AUTHOR]

The Taklamakan Desert and the Gobi Desert in East Asia constitute the second-largest sources of dust in the world. In particular, dust originating from the Gobi Desert is more susceptible to long-range transport, with consequent impacts in downwind Asian countries and the Northwest Pacific region. Two intensive dust events (the 3·15 dust event and the 3·28 dust event) were experienced in North China in March 2021. The 3·15 dust process was rated as the most intensive dust process in China in the past 10 years. In this study, by using a combination of spaceborne remote sensing datasets from geostationary and polar-orbiting satellites, ground-based columnar observations of aerosol optical parameters, meteorological reanalysis data, and backward trajectory simulations of air masses, the transport pathways and the three-dimensional structure characteristics of dust aerosols during the transport of the two dust events in March 2021 were cross-validated. The results of the study indicated that the two dust events were induced by the Mongolian cyclone. Due to the different configurations of the ground meteorological system conditions, a backflow process occurred during the 3·15 dust event transmission process. After passing over North China and the Bohai Sea, the direction of transport of the dust plume was reversed. The wind deflected from northwest to northeast, and the dust reached the eastern coastal areas of China and was finally deposited on land. The 3·28 dust event exhibited aerosol stratification in the transport path, the higher pure dust layer reached up to 9 km height, and the lower layer underwent aerosol mixing and became a polluted dust aerosol. This study implies that the investigation of dust aerosol transport and the deposition processes, the impact on the ocean, and the impact of marine aerosols on land also needs to be taken into consideration; the integration of advanced satellites and ground-based remote sensing data, the meteorological reanalysis data and the backward trajectories simulation, which complemented and verified each other, can enhance the ability to delineate the transport pathways and the three-dimensional structural characteristics of dust events. [ABSTRACT FROM AUTHOR]

Based on the strict radiative transfer algorithm, a new method is developed to derive the Precipitable Water Vapor (PWV) and Aerosol optical depth (AOD) from the ground-based measurements of direct sun irradiance. The attenuated direct irradiance from 300 nm to 1700 nm with FWHM of 6.5 nm are measured by a pair of grating spectroradiometers MS711 and MS712, located at the Institute of Atmospheric Physics, Chinese Academy of Sciences (39.98° N, 116.38° E), from June 2020 to March 2021. Compared to that of regular sun photometers such as CIMEL and POM, a strong water vapor absorption band near 1370 nm is introduced to derive PWV for the relatively dry atmosphere. The PWV and AOD inversion results obtained by EKO are compared with the synchronous data of CIMEL, and the two are highly consistent. The correlation coefficient, mean bias and standard deviation of PWVEKO and PWVCIMEL are 0.999, -0.027 cm (-3.57 %) and 0.054 cm (3.93 %) respectively, and the relative deviations of the differences between the two are slightly larger for drier air (PWV<5 mm) and lower solar elevation angle. The correlation coefficients of AODEKO and AODCIMEL at 380, 440, 500, 675, 870, 1020 nm are greater than 0.99, and the relative deviations are between -13.59 % and 9.37 %. [ABSTRACT FROM AUTHOR]

Aerosol‐cloud‐precipitation interactions represent one of the most significant uncertainties in climate simulation and projection. In particular, the impact of aerosols on precipitation is highly uncertain due to limited and conflicting observational evidence. A major challenge is to distinguish the effects of different types of aerosols on precipitation associated with deep convective clouds, which produces most of the precipitation in East Asia. Here, we use 9‐yr observations from multiple satellite‐borne sensors and find that the occurrent frequency of heavy rain increases while that of light rain decreases with the increase of aerosol optical depth (AOD) for dust and polluted continental aerosol types. For average hourly precipitation amount, elevated smoke tends to suppress deep convective precipitation, while dust and polluted continental aerosols enhance precipitation mainly through the invigoration of deep convection. The invigoration effect is more significant for clouds with higher cloud base temperature (CBT), while no significant invigoration is observed when CBT is <12°C. A great contrast is found for the response of average hourly precipitation amount to aerosols over ocean and land. While the prevailing continental aerosol types other than smoke increase precipitation, the marine aerosols first enhance and then inhibit precipitation with the increase of AOD. Moreover, our analysis indicates that the above‐mentioned enhancement and inhibition effects on precipitation are mainly caused by aerosols themselves, rather than by the covariation of meteorological factors. These observed relationships between different aerosol types and precipitation frequency and amount provide valuable constraints on the model forecasting of precipitation. Key Points: Dust and polluted continental aerosols enhance deep convective precipitation while elevated smoke suppresses itThe aerosol invigoration effect is more significant for clouds with higher cloud base temperatureUnlike terrestrial aerosols, marine aerosols first enhance and then inhibit precipitation with the increase of AOD [ABSTRACT FROM AUTHOR]

The long-term effects of complex terrain on solar energy distributions and surface hydrology over the Tibetan Plateau (TP) are investigated using the 4th version of the global Community Climate System Model (CCSM4) coupled with a 3-D radiative transfer (RT) parameterization. We examine the differences between the results from CCSM4 with the 3-D RT parameterization and the results from CCSM4 with the plane-parallel RT scheme. In January (winter), the net surface solar flux (FSNS) displays negative deviations over valleys and the north slopes of mountains, especially in the northern margin of the TP, as a result of the 3-D shadow effect. Positive deviations in FSNS in January are found over the south slopes of mountains and over mountain tops, where more solar flux is intercepted. The deviations in total cloud fraction and snow water equivalent (SWE) exhibit patterns opposite to that of FSNS. The SWE decreases due to the 3-D mountain effect in spring and the magnitude of this effect depends on the terrain elevations. The SWE is reduced by 1–17 mm over the TP in April, with the largest decrease in SWE at an elevation of 3.5–4.5 km. Negative deviations in precipitation are found throughout the year, except in May and December, and they follow the seasonal variations in the deviations in total cloud fraction. The total liquid runoff at 3.5–4.5 km elevation increases in April due to earlier (March) snowmelt caused by increased downward solar radiation. The possible deviations in surface energy and SWE over the TP, caused by plane-parallel assumption in most climate models may result in biases in the liquid runoff and the river water resources over the TP and downstream. [ABSTRACT FROM AUTHOR]

Copyright of Advances in Atmospheric Sciences is the property of Springer Nature and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

The climatic and health effects of aerosols are strongly dependent on the intra-annual variations in their loading and properties. While the seasonal variations of regional aerosol optical depth (AOD) have been extensively studied, understanding the temporal variations in aerosol vertical distribution and particle types is also important for an accurate estimate of aerosol climatic effects. In this paper, we combine the observations from four satellite-borne sensors and several ground-based networks to investigate the seasonal variations of aerosol column loading, vertical distribution, and particle types over three populous regions: the Eastern United States (EUS), Western Europe (WEU), and Eastern and Central China (ECC). In all three regions, column AOD, as well as AOD at heights above 800 m, peaks in summer/spring, probably due to accelerated formation of secondary aerosols and hygroscopic growth. In contrast, AOD below 800m peaks in winter over WEU and ECC regions because more aerosols are confined to lower heights due to the weaker vertical mixing. In the EUS region, AOD below 800m shows two maximums, one in summer and the other in winter. The temporal trends in low-level AOD are consistent with those in surface fine particle (PM2:5) concentrations. AOD due to fine particles (< 0:7 µm diameter) is much larger in spring/summer than in winter over all three regions. However, the coarse mode AOD (> 1:4 µm diameter), generally shows small variability, except that a peak occurs in spring in the ECC region due to the prevalence of airborne dust during this season. When aerosols are classified according to sources, the dominant type is associated with anthropogenic air pollution, which has a similar seasonal pattern as total AOD. Dust and sea-spray aerosols in the WEU region peak in summer and winter, respectively, but do not show an obvious seasonal pattern in the EUS region. Smoke aerosols, as well as absorbing aerosols, present an obvious unimodal distribution with a maximum occurring in summer over the EUS and WEU regions, whereas they follow a bimodal distribution with peaks in August and March (due to crop residue burning) over the ECC region. [ABSTRACT FROM AUTHOR]

Copyright of Advances in Atmospheric Sciences is the property of Springer Nature and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

Using radiosonde measurements from 26 July to 30 July 2014 at Baiqi over the Inner Mongolia grassland of China, the vertical structure of shallow cumulus (SCu) clouds and associated environmental conditions were investigated. The cloud base height and the cloud top height of SCu was 3.4 km and 5 km, respectively. The temperature of the SCu layer was less than 0°C. The horizontal advection of specific humidity was smaller than the vertical transport in the atmosphere below 5 km. Above 5 km, the thermodynamic structure of the atmosphere remained stable. At the interface of the cloud layer and free air atmosphere, there was obvious wind shear and a temperature inversion (~2.9°C). Comparisons of environmental parameters associated with cumulus congestus, rain and clear days, showed that the formation of SCu was characterized by a higher Bowen ratio (high sensible heat flux and low latent heat flux), which indicated intensive turbulence in the boundary layer. The formation of SCu was associated with the boundary layer height exceeding the lifting condensation level. The maintenance of SCu was likely associated with the lower convective available potential energy, weak wind shear, and weak subsidence of the synoptic system, which did not favor the dramatic vertical development of SCu and thereby the transformation of SCu to cumulus congestus. [ABSTRACT FROM AUTHOR]

Knowledge of the statistical characteristics of inversions and their effects on aerosols under different large-scale synoptic circulations is important for studying and modeling the diffusion of pollutants in the boundary layer. Based on results generated using the self-organizing map (SOM) weather classification method, this study compares the statistical characteristics of surface-based inversions (SBIs) and elevated inversions (EIs), and quantitatively evaluates the effect of SBIs on aerosol condensation nuclei (CN) concentrations and the relationship between temperature gradients and aerosols for six prevailing synoptic patterns over the the Southern Great Plains (SGP) site during 2001-10. Large-scale synoptic patterns strongly influence the statistical characteristics of inversions and the accumulation of aerosols in the low-level atmosphere. The activity, frequency, intensity, and vertical distribution of inversions are significantly different among these synoptic patterns. The vertical distribution of inversions varies diurnally and is significantly different among the different synoptic patterns. Anticyclonic patterns affect the accumulation of aerosols near the ground more strongly than cyclonic patterns. Mean aerosol CN concentrations increase during SBIs compared to no inversion cases by 16.1%, 22.6%, 24.5%, 58.7%, 29.8% and 23.7% for the six synoptic patterns. This study confirms that there is a positive correlation between temperature gradients and aerosol CN concentrations near the ground at night under similar large-scale synoptic patterns. The relationship is different for different synoptic patterns and can be described by linear functions. These findings suggest that large-scale synoptic patterns change the static stability of the atmosphere and inversions in the lower atmosphere, thereby influencing the diffusion of aerosols near the ground. [ABSTRACT FROM AUTHOR]

The column-integrated optical properties of aerosol in Beijing and Xianghe, two AErosol RObotic NETwork (AERONET) sites situated on the North China Plain (NCP), are investigated based on Cimel sunphotometer measurements from October 2004 to June 2012. The outstanding feature found is that the seasonal medians of aerosol optical depth (AOD) at the two stations are in good agreement. The correlation coefficients and the absolute differences between AOD at the two stations are larger than 0.84 and less than 0.05, respectively. Good agreement in AOD at these two sites (one urban and the other suburban; 70 km apart) indicates that aerosol pollution in the Greater Beijing area is regional in nature. However, we find significant differences in the absorption Ångström Exponent (AAE), the real and imaginary part of the refractive index, and thereby the single scattering albedo (SSA), and the difference is seasonally dependent. The feature is found to be more prominent in fall when the fine-mode fraction (FMF) and fine-mode effective radius are significantly different at the two stations, besides the parameters mentioned above. The SSA in Beijing at four wavelengths shows lower values as compared to those in Xianghe, although the difference is not significant in some cases. Significant differences in AAE and fine-mode effective radius indicate that there are differences in aerosol physical and chemical properties in urban and suburban regions on the NCP. [ABSTRACT FROM AUTHOR]

Aerosol optical properties over Beijing and Xianghe under several typical weather conditions (clear sky, light haze, heavy pollution and dust storm) are derived from POLDER (POLarization and Directionality of the Earth’s Reflectances)/PARASOL (Polarization and Anisotropy of Reflectances for Atmospheric Sciences coupled with Observations from a Lidar) multi-directional, multi-spectral polarized signals using a more reliable retrieval algorithm as proposed in this paper. The results are compared with those of the operational retrieval algorithm of POLDER/PARASOL group and the ground-based AERONET (AErosol RObotic NETwork)/PHOTONS (PHOtométrie pour le Traitement Opérational de Normalisation Satellitaire) measurements. It is shown that the aerosol optical parameters derived from the improved algorithm agree well with AERONET/PHOTONS measurement. The retrieval accuracies of aerosol optical thickness (AOT) and effective radius are 0.06 and 0.05 µm respectively, which are close to or better than the required accuracies (0.04 for AOT and 0.1 µm for effective radius) for estimating aerosol direct forcing. [ABSTRACT FROM AUTHOR]

We present the mapping at fine spatial scale of aerosol optical properties using a mobile laboratory equipped with LIDAR (Light Detection And Ranging), sun photometer and in situ instruments for performing on-road measurements. The mobile campaign was conducted from 9 May to 19 May 2017 and had the main objective of mapping the distribution of pollutants in the Beijing and North China Plain (NCP) region. The highest AOD (Aerosol Optical Depth) at 440 nm of 1.34 and 1.9 were recorded during two heavy pollution episodes on 18 May and 19 May 2017, respectively. The lowest Planetary Boundary Layer (PBL) heights (0.5–1.5 km) were recorded during the heavy pollution events, correlating with the highest AOD and southern winds. The transport of desert dust from the Gobi Desert was captured during the mobile measurements, impacting Beijing during 9–13 May 2017. Exploring the NCP outside Beijing provided datasets for regions with scarce ground measurements and allowed the mapping of high aerosol concentrations when passing polluted cities in the NCP (Baoding, Tianjin and Tangshan) and along the Binhai New Area. For the first time, we provide mass concentration profiles from the synergy of LIDAR, sun photometer and in situ measurements. The case study along the Binhai New Area revealed mean extinction coefficients of 0.14 ± 0.10 km−1 at 532 nm and a mass concentration of 80 ± 62 μg/m3 in the PBL (<2 km). The highest extinction (0.56 km−1) and mass concentrations (404 μg/m3) were found in the industrial Binhai New Area. The PM10 and PM2.5 fractions of the total mass concentration profiles were separated using the columnar size distribution, derived from the sun photometer measurements. This study offers unique mobile datasets of the aerosol optical properties in the NCP for future applications, such as satellite validation and air quality studies. [ABSTRACT FROM AUTHOR]

In this study, using Aerosol Robotic Network aerosol optical depth (AOD) products at three stations in the North China Plain (NCP)—a heavily polluted region in China—the AOD products from six satellite-borne radiometers: the Moderate Resolution Imagining Spectroradiometer (MODIS), the Multiangle Imaging Spectroradiometer (MISR), Ozone Mapping Imaging (OMI), the Visible Infrared Imaging Radiometer (VIIRS), the Sea-Viewing Wide Field-of-View Sensor (SeaWiFS), and Polarization and Directionality of the Earth's Reflectances (POLDER), were thoroughly validated, shedding new light on their advantages and disadvantages. The MODIS Deep Blue (DB) products provide more accurate retrievals than the MODIS Dark Target (DT) and other satellite products at the Beijing site (BJ, a megacity), with higher correlations with AERONET (R > 0.93), lower mean absolute bias (MB < 0.012), and higher percentages (>68%) falling within the expected error (EE). All MODIS DT and DB products perform better than the other satellite products at the Xianghe site (XH, a suburb). The MODIS/Aqua DT products at both 3-km and 10-km resolutions performed better than the other space-borne AOD products at the Xinglong site (XL, a rural area at the top of a mountain). MISR, VIIRS, and SeaWiFS tend to underestimate high AOD values and overestimate AOD values under very low AOD conditions in the NCP. Both OMI and POLDER significantly underestimate the AOD. In terms of data volume, MISR with the limited swath width of 380 km has less data volume than the other satellite sensors. MODIS products have the highest sampling rate, especially the MODIS DT and DB merged products, and can be used for various climate study and air-quality monitoring. [ABSTRACT FROM AUTHOR]

Aerosols and their radiative effects are of primary interest in climate research because of their vital influence on climate change. Dust aerosols are an important aerosol type in the North China Plain (NCP), mainly as a result of long-range transport, showing substantial spatiotemporal variations. By using measurements from the Aerosol Robotic Network (AERONET) between September 2004 and May 2017, and the space-borne Moderate Resolution Imaging Spectroradiometer (MODIS) and Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observations (CALIPSO) aerosol products, we investigated the properties of dust aerosols and their radiative effects at Xianghe (XH)—a suburban site in the NCP. Dust events occurred most frequently during spring (a total of 105 days) relative to the other three seasons (a total of 41 days) during the periods concerned. The dust aerosol optical depth (AOD) at 675 nm was at a maximum in spring (0.60 ± 0.44), followed (in decreasing order) by those in autumn (0.58 ± 0.39), summer (0.54 ± 0.15), and winter (0.53 ± 0.23). Cooling effects of dust aerosol radiative forcing (RF) at the bottom and top of the atmosphere tended to be strongest in spring (−96.72 ± 45.69 and −41.87 ± 19.66 Wm−2) compared to that in summer (−57.08 ± 18.54 and −25.54 ± 4.45 Wm−2), autumn (−72.01 ± 27.27 and −32.54 ± 15.18 Wm−2), and winter (−79.57 ± 32.96 and −37.05 ± 17.06 Wm−2). The back-trajectory analysis indicated that dust air mass at 500 m that arrived at XH generally originated from the Gobi and other deserts of northern China and Mongolia (59.8%), and followed by northwest China and Kazakhstan (37.2%); few dust cases came from northeast China (3.0%). A single-peaked structure with the maximum occurring at ~2 km was illustrated by all dust events and those sorted by their sources in three directions. Three typical dust events were specifically discussed to better reveal how long-range transport impacted the dust properties and radiative effects over the NCP. The results presented here are expected to improve our understanding of the physical properties of dust aerosols over the NCP and their major transport path and significant impacts on the regional solar radiation budget. [ABSTRACT FROM AUTHOR]

A thorough understanding of aerosol optical properties and their spatio-temporal variability are required to accurately evaluate aerosol effects in the climate system. In this study, a multi-year study of aerosol optical and microphysical properties was firstly performed in Xi’an based on three years of sun photometer remote sensing measurements from 2012 to 2015. The multi-year average of aerosol optical depth (AOD) at 440 nm was about 0.88 ± 0.24 (mean ± SD), while the averaged Ångström Exponent (AE) between 440 and 870 nm was 1.02 ± 0.15. The mean value of single scattering albedo (SSA) was around 0.89 ± 0.03. Aerosol optical depth and AE showed different seasonal variation patterns. Aerosol optical depth was slightly higher in winter (0.99 ± 0.36) than in other seasons (~0.85 ± 0.20), while AE showed its minimum in spring (0.85 ± 0.05) due to the impact of dust episodes. The seasonal variations of volume particle size distribution, spectral refractive index, SSA, and asymmetry factor were also analyzed to characterize aerosols over this region. Based on the aerosol products derived from sun photometer measurements, the classification of aerosol types was also conducted using two different methods in this region. Results show that the dominant aerosol types are absorbers in all seasons, especially in winter, demonstrating the strong absorptivity of aerosols in Xi’an. [ABSTRACT FROM AUTHOR]